Related papers: Irreversible thermodynamics and Glansdorff-Prigogi…
Irreversibility is a critical property of non-equilibrium transport processes. An opinion has long been insisted that the entropy production rate is a Lyapunov function for all kinds of processes, that is, the principle of minimum entropy…
In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…
Glansdorff and Prigogine (1970) proposed a decomposition of the entropy production rate, which today is mostly known for Markov processes as the Hatano-Sasa approach. Their context was irreversible thermodynamics which, while ignoring…
We report on a numerical experiment performed to analyze fluctuations of the entropy production in turbulent thermal convection, a physical configuration that represents here a prototypical case of an out-of-equilibrium dissipative system.…
In the framework of irreversible thermodynamics, we study autonomous systems of reaction-diffusion equations to show how the entropy and free energy of an open and irreversible reactor depend on concentrations. To do this, we find a…
Extended irreversible thermodynamics is a theory that expands the classical framework of nonequilibrium thermodynamics by going beyond the local-equilibrium assumption. A notable example of this is the Maxwell-Cattaneo heat flux model,…
Linear, irreversible thermodynamics predicts that the entropy production rate can become negative. We demonstrate this prediction for metals under AC-driving whose conductivity is well-described by the Drude-Sommerfeld model. We then show…
In the theory of extended irreversible thermodynamics (EIT), the flux-dependent entropy function plays a key role and has a fundamental distinction from the usual flux-independent entropy function adopted by classical irreversible…
The entropy production rate is a key quantity in non-equilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress towards its full grasping. By…
Despite its simplicity, it seems to my best of knowledge that the possibly simplest approach towards deriving equations governing irreversible thermodynamics from gas-kinetic considerations within the framework of classical mechanics has…
Entropy production is a key quantity in any finite-time thermodynamic process. It is intimately tied with the fundamental laws of thermodynamics, embodying a tool to extend thermodynamic considerations all the way to non-equilibrium…
We analyze underdamped Brownian motion in non-isothermal media with quadratic, linear, and piecewise-constant temperature profiles. Exact identities for entropy production and entropy extraction are derived, addressing whether a vanishing…
Starting at the mesoscopic level with a general formulation of stochastic thermodynamics in terms of Markov jump processes, we identify the scaling conditions that ensure the emergence of a (typically nonlinear) deterministic dynamics and…
We address the emergence of entropy production in the non-equilibrium process of an open quantum system from the viewpoint of the environment. By making use of a dilation-based approach akin to Stinespring theorem, we derive an expression…
Stochastic thermodynamics provides the framework to analyze thermodynamic laws and quantities along individual trajectories of small but fully observable systems. If the observable level fails to capture all relevant degrees of freedom,…
A historical perspective is presented on thermodynamics from the pioneering contributions by Carnot and Clausius to recent advances on active matter. Non-equilibrium thermodynamics develops from the identification of the irreversible…
We establish that entropy production, which is crucial to the characterization of thermodynamic irreversibility, is obtained through a variational principle involving the Kulback-Leibler divergence. A simple application of this…
This paper presents an {\it ab initio} derivation of the expression given by irreversible thermodynamics for the rate of entropy production for different classes of diffusive processes. The first class are Lorentz gases, where…
Nonequilibrium thermodynamics of a general second-order stochastic system is investigated. We prove that at steady state, under inversion of velocities, the condition of time-reversibility over the phase space is equivalent to the…
A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…