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The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…

Soft Condensed Matter · Physics 2013-03-26 Aaron S. Keys , Juan P. Garrahan , David Chandler

A new graph-based order parameter is introduced for the characterization of atomistic structures. The order parameter is universal to any material/chemical system, and is transferable to all structural geometries. Three sets of data are…

Materials Science · Physics 2022-03-22 James Chapman , Nir Goldman , Brandon Wood

There exists a variety of theories of the glass transition and many more numerical models. But because the models need built-in complexity to prevent crystallization, comparisons with theory can be difficult. We study the dynamics of a…

Statistical Mechanics · Physics 2010-04-16 P. Charbonneau , A. Ikeda , J. A. van Meel , K. Miyazaki

The gauge theory of spin glasses and statistical-mechanical formulation of error-correcting codes are reviewed with an emphasis on their similarities. For the gauge theory, we explain the functional identities on dynamical autocorrelation…

Disordered Systems and Neural Networks · Physics 2009-11-07 Hidetoshi Nishimori

Using two extremely different models of glass formers in two and three dimensions we demonstrate how to encode the subtle changes in the geometric rearrangement of particles during the scenario of the glass transition. We construct a…

Statistical Mechanics · Physics 2015-05-13 Laurent Boue , Edan Lerner , Itamar Procaccia , Jacques Zylberg

Glasses usually represent the lower limit for the thermal conductivity of solids, but a fundamental understanding of lattice heat transport in amorphous materials can provide design rules to beat such a limit. Here we investigate the role…

Materials Science · Physics 2021-01-27 Nicholas W. Lundgren , Giuseppe Barbalinardo , Davide Donadio

Simple statistical agglomeration models can provide a universal link between the local structure and the glass transition temperature in network glasses. We first stress the physical features of the models and the hypothesis made, and then…

Materials Science · Physics 2009-10-31 Matthieu Micoulaut

The glass transition can simply be viewed as the point at which the viscosity of a structurally disordered liquid reaches 10^{13} Poise [1]. This definition is operational but it sidesteps fundamental controversies about the glass: Is the…

Statistical Mechanics · Physics 2017-05-10 Ludger Santen , Werner Krauth

All liquids are topologically disordered materials; however, the degree of disorder can vary as a result of internal fluctuations in structure and topology. These fluctuations depend on both the composition and temperature of the system.…

Statistical Mechanics · Physics 2018-08-15 Katelyn A. Kirchner , Seong H. Kim , John C. Mauro

Structurally stable (rough) flows on surfaces have only finitely many singularities and finitely many closed orbits, all of which are hyperbolic, and they have no trajectories joining saddle points. The violation of the last property leads…

Dynamical Systems · Mathematics 2017-06-07 Vladislav Kruglov , Dmitry Malyshev , Olga Pochinka

If quenched fast enough, a liquid is able to avoid crystallization and will remain in a metastable supercooled state down to the glass transition, with an important increase in viscosity upon further cooling. There are important differences…

Disordered Systems and Neural Networks · Physics 2016-06-01 C. Yildirim , J. -Y. Raty , M. Micoulaut

The available sites for ions in a typical disordered ionic conductor are determined. For this purpose we devised a straightforward algorithm which via cluster analysis identifies these sites from long time ionic trajectories below the glass…

Condensed Matter · Physics 2009-11-10 Heiko Lammert , Magnus Kunow , Andreas Heuer

Quantifying the evolution and complexity of materials is of importance in many areas of science and engineering, where a central open challenge is developing experimental complexity measurements to distinguish random structures from evolved…

Materials Science · Physics 2025-02-26 Keith Y Patarroyo , Abhishek Sharma , Ian Seet , Ignas Packmore , Sara I. Walker , Leroy Cronin

Within the framework of mode-coupling theory, the glass-transition scenario is investigated for a system of particles interacting with a hard-core repulsion and an additional square-shoulder soft core at larger distances. The static…

Soft Condensed Matter · Physics 2011-01-11 Matthias Sperl

Understanding the physics of glass formation remains one of the major unsolved challenges of condensed matter science. As a material solidifies into a glass, it exhibits a spectacular slowdown of the dynamics upon cooling or compression,…

Statistical Mechanics · Physics 2018-10-03 Liesbeth M. C. Janssen

Crystals and glasses exhibit fundamentally different heat conduction mechanisms: the periodicity of crystals allows for the excitation of propagating vibrational waves that carry heat, as first discussed by Peierls; in glasses, the lack of…

Materials Science · Physics 2019-09-04 Michele Simoncelli , Nicola Marzari , Francesco Mauri

The high-throughput screening of periodic inorganic solids using machine learning methods requires atomic positions to encode structural and compositional details into appropriate material descriptors. These atomic positions are not…

Materials Science · Physics 2018-12-26 Ankit Jain , Thomas Bligaard

In this paper we demonstrate that the weak temperature dependence of structure factor of supercooled liquids, a defining feature of the glass transition, is a consequence of the averaging of the scattering intensity either due to the use of…

Materials Science · Physics 2023-12-08 Charlotte F. Petersen , Peter Harrowell

The postulate of the existence of a jamming phase diagram (Liu and Nagel, Nature 396, 21 EP (1998aa)) provides a theoretical basis for the classification of a wide range of amorphous solids (colloidal, molecular and emulsion glasses,…

Soft Condensed Matter · Physics 2020-02-04 Ruru Li , Daniel Lester

We present a simple method for fast and cheap thermal analysis on supercooled glass-forming liquids. This "Thermalization Calorimetry" technique is based on monitoring the temperature and its rate of change during heating or cooling of a…