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It is known that the chiral interaction described by Dzyaloshinskii-Moriya (DMI) term lead to the plethora of topological structures of magnetic spins, such as helical or skyrmion phases. Here we present the that analogues electrical DMI…

Ferroelectric nematic phases are a new class of polar fluids in which spontaneous polarization is directly coupled to the orientational order, providing unique opportunities for creating self-organized materils with spatially modulated…

Ferroelectric ordering in liquids is a fundamental question of physics. Here, we show that ferroelectric ordering of the molecules causes formation of recently reported splay nematic liquid-crystalline phase. As shown by dielectric…

Strongly dipolar mesogenic compounds with a chiral center located in a lateral alkyl chain were synthesized, and shown to form the ferroelectric nematic phase. The presence of molecular chirality induced a helical structure in both the N…

Spontaneous symmetry breaking and emergent polar order are each of fundamental importance to a range of scientific disciplines, as well as generating rich phase behaviour in liquid crystals (LCs). Here, we show the union of these phenomena…

Soft Condensed Matter · Physics 2024-08-06 Calum Gibb , Jordan Hobbs , Diana Nikolova , Tom Raistrick , Helen Gleeson , Richard Mandle

Topological spin and polar textures have fascinated people in different areas of physics and technologies. However, the observations are limited in magnetic and solid-state ferroelectric systems. Ferroelectric nematic is the first…

Soft Condensed Matter · Physics 2022-12-22 Jidan Yang , Yu Zou , Wentao Tang , Jinxing Li , Mingjun Huang , Satoshi Aya

Under an electric field, chiral smectic liquid crystals transit usually to the unwound SmC* phase where the helical structure is completely unrolled. Sometimes the sample transits initially towards an intermediate polar state before the…

Soft Condensed Matter · Physics 2019-10-02 H. Dhaouadi , O. Riahi , R. Zgueb , F. Trabelsi , T. Othman

In soft ferroelectric crystals, the depolarization field can be reduced by periodic distortion of the polarization direction. In the polar nematic and tilted smectic phases, this process is energetically favorured , as it only requires…

Liquid crystal materials exhibiting up to three nematic phases are reported. Dielectric response measurements show that while the lower temperature nematic phase has ferroelectric order and the highest temperature nematic phase is apolar,…

Soft Condensed Matter · Physics 2021-09-07 S. Brown , E. Cruickshank , J. M. D. Storey , C. T. Imrie , D. Pociecha , M. Majewska , A. Makal , E. Gorecka

General microscopic mechanism of ferroelectric ordering in chiral smectic C* liquid crystals is considered. It is shown that if the mesogenic molecules have a sufficiently low symmetry, the spontaneous polarization is proportional to one of…

Soft Condensed Matter · Physics 2009-11-13 M. A. Osipov , M. V. Gorkunov

We have numerically studied a liquid composed of achiral, bent-shaped molecules built of tangent spheres. The system is known to spontaneously break mirror symmetry, as it forms a macroscopically chiral, twist-bend nematic phase [Phys. Rev.…

Soft Condensed Matter · Physics 2022-09-27 Piotr Kubala , Wojciech Tomczyk , Michał Cieśla

In soft matter, the polar orientational order of molecules can facilitate the coexistence of structural chirality and ferroelectricity. The ferroelectric nematic (NF) state, exhibited by achiral calamitic molecules with large dipole…

Soft Condensed Matter · Physics 2025-03-13 Hiroya Nishikawa , Yasushi Okumura , Dennis Kwaria , Atsuko Nihonyanagi , Fumito Araoka

The discovery of fluid states of matter with spontaneous bulk polar order is appreciated as a major discovery in the fields of soft matter and liquid crystals. Typically, this manifests as polar order superimposed atop conventional phase…

Soft Condensed Matter · Physics 2024-11-22 Jordan Hobbs , Calum J. Gibb , Damian Pociecha , Jadwiga Szydłowska , Ewa Górecka , Richard. J. Mandle

A material showing a sequence of three ferroelectric liquid crystalline phases below the paraelectric nematic phase has been synthesized and studied. The polar order of molecules appearing due to the dipole-dipole interactions in the NF…

Soft Condensed Matter · Physics 2024-10-16 Grant J. Strachan , Ewa Górecka , Jadwiga Szydłowska , Anna Makal , Damian Pociecha

We show that development of polar order may spontaneously destroy the lamellar structure of a liquid crystal. This results in an unusual sequence of phases with the ferroelectric nematic phase appearing below a non-polar smectic phase. The…

Ferroelectric nematic liquid crystals are formed by achiral molecules with large dipole moments. Its three-dimensional orientational order is universally described as unidirectionally polar. We demonstrate that the ground state of…

Soft Condensed Matter · Physics 2024-04-01 Priyanka Kumari , Bijaya Basnet , Maxim O. Lavrentovich , Oleg D. Lavrentovich

The recent discovery of ferroelectric nematic liquid crystalline phases marks a major breakthrough in soft matter research. An intermediate phase, often observed between the nonpolar and the ferroelectric nematic phase, shows a distinct…

We report the experimental determination of the structure and response to applied electric field of the lower-temperature nematic phase of the previously reported calamitic compound 4-[(4-nitrophenoxy)carbonyl]phenyl2,4-dimethoxybenzoate…

A system that possesses translational symmetry but breaks orientational symmetry is known as a nematic phase. While there are many examples of nematic phases in a wide range of contexts, such as in liquid crystals, complex oxides, and…

We have structurally characterized the liquid crystal phase that appears as an intermediate state when a dielectric nematic, having polar disorder of its molecular dipoles, transitions to the almost perfectly polar-ordered ferroelectric…

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