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Despite the organic molecule inventory detected in Orion KL, acetaldehyde (CH3CHO) -- one of the most ubiquitous interstellar aldehydes -- has not been firmly identified with mm-wave interferometry. We analyze extensive ALMA archival…

The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry…

We report the first high angular resolution imaging (3.4\arcsec $\times$ 3.0\arcsec) of deuterated formaldehyde (HDCO) toward Orion--KL, carried out with the Submillimeter Array (SMA). We find that the spatial distribution of the…

Astrophysics of Galaxies · Physics 2015-08-06 Cecile Favre , Edwin Bergin , Justin Neill , Nathan Crockett , Qizhou Zhang , Dariusz Lis

The formyl radical HCO has been proposed as the basic precursor of many complex organic molecules such as methanol (CH$_3$OH) or glycolaldehyde (CH$_2$OHCHO). Using ALMA, we have mapped, for the first time at high angular resolution…

Astrophysics of Galaxies · Physics 2018-11-28 V. M. Rivilla , M. T. Beltrán , A. Vasyunin , P. Caselli , S. Viti , F. Fontani , R. Cesaroni

Methanol is the most complex molecule securely identified in interstellar ices and is a key chemical species for understanding chemical complexity in astrophysical environments. Important aspects of the methanol ice photochemistry are still…

Astrophysics of Galaxies · Physics 2023-05-10 W. R. M. Rocha , P. Woitke , S. Pilling , W. -F. Thi , J. K. Jørgensen , L. E. Kristensen , G. Perotti , I. Kamp

The recent unexpected detection of terrestrial complex organic molecules in the cold (~ 10 K) gas has cast doubts on the commonly accepted formation mechanisms of these species. Standard gas-phase mechanisms are inefficient and tend to…

Astrophysics of Galaxies · Physics 2016-03-02 Aurore Bacmann , Alexandre Faure

Glycolaldehyde (HOCH$_2$CHO) and ethylene glycol ((CH$_2$OH)$_2$) are two complex organic molecules detected in the hot cores and hot corinos of several star-forming regions. The ethylene glycol/glycolaldehyde abundance ratio seems to show…

Solar and Stellar Astrophysics · Physics 2018-02-07 A. Coutens , S. Viti , J. M. C. Rawlings , M. T. Beltrán , J. Holdship , I. Jiménez-Serra , D. Quénard , V. M. Rivilla

Two main formation routes have been proposed for interstellar complex organic molecules (iCOMs): on dust grain surfaces and in the gas phase. Observing such molecules in protostellar outflow shock regions - provided that their ages are…

Solar and Stellar Astrophysics · Physics 2025-10-20 Juliette Robuschi , Ana López-Sepulcre , Cecilia Ceccarelli , Layal Chahine , Claudio Codella , Linda Podio

(Abridged) We aim to enlarge the number of known hot corinos and carry out a first comparative study with hot cores. The ultimate goal is to understand whether complex organic molecules form in the gas phase or on grain surfaces, and what…

Complex organic molecules (COMs) have been identified in different environments in star- forming regions. Laboratory studies show that COMs form in the solid state, on icy grains, typically following a non-energetic (atom-addition) or…

Astrophysics of Galaxies · Physics 2017-05-23 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Astrophysical observations show complex organic molecules (COMs) in the gas phase of protoplanetary disks. X-rays emitted from the central young stellar object (YSO) that irradiate interstellar ices in the disk, followed by the ejection of…

Earth and Planetary Astrophysics · Physics 2021-02-22 R. Basalgète , R. Dupuy , G. Féraud , C. Romanzin , L. Philippe , X. Michaut , J. Michoud , L. Amiaud , A. Lafosse , J. -H. Fillion , M. Bertin

We present a survey of the formaldehyde emission in a sample of eight Class 0 protostars obtained with the IRAM and JCMT telescopes. The data have been analyzed with three different methods with increasing level of sophistication. We first…

A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable…

Astrophysics of Galaxies · Physics 2020-08-19 Mihwa Jin , Robin T. Garrod

Molecular complexity builds up at each step of the Sun-like star formation process, starting from simple molecules and ending up in large polyatomic species. Complex organic molecules (COMs; such as methyl formate, HCOOCH$_3$, dymethyl…

Methyl formate, HCOOCH$_3$, and many of its isotopologues have been detected in astrophysical regions with considerable abundances. However, the recipe for the formation of this molecule and its isotopologues is not yet known. In this work,…

Astrophysics of Galaxies · Physics 2021-06-30 Zainab Awad , Audrey Coutens , Serena Viti , Jonathan Holdship

This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Herma M. Cuppen , Sergio Ioppolo , Thanja Lamberts , Harold Linnartz

Complex organic molecules (COMs) have been identified toward high- and low-mass protostars as well as molecular clouds, suggesting that these interstellar species originate from the early stage(s) of starformation. The reaction pathways…

Solar and Stellar Astrophysics · Physics 2020-04-08 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , C. Jäger , Th. Henning , M. E. Palumbo , E. F. van Dishoeck , H. Linnartz

A number of recent experimental studies have shown that solid-state complex organic molecules (COMs) can form under conditions that are relevant to the CO freeze-out stage in dense clouds. In this work, we show that alcohols can be formed…

Astrophysics of Galaxies · Physics 2019-05-16 D. Qasim , G. Fedoseev , T. Lamberts , K. -J. Chuang , J. He , S. Ioppolo , J. Kästner , H. Linnartz

Complex Organic Molecules (COMs) are considered crucial molecules, since they are connected with organic chemistry, at the basis of the terrestrial life. More pragmatically, they are molecules in principle difficult to synthetize in the…

Solar and Stellar Astrophysics · Physics 2015-06-22 Ali A. Jaber , C. Ceccarelli , C. Kahane , E. Caux