Related papers: Quantitative thermodynamic analyses of nucleation,…
Significant leaps in the understanding of quantum systems have been driven by the exploration of geometry, topology, dimensionality, and interactions with ultracold atomic ensembles. A system where atoms evolve while confined on an…
Nanoparticles with different surface morphologies that straddle the interface between two immiscible liquids are studied via molecular dynamics simulations. The methodology employed allows us to compute the interfacial free energy at…
Nanobubbles formed in monolayers of transition metal dichalcogenides (TMDCs) on top of a substrate feature localized potentials, in which electrons can be captured. We show that the captured electronic density can exhibit a non-trivial…
Gas bubble growth as a result of diffusion flux of dissolved gas molecules from the surrounding supersaturated solution to the bubble surface is studied. The condition of the flux steadiness is revealed. A limitation from below on the…
Assuming that the electroweak and QCD phase transitions are first order, upon supercooling, bubbles of the new phase appear. These bubbles grow to macroscopic sizes compared to the natural scales associated with the Compton wavelengths of…
Improved understanding of molecular systems has only emphasised the sophistication of networks within the cell. Simultaneously, the advance of nucleic acid nanotechnology, a platform within which reactions can be exquisitely controlled, has…
Laser-induced cavitation under nanosecond optical breakdown is central to applications such as laser-induced forward transfer, microsurgery, and microfluidic actuation, yet the physical origin of the earliest cavity and its connection to…
The formation, growth and detachment of gas bubbles on electrodes are omnipresent in electrolysis and other gas-producing chemical processes. To better understand their role in the mass transfer efficiency, we perform experiments involving…
Recently-reported data suggest that bubble nucleation on surfaces with nano-sized features (cavities and posts) may occur close to the thermodynamic saturation temperature. However, according to the traditional theory of heterogeneous…
Cavitation, the formation of vapor bubbles in metastable liquids, is highly sensitive to nanoscale surface defects. Using molecular dynamics simulations and classical nucleation theory, we show that pure water confined within defect-free…
In gas evolving electrolysis, bubbles grow at electrodes due to a diffusive influx from oversaturation generated locally in the electrolyte by the electrode reaction. When considering electrodes of micrometer-size resembling catalytic…
The field of plasmonic nanobubbles, referring to bubbles generated around nanoparticles due to plasmonic heating, is growing rapidly in recent years. Theoretical, simulation and experimental studies have been reported to reveal the…
The nucleation of vapor bubbles within a superheated fluid is studied using density functional theory. The nudged elastic band technique is used to find the minimum energy pathway from the metastable uniform liquid to the stable uniform gas…
In many environmental and industrial applications, the mass transfer of gases in liquid solvents is a fundamental process during the generation of bubbles for specific purposes or, vice versa, the removal of entrapped bubbles. We address…
Surface energy is a fundamental property of materials and is particularly important in describing nanomaterials where atoms or molecules at the surface constitute a large fraction of the material. Traditionally, surface energy is considered…
Nanothermodynamics provides the theoretical foundation for understanding stable distributions of statistically independent subsystems inside larger systems. In this review it is emphasized that adapting ideas from nanothermodynamics to…
Large-scale molecular dynamics simulations are used to simulate a layer of nanoparticles diffusing on the surface of a liquid. Both a low viscosity liquid, represented by Lennard-Jones monomers, and a high viscosity liquid, represented by…
The theory of small-system thermodynamics was originally developed to extend the laws of thermodynamics to length scales of nanometers. Here we review this "nanothermodynamics," and stress how it also applies to large systems that subdivide…
The dynamical perspectives of bubble in a liquid droplet on smooth solid substrate can be revealed by investigating interfacial self-assembly phenomena. Moreover, the complexity in such system can be scaled down into a transparent immobile…
Cavitation and bubble dynamics are central concepts in engineering, the natural sciences, and the mathematics of fluid mechanics. Due to the nonlinear nature of their dynamics, the governing equations are not fully solvable. Here, the…