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Methods which aim at universal applicability must be able to describe both weak and strong electronic correlation with equal facility. Such methods are in short supply. The combination of symmetry projection for strong correlation and…

Chemical Physics · Physics 2020-05-14 Yiheng Qiu , Thomas M. Henderson , Jinmo Zhao , Gustavo E. Scuseria

We study methods for efficient preparation of approximate ground states of $SU(3)$ lattice gauge theory on quantum hardware. Working in a variant of the electric basis, we introduce a refinement of the irrep truncation based on the energy…

High Energy Physics - Lattice · Physics 2025-10-07 Praveen Balaji , Cianan Conefrey-Shinozaki , Patrick Draper , Jason K. Elhaderi , Drishti Gupta , Luis Hidalgo , Andrew Lytle

We have studied electron correlations in the doped two-dimensional (2D) Hubbard model by using the coupled-cluster method (CCM) to investigate whether or not the method can be applied to correct the independent particle approximations…

Strongly Correlated Electrons · Physics 2009-10-31 Yoshihiro Asai , Hideki Katagiri

We derive and implement a new way of solving coupled cluster equations with lower computational scaling. Our method is based on decomposition of both amplitudes and two electron integrals, using a combination of tensor hypercontraction and…

Chemical Physics · Physics 2020-05-14 Roman Schutski , Jinmo Zhao , Thomas M. Henderson , Gustavo E. Scuseria

We develop a coupled-cluster theory for bosonic mixtures of binary species in external traps, providing a promising theoretical approach to demonstrate highly accurately the many-body physics of mixtures of Bose-Einstein condensates. The…

Quantum Gases · Physics 2024-02-01 Anal Bhowmik , Ofir E. Alon

We derive a perturbation theory (PT) for the Lorentz boost operator in the space of two-nucleon wave functions. The latter is expressed in terms of the nucleon-nucleon ($NN$) potentials, developed so far in great detail for their use in the…

Nuclear Theory · Physics 2025-09-15 Alexander N. Kvinikhidze , Hagop Sazdjian , Boris Blankleider

We present a generalization of the recently proposed variational cluster perturbation theory to extended Hubbard models at half filling with repulsive nearest neighbor interaction. The method takes into account short-range correlations…

Strongly Correlated Electrons · Physics 2009-11-10 M. Aichhorn , H. G. Evertz , W. von der Linden , M. Potthoff

We use perturbed relativistic coupled-cluster (PRCC) theory to compute the electric dipole polarizabilities $\alpha$ of Zn, Cd and Hg. The computations are done using the Dirac-Coulomb-Breit Hamiltonian with Uehling potential to incorporate…

Atomic Physics · Physics 2015-05-20 S. Chattopadhyay , B. K. Mani , D. Angom

Statistical inference for stochastic block models typically relies on the spectrum of the normalized adjacency matrix $\A^*$. In practice, the true probability matrix $\mathbf{B}$ is unknown and must be replaced by a plug-in estimator…

Methodology · Statistics 2026-04-09 Jianwei Hu , Ding Chen , Ji Zhu

A new method that accurately describes strongly correlated states and captures dynamical correlation is presented. It is derived as a modification of coupled-cluster theory with single and double excitations (CCSD) through consideration of…

Chemical Physics · Physics 2013-07-15 Daniel Kats , Frederick R. Manby

In classical computational chemistry, the coupled-cluster ansatz is one of the most commonly used $ab~initio$ methods, which is critically limited by its non-unitary nature. The unitary modification as an ideal solution to the problem is,…

Quantum Physics · Physics 2017-03-01 Yangchao Shen , Xiang Zhang , Shuaining Zhang , Jing-Ning Zhang , Man-Hong Yung , Kihwan Kim

Recent progress towards universal machine-learned interatomic potentials holds considerable promise for materials discovery. Yet the accuracy of these potentials for predicting phase stability may still be limited. In contrast, cluster…

Materials Science · Physics 2024-05-03 A. Dana , L. Mu , S. Gelin , S. B. Sinnott , I. Dabo

We present the working equations for a reduced-scaling method of evaluating the perturbative triples (T) energy in coupled-cluster theory, through the tensor hypercontraction (THC) of the triples amplitudes ($t_{ijk}^{abc}$). Through our…

Chemical Physics · Physics 2024-06-12 Andy Jiang , Justin M. Turney , Henry F. Schaefer

Hyperfine constants and anomalies of ground as well as few low lying excited states of $^{113,115,117}$In III are studied with highly correlated relativistic coupled-cluster theory. The ground state hyperfine splitting of $^{115}$In III is…

Atomic Physics · Physics 2015-06-18 Sourav Roy , Narendra Nath Dutta , Sonjoy Majumder

The work presents a simple formalism which proposes an estimate of the ground state energy from a single reference function. It is based on a perturbative expansion but leads to non linear coupled equations. It can be viewed as well as a…

Strongly Correlated Electrons · Physics 2007-05-23 Mohamad Al Hajj , Jean-Paul Malrieu

An efficiency of the Tucker decomposition of amplitude tensors within the single-reference relativistic coupled cluster method with single and double excitations (RCCSD) was studied in a series of benchmark calculations for (AuCl)$_n$…

Computational Physics · Physics 2025-07-29 Alexander V. Oleynichenko , Artem S. Rumiantsev , Andrei Zaitsevskii , Ephraim Eliav

Physics of high-$T_c$ superconducting cuprates is obscured by the effect of strong electronic correlations. One way to overcome the problem is to seek for an exact solution at least within the small cluster and expand it to the whole…

Strongly Correlated Electrons · Physics 2023-07-19 V. I. Kuz'min , S. V. Nikolaev , M. M. Korshunov , S. G. Ovchinnikov

We report a complete implementation of the coupled-cluster method with single, double, and triple excitations (CCSDT) where tensor decompositions are used to reduce its scaling and overall computational costs. For the decomposition of the…

Chemical Physics · Physics 2020-02-20 Michał Lesiuk

The quadratic computational cost of the self-attention mechanism is a primary challenge in scaling Transformer models. While attention sparsity is widely studied as a technique to improve computational efficiency, it is almost universally…

Computation and Language · Computer Science 2025-08-11 Sagar Gandhi , Vishal Gandhi

Coupled cluster theory is the method of choice for weakly correlated systems. But in the strongly correlated regime, it faces a symmetry dilemma, where it either completely fails to describe the system, or has to artificially break certain…

Chemical Physics · Physics 2020-05-14 Yiheng Qiu , Thomas M. Henderson , Jinmo Zhao , Gustavo E. Scuseria