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At very high doping levels the van Hove singularity in the $\pi^*$ band of graphene becomes occupied and exotic ground states possibly emerge, driven by many-body interactions. Employing a combination of ytterbium intercalation and…

Mesoscale and Nanoscale Physics · Physics 2020-10-20 Philipp Rosenzweig , Hrag Karakachian , Dmitry Marchenko , Kathrin Küster , Ulrich Starke

Heavily doping graphene by intercalation can raise its Fermi level near an extended van Hove singularity, potentially inducing correlated electronic phases. Intercalation also modifies the band structure: dopants may hybridize with carbon…

Graphene band renormalization at the proximity of the van Hove singularity (VHS) has been investigated by angle-resolved photoemission spectroscopy (ARPES) on the Li-doped quasi-freestanding graphene on the cobalt (0001) surface. The…

Controlled modulation of electronic band structure in two-dimensional (2D) materials via doping is crucial for devices fabrication. For instance doped graphene has been envisaged for various applications like sensors, super-capacitors,…

Materials Science · Physics 2025-01-08 Imtiaz Noor Bhatti , J. Avila , Z. Chen , A. Baron , Y. Zhang , A. Shukla , P. Dudin

Electronic instabilities at the crossing of the Fermi energy with a Van Hove singularity in the density of states often lead to new phases of matter such as superconductivity, magnetism or density waves. However, in most materials this…

Mesoscale and Nanoscale Physics · Physics 2011-04-18 Guohong Li , A. Luican , J. M. B. Lopes dos Santos , A. H. Castro Neto , A. Reina , J. Kong , E. Y. Andrei

Recently the graphene/SiC interface has emerged as a versatile platform for the epitaxy of otherwise unstable, monoelemental, two-dimensional (2D) layers via intercalation. Intrinsically capped into a van der Waals heterostructure with…

Mesoscale and Nanoscale Physics · Physics 2022-06-23 Philipp Rosenzweig , Hrag Karakachian , Dmitry Marchenko , Ulrich Starke

Recently it was reported experimentally that the monolayer graphene can be doped to beyond the Van Hove singularity. We study theoretically the possible superconductivity and the corresponding spin excitations of the monolayer graphene in…

Superconductivity · Physics 2021-05-25 Wei-Jie Lin , W. LiMing , Tao Zhou

The electronic band structure of twisted bilayer graphene develops van Hove singularities whose energy depends on the twist angle between the two layers. Using Raman spectroscopy, we monitor the evolution of the electronic band structure…

In monolayer graphene, substitutional doping during growth can be used to alter its electronic properties. We used scanning tunneling microscopy (STM), Raman spectroscopy, x-ray spectroscopy, and first principles calculations to…

We study the instability of the metallic state towards the formation of a new ground state in graphene doped near the van Hove singularity. The system is described by the Hubbard model and a field theoretical approach is used to calculate…

Mesoscale and Nanoscale Physics · Physics 2011-09-16 D. Makogon , R. van Gelderen , R. Roldán , C. Morais Smith

A variety of new and interesting correlated states have been predicted in graphene monolayer doped to Van Hove singularities (VHSs) of its density-of-state (DOS). However, tuning the Fermi energy to reach a VHS of graphene by either gating…

Mesoscale and Nanoscale Physics · Physics 2017-05-11 Si-Yu Li , Ke-Qin Liu , Long-Jin Yin , Wen-Xiao Wang , Wei Yan , Xu-Qin Yang , Jun-Kai Yang , Haiwen Liu , Hua Jiang , Lin He

We have performed scanning gate microscopy (SGM) on graphene field effect transistors (GFET), using a biased metallic nanowire coated with a dielectric layer as a contact mode tip and local top gate. Electrical transport through graphene at…

We achieve fine tuning of graphene effective doping by applying ultrahigh pressures (> 10 GPa) using Atomic Force Microscopy (AFM) diamond tips. Specific areas in graphene flakes are irreversibly flattened against a SiO2 substrate. Our work…

The nature of the coupling leading to superconductivity in layered materials such as high-Tc superconductors and graphite intercalation compounds (GICs) is still unresolved. In both systems, interactions of electrons with either phonons or…

Strongly Correlated Electrons · Physics 2007-05-24 Jessica L. McChesney , Aaron Bostwick , Taisuke Ohta , Konstantin V. Emtsev , Thomas Seyller , Karsten Horn , Eli Rotenberg

The design of stacks of layered materials in which adjacent layers interact by van der Waals forces[1] has enabled the combination of various two-dimensional crystals with different electrical, optical and mechanical properties, and the…

Mesoscale and Nanoscale Physics · Physics 2016-02-17 L. Ju , J. Velasco , E. Huang , S. Kahn , C. Nosiglia , H. Tsai , W. Yang , T. Taniguchi , K. Watanabe , Y. Zhang , G. Zhang , M. Crommie , A. Zettl , F. Wang

We determine the properties and leading instabilities of a spin liquid with a Fermi surface passing near a van Hove singularity. Our study is motivated by recent photoemission experiments on high $T_c$ cuprates in which it is found that for…

Condensed Matter · Physics 2009-10-28 L. B. Ioffe , A. J. Millis

Layered electrides, as typified by Ca$_2$N, are a new class of quasi-two-dimensional materials with low work functions. Using first-principles calculations, we have shown that a graphene layer deposited on Ca$_2$N is doped to $n=5\times…

Materials Science · Physics 2017-12-20 Takeshi Inoshita , Masaru Tsukada , Susumu Saito , Hideo Hosono

The density of states of graphene has Van Hove singularities that can be reached by chemical doping and have already been explored in photoemission experiments. We show that in the presence of Coulomb interactions the system at the Van Hove…

Strongly Correlated Electrons · Physics 2009-11-13 Belen Valenzuela , Maria A. H Vozmediano

Extensive scanning tunnelling microscopy and spectroscopy experiments complemented by first principles and parameterized tight binding calculations provide a clear answer to the existence, origin and robustness of van Hove singularities…

We show that the electron-phonon coupling strength obtained from the slopes of the electronic energy vs. wavevector dispersion relations, as often done in analyzing angle-resolved photoemission data, can differ substantially from the actual…

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