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The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

A pedagogical derivation of statistical mechanics from quantum mechanics is provided, by means of open quantum systems. Besides, a new definition of Boltzmann entropy for a quantum closed system is also given to count microstates in a way…

High Energy Physics - Theory · Physics 2015-04-08 Yu-Lei Feng , Yi-Xin Chen

We introduce a variant of the asymmetric random average process with continuous state variables where the maximal transport is restricted by a cutoff. For periodic boundary conditions, we show the existence of a phase transition between a…

Statistical Mechanics · Physics 2009-11-07 Frank Zielen , Andreas Schadschneider

Stochastic Thermodynamics (ST) extends the notions of classical thermodynamics to trajectories taken from a nonequilibrium ensemble. This extension yields a simple approach to fluctuation relations in small systems. Multiple time- and…

Statistical Mechanics · Physics 2012-10-19 Bernhard Altaner

The R\'enyi entanglement entropy is calculated exactly for mode-partitioned isolated systems such as the two-mode squeezed state and the multi-mode Silbey-Harris polaron ansatz state. Effective thermodynamic descriptions of the correlated…

Quantum Physics · Physics 2015-12-24 King Karl R. Seroje , Rafael S. dela Rosa , Francis N. C. Paraan

Understanding how macroscopic systems exhibit irreversible thermal behavior has been a long-standing challenge, first brought to prominence by Boltzmann. Recent advances have established rigorous conditions for isolated quantum systems to…

Quantum Physics · Physics 2025-04-10 M. R. Passos , Thiago R. de Oliveira

Sampling the Boltzmann distribution using forces that violate detailed balance can be faster than with the equilibrium evolution, but the acceleration depends on the nature of the nonequilibrium drive and the physical situation. Here, we…

Soft Condensed Matter · Physics 2023-12-20 Federico Ghimenti , Ludovic Berthier , Grzegorz Szamel , Frédéric van Wijland

Although coarse-grained models have been widely used to explain exotic phenomena in complex fluids, such as droplet formation in living cells, these conventional approaches often fail to capture the intricate microscopic degrees of freedom…

Soft Condensed Matter · Physics 2025-06-13 Masanari Shimada , Tetsuya J. Kobayashi

Identifying dissipation is essential for understanding the physical mechanisms underlying nonequilibrium processes. {In living systems, for example, the dissipation is directly related to the hydrolysis of fuel molecules such as adenosine…

Statistical Mechanics · Physics 2019-09-02 Ignacio A. Martínez , Gili Bisker , Jordan M. Horowitz , Juan M. R. Parrondo

We demonstrate that in the space of distributions operated on by lattice Boltzmann methods that there exists a vicinity of the equilibrium where collisions with entropy balance are possible and, at the same time, there exist an area of…

Computational Physics · Physics 2013-08-05 A. N. Gorban , D. Packwood

We propose a formal extension of thermodynamics and kinetic theories to a larger class of entropy functionals. Kinetic equations associated to Boltzmann, Fermi, Bose and Tsallis entropies are recovered as a special case. This formalism…

Statistical Mechanics · Physics 2015-06-24 Pierre-Henri Chavanis

Traditionally, phase transitions are defined in the thermodynamic limit only. We propose a new formulation of equilibrium thermo-dynamics that is based entirely on mechanics and reflects just the {\em geometry and topology} of the N-body…

Statistical Mechanics · Physics 2009-10-31 D. H. E. Gross

Considering a broad class of steady-state nonequilibrium systems for which some additive quantities are conserved by the dynamics, we introduce from a statistical approach intensive thermodynamic parameters (ITPs) conjugated to the…

Statistical Mechanics · Physics 2007-05-23 Eric Bertin , Kirsten Martens , Olivier Dauchot , Michel Droz

The selection of an equilibrium state by maximising the entropy of a system, subject to certain constraints, is often powerfully motivated as an exercise in logical inference, a procedure where conclusions are reached on the basis of…

Statistical Mechanics · Physics 2015-12-03 Ian J. Ford

We propose a variational formulation for the nonequilibrium thermodynamics of discrete open systems, i.e., discrete systems which can exchange mass and heat with the exterior. Our approach is based on a general variational formulation for…

Mathematical Physics · Physics 2018-12-05 François Gay-Balmaz , Hiroaki Yoshimura

An unified thermodynamical framework based in the use of a generalized Massieu-Planck thermodynamic potential is proposed and a new formulation of Boltzmann-Gibbs Statistical Mechanics is established. Under this philosophy a generalization…

Mathematical Physics · Physics 2007-05-23 V. Garcia-Morales , J. Pellicer

We consider dynamical systems evolving near an equilibrium statistical state where the interest is in modelling long term behavior that is consistent with thermodynamic constraints. We adjust the distribution using an entropy-optimizing…

Fluid Dynamics · Physics 2014-11-25 Keith Myerscough , Jason Frank , Benedict Leimkuhler

We use the work done on and the heat removed from a system to maintain it in a nonequilibrium steady state for a thermodynamic-like description of such a system as well as of its fluctuations. Based on a generalized Onsager-Machlup theory…

Statistical Mechanics · Physics 2008-02-10 Tooru Taniguchi , E. G. D. Cohen

The question of characterization of the degree of non-equilibrium activity in active matter systems is studied in the context of a stochastic microswimmer model driven by a chemical cycle. The resulting dynamical properties and entropy…

Statistical Mechanics · Physics 2024-05-27 Michalis Chatzittofi , Jaime Agudo-Canalejo , Ramin Golestanian

Open quantum systems are studied from the thermodynamical point of view unifying the principle of maximum informational entropy and the hypothesis of relaxation times hierarchy. The result of the unification is a non-Markovian and local in…

Quantum Physics · Physics 2014-11-24 Vitalii Semin , Francesco Petruccione