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Metal halide perovskites (MHPs) are known to undergo several structural phase transitions, from lower to higher symmetry, upon heating. While structural phase transitions have been investigated by a wide range of optical, thermal and…

Materials Science · Physics 2022-03-07 Shunran Li , Zhenghong Dai , Conrad A. Kocoj , Eric I. Altman , Nitin P. Padture , Peijun Guo

The defect tolerance nature of organic-inorganic hybrid perovskite is reflected from its stupendous growth in photovoltaic performances. The presence of lattice defect can manipulate or even gives rise to some exceptional properties which…

Organolead halide perovskites are a family of hybrid organic-inorganic compounds whose remarkable optoelectronic properties have been under intensive scrutiny in recent years. Here we use inelastic X-ray scattering to study low-energy…

Lead halide perovskites such as methylammonium lead triiodide (MAPI) have outstanding optical and electronic properties for photovoltaic applications, yet a full understanding of how this solution processable material works so well is…

The reversible phase transition between orthorhombic and cubic phases is demonstrated in all-inorganic perovskite CsPbIBr2 grown by a dual-source vapor-deposition method. The phase transition is actuated via heating and moisture exposure.…

Applied Physics · Physics 2018-12-24 Chen Zou , Jiajiu Zheng , Cheng Chang , Arka Majumdar , Lih Y. Lin

Besides permitting an accurate determination of the ferromagnetic-to-paramagnetic phase transition temperature and the characteristic temperatures for the beginning and end of the growth of martensite (austenite) phase at the expense of…

Materials Science · Physics 2009-11-13 P. K. Mukhopadhyay , S. N. Kaul

Methylammonium lead iodide, as related organometal halide perovskites, emerged recently as a particularly attractive material for photovoltaic applications. The origin of its appealing properties is sometimes assigned to its potential…

Materials Science · Physics 2022-04-04 Wen-Yi Tong , Jin-Zhu Zhao , Philippe Ghosez

The partially overlapped ferroelastic/martensitic and para-ferromagnetic phase transitions of a Ni$_{50.53}$Mn${33.65}$In$_{15.82}$ metamagnetic shape memory alloy have been studied from calorimetric, magnetic and acoustic emission…

The spectacular performance of halide perovskites in optoelectronic devices is rooted in their tolerance to defects. Previous studies showed that defects in these materials generate shallow electronic states. However, how these shallow…

Materials Science · Physics 2025-05-20 Frederico P. Delgado , Frederico Simões , Leeor Kronik , Waldemar Kaiser , David A. Egger

Mixed halide perovskites undergo phase segregation, manifested as spectral red-shifting of photoluminescence spectra under illumination. In the iodine-bromide mixed perovskites, the origin of the low-energy luminescence is related to…

Materials Science · Physics 2023-07-18 Grigorii Verkhogliadov , Ross Haroldson , Dmitry Gets , Anvar A. Zakhidov , Sergey V. Makarov

Halide perovskites belong to an important family of semiconducting materials with unique electronic properties that enable a myriad of applications, especially in photovoltaics and optoelectronics. Their optical properties, including…

Photo- and charge-carrier induced ion migration is a major challenge when utilizing metal halide perovskite semiconductors for optoelectronic applications. For mixed iodide/bromide perovskites, the compositional instability due to light- or…

Under continuous light illumination, it is known that localized domains with segregated halide compositions form in semiconducting mixed-halide perovskites, thus severely limiting their optoelectronic applications due to the negative…

Materials Science · Physics 2023-03-21 Shengnan Feng , Rentong Duan , Yu Ju , Shuyi Li , Chunfeng Zhang , Shuxia Tao , Min Xiao , Xiaoyong Wang

Halide perovskite and elpasolite semiconductors are extensively studied for optoelectronic applications due to their excellent performance together with significant chemical and structural flexibility. However, there is still limited…

Microscopic pathways of structural phase transitions are difficult to probe because they occur over multiple, disparate time and length scales. Using $in$ $situ$ nanoscale cathodoluminescence microscopy, we visualize the thermally-driven…

Phase diagrams are an invaluable tool for material synthesis and provide information on the phases of the material at any given thermodynamic condition. Conventional phase diagram generation involves experimentation to provide an initial…

Lead halide perovskites are causing a change of paradigm in photovoltaics. Among other peculiarities, these perovskites exhibit an atypical temperature dependence of the fundamental optical gap: It decreases in energy with decreasing…

A tungsten filament immersed in superfluid helium has strong hysteretic $I$-$V$ characteristics. By increasing the applied voltage, a remarkable current drop occurs at a transition voltage, at which the filament enters a non-ohmic hot state…

Applied Physics · Physics 2021-01-01 Che-Chi Shih , Ming-Huei Huang , Pang-Chia Chang , Po-Wei Yu , Wen-Bin Jian , Kimitoshi Kono

Information technologies require entangling data stability with encryption for a next generation of secure data storage. Current magnetic memories, ranging from low-density stripes up to high-density hard drives, can ultimately be detected…

Urban centers across the globe are responsible for a significant fraction of energy consumption and CO2 emission. As urban centers continue to grow, the popularity of glass as cladding material in urban buildings is an alarming trend.…

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