Related papers: Quantitative thermodynamic analyses of nucleation,…
The dynamic behavior of a partially wetting polymer droplet driven over a nanostructured interface is studied using molecular dynamics simulations. We consider the bead-spring model to represent a polymeric liquid that partially wets a…
The effect of viscosity on the behaviour of a non-equilibrium bubble is investigated experimentally, in two scenarios; firstly, when the bubble is generated in the bulk of the fluid (termed as ``free-field'' bubble) and secondly when the…
Photothermal surface bubbles play important roles in a wide range of applications like catalysis, microfluidics and biosensing, but their formation on a transparent substrate immersed in a plasmonic nanoparticle (NP) suspension has an…
The evolution of the interface separating a conduit of light, viscous fluid rising buoyantly through a heavy, more viscous, exterior fluid at small Reynolds numbers is governed by the interplay between nonlinearity and dispersion. Previous…
The well-known classical nucleation theory (CNT) for the free energy barrier towards formation of a nucleus of critical size of the new stable phase within the parent metastable phase fails to take into account the influence of other…
Ice formation is one of the most common and important processes on earth and almost always occurs at the surface of a material. A basic understanding of how the physicochemical properties of a material's surface affect its ability to form…
The melting of metallic nanoparticles is governed by surface pre-melting, a phenomenon traditionally modeled as the isotropic growth of a uniform liquid shell. Challenging this classical view, we report facet-dependent surface pre-melting…
A thermodynamic approach to rapid phase transformations within a diffuse interface in a binary system is developed. Assuming an extended set of independent thermodynamic variables formed by the union of the classic set of slow variables and…
The physicochemical hydrodynamics of bubbles and droplets out of equilibrium, in particular with phase transitions, displays surprisingly rich and often counterintuitive phenomena. Here we experimentally and theoretically study the…
Control of the crystallization process is central to developing novel materials with atomic precision to meet the demands of electronic and quantum technology applications. Semiconductor nanowires grown by the vapor-liquid-solid process are…
The dynamics of the electroweak phase transition in the early universe has profound implications for cosmology and particle physics. We systematically study the steady-state dynamics of bubble walls in scenarios where the transition is…
We provide a non-equilibrium thermodynamic description of the life-cycle of a droplet based, chemically feasible, system of protocells. By coupling the protocells metabolic kinetics with its thermodynamics, we demonstrate how the system can…
The thermodynamics and kinetics of crystallization of nanoparticles, as opposed to bulk phases, may be influenced by surface and size effects. We investigate the importance of such factors in the crystallization process of gold, silver, and…
The role of thermodynamics in the evolution of systems evolving under purely gravitational forces is not completely established. Both the infinite range and singularity in the Newtonian force law preclude the use of standard techniques.…
Surface-active agents (surfactants) release potential energy as they migrate from one of two adjacent fluids onto their fluid-fluid interface, a process that profoundly impacts the system's energy and entropy householding. The continuum…
Nanobubbles in liquids are mysterious gaseous objects having exceptional stability. They promise a wide range of applications but their production is not well controlled and localized. Alternating polarity electrolysis of water is a tool…
The use of CO2 as a natural refrigerant in data center cooling, oil recovery and in CO2 capture and storage which is gaining traction in recent years involves heat transfer between CO2 and the base fluid. A need arises to improve the…
The Thermodynamic Non-Equilibrium (TNE) effects in the coalescing process of two initially static bubbles under thermal conditions are investigated by a Discrete Boltzmann Model (DBM). The spatial distributions of the typical…
Recent Chandra and XMM-Newton observations of galaxy cluster cooling flows have revealed X-ray emission voids of up to 30 kpc in size that have been identified with buoyant, magnetized bubbles. Motivated by these observations, we have…
We use spherically symmetric hydrodynamic simulations to study the dynamical evolution and internal structure of superbubbles (SBs) driven by clustered supernovae (SNe), focusing on the effects of thermal conduction and cooling in the…