Related papers: Nonequilibrium and Irreversibility
In the second half of the 19th century, the kinetic theory of gases has probably raised one of the most impassioned debates in the history of science. The so-called reversibility paradox around which intense polemics occurred reveals the…
We propose a new approach concerning the introduction of time-irreversibility in statistical mechanics. It is based on a transition function defined in terms of path integral and verifying a time-irreversible equation. We show first how…
The foundations of the chaotic scattering theory for transport and reaction-rate coefficients for classical many-body systems are considered here in some detail. The thermodynamic formalism of Sinai, Bowen, and Ruelle is employed to obtain…
A heuristic generalization of the Boltzmann-Gibbs microcanonical entropy is proposed, able to describe meta-equilibrium features and evolution of macroscopic systems. Despite its simple-minded derivation, such a function of "collective…
The article sets forth comprehensive basics of thermodynamics of chemical equilibrium as balance of the thermodynamic forces. Based on the linear equations of irreversible thermodynamics, De Donder definition of the thermodynamic force, and…
The heat theorem (i.e. the second law of thermodynamics or the existence of entropy) is a manifestation of a general property of hamiltonian mechanics and of the ergodic Hypothesis. In nonequilibrium thermodynamics of stationary states the…
The approach to the analysis of the dynamic of non-equilibrium open systems within the framework of the laws of classical mechanics on the example a hard-disks is offered. This approach was based on Hamilton and Liouville generalized…
The paper discusses the main ideas of the chaos theory and presents mainly the importance of the nonlinearities in the mathematical models. Chaos and order are apparently two opposite terms. The fact that in chaos can be found a certain…
A variant of continuous nonequilibrium thermodynamic theory based on the postulate of the scale invariance of the local relation between generalized fluxes and forces has been proposed. This single postulate replaces the assumptions on…
The non-equilibrium self-consistent generalized Langevin equation theory of irreversible processes in liquids is extended to describe the positional and orientational thermal fluctuations of the instantaneous local concentration profile…
Bridging equilibrium and nonequilibrium statistical physics attracts sustained interest. Hallmarks of nonequilibrium systems include a breakdown of detailed balance, and an absence of a priori potential function corresponding to the…
The time irreversibility problem is the dichotomy of the reversible microscopic dynamics and the irreversible macroscopic physics. This problem was considered by Boltzmann, Poincar\'e, Bogolyubov and many other authors and though some…
Fluctuations of observables as functions of time, or "fluctuation patterns", are studied in a chaotic microscopically reversible system that has irreversibly reached a nonequilibrium stationary state. Supposing that during a certain, long…
We discuss the fluctuation properties of equilibrium chaotic systems with constraints such as iso-kinetic and Nos\'e-Hoover thermostats. Although the dynamics of these systems does not typically preserve phase-space volumes, the average…
Statistical equilibrium models of coherent structures in two-dimensional and barotropic quasi-geostrophic turbulence are formulated using canonical and microcanonical ensembles, and the equivalence or nonequivalence of ensembles is…
We use a recently proved fluctuation theorem for the currents to develop the response theory of nonequilibrium phenomena. In this framework, expressions for the response coefficients of the currents at arbitrary orders in the thermodynamic…
We provide a general macrostatistical formulation of nonequilibrium steady states of reservoir driven quantum systems. This formulation is centred on the large scale properties of the locally conserved hydrodynamical observables, and our…
We consider the general response theory proposed by Ruelle for describing the impact of small perturbations to the non-equilibrium steady states resulting from Axiom A dynamical systems. We show that the causality of the response functions…
How is the irreversibility of a high-dimensional chaotic system controlled by the heterogeneity in the non-reciprocal interactions among its elements? In this paper, we address this question using a stochastic model of random recurrent…
We numerically study a billiard system with a time-dependent force, and our results suggest the existence of a limitation on possible transitions between steady states in Hamiltonian chaos, in analogy to the limitation on transitions…