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The high performance of hybrid perovskite based devices is attributed to its excellent bulk-transport properties. However, carrier dynamics, especially at the metal-perovskite interface, and its influence on device operation are not widely…

Materials Science · Physics 2022-02-25 N. Ganesh , A. Z. Ashar , Sumukh Purohit , K. L. Narasimhan , K. S. Narayan

The great variety of lead halide perovskite semiconductors represents an outstanding platform for studying crystal symmetry effects on the spin-dependent properties. Access to them is granted through optical orientation of exciton and…

Controlling the spin degree of freedom of light at the microscale is crucial for advancing photonic information processing. Spin polarized light propagation, combined with strong optical nonlinearities, unlocks new functionalities in…

Other Condensed Matter · Physics 2025-10-20 Mateusz Kędziora , Andrzej Opala , Maciej Zaremba , Helgi Sigurðsson , Barbara Piętka

Inorganic-organic lead halide perovskites, particularly methylammonium lead halide (MAPbI$_3$) perovskite, is perceived to be a promising material for optoelectronics and spintronics. However, lead toxicity and instability under air and…

Materials Science · Physics 2022-12-07 Megha Arya , Preeti Bhumla , Sajjan Sheoran , Suraj , S Bhattacharya

Cesium based halide perovskites, such as CsPbI3 and CsSnI3, have emerged as exceptional candidates for next generation photovoltaic and optoelectronic technologies, but their practical application is limited by temperature dependent phase…

Materials Science · Physics 2025-10-30 Atefe Ebrahimi , Franco Pellegrini , Stefano De Gironcoli

Owing to their exceptional semiconducting properties, hybrid inorganic-organic perovskites show great promise as photovoltaic absorbers. In these materials, long-range diffusion of charge carriers allows for most of the photogenerated…

The spin degree of freedom of charge carriers in halide-perovskite semiconductors can be highly useful for information photonics applications. The Faraday effect is known to be the best indicator of paramagnetism of the material and of the…

Organometal halide perovskites are promising solar-cell materials for next-generation photovoltaic applications. The long carrier lifetime and diffusion length of these materials make them very attractive for use in light absorbers and…

Materials Science · Physics 2016-12-21 Fan Zheng , Liang Z. Tan , Shi Liu , Andrew M. Rappe

Spin-orbit coupling (SOC) is responsible for a range of spintronic and topological processes in condensed matter. Here we show photonic analogs of SOCs in exciton-polaritons and their condensates in microcavities composed of birefringent…

Halide perovskites are a promising optical gain media with high tunability and simple solution synthesis. In this study, two gain regimes, namely amplified spontaneous emission and random lasing, are demonstrated in same MAPbBr$_3$ halide…

In semiconductor spintronics, the generation of highly spin-polarized carriers and the efficient probe of spin order (due to strong ferromagnetism) -- at or above room temperature -- are crucial because it allows for the design of…

Materials Science · Physics 2023-06-09 Hong Jian Zhao , Longju Yu , Yanchao Wang , Laurent Bellaiche , Yanming Ma

Metal halide perovskites exhibit a materials physics that is distinct from traditional inorganic and organic semiconductors. While materials such as CH3NH3PbI3 are non-magnetic, the presence of heavy elements (Pb and I) in a…

The hybrid organic-inorganic halide perovskite (HOIP), for example MAPbBr3, exhibits extended spin lifetime and apparent spin lifetime anisotropy in experiments. The underlying mechanisms of these phenomena remain illusive. By utilizing our…

Materials combining the optoelectronic functionalities of semiconductors with control of the spin degree of freedom are highly sought after for the advancement of quantum technology devices. Here, we report the paramagnetic…

Lead-halide perovskites enjoy a number of remarkable optoelectronic properties. To explain their origin, it is necessary to study how electromagnetic fields interact with these systems. We address this problem here by studying two classical…

Here we develop a microscopic approach aimed at the description of a suite of physical effects related to carrier transport in, and the optical properties of, halide perovskites. Our theory is based on the description of the nuclear…

Materials Science · Physics 2018-11-13 Matthew Z. Mayers , Liang Z. Tan , David A. Egger , Andrew M. Rappe , David R. Reichman

For static crystals it is well known that electronic states are doubly degenerate in their spin degree of freedom in the presence of time reversal and inversion symmetries. This degeneracy can only be lifted by either (i) breaking time…

Materials Science · Physics 2017-11-20 Bartomeu Monserrat , David Vanderbilt

Hybrid organic-inorganic halide perovskites have shown remarkable optoelectronic properties (1-3), believed to originate from correlated motion of charge carriers and the polar lattice forming large polarons (4-7). Few experimental…

We theoretically investigate lead iodide perovskites of general formula APbI$_3$ for a series of metallic cations (namely Cs$^+$, Rb$^+$, K$^+$, Na$^+$ and Li$^+$) by means of the density functional theory, GW method and Bethe-Salpeter…

Materials Science · Physics 2024-01-30 Małgorzata Wierzbowska , Juan J. Meléndez

The family of organometal trihalide perovskite (OTP), CH3NH3PbX3 (where X is halogen) has recently revolutionized the photovoltaics field and shows promise in a variety of optoelectronic applications. The characteristic spin properties of…