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We present a novel theory and implementation for computing coupled electronic and quantal nuclear subsystems on a single potential energy surface, moving beyond the standard Born-Oppenheimer (BO) separation of nuclei and electrons. We…

Chemical Physics · Physics 2021-11-15 Ziyong Chen , Jun Yang

We perform an uncertainty estimate of quadrupole moments and B(E2) transition rates that inform nuclear collectivity. In particular, we study the low-lying states of 6Li and 12C using the ab initio symmetry-adapted no-core shell model. For…

We discuss the accuracy of mass models for extrapolating to very asymmetric nuclei and the impact of such extrapolations on the predictions of isotopic observables in multifragmentation. We obtain improved mass predictions by incorporating…

Nuclear Experiment · Physics 2009-11-10 S. R. Souza , P. Danielewicz , S. Das Gupta , R. Donangelo , W. A. Friedman , W. G. Lynch , W. P. Tan , M. B. Tsang

Nuclei with an octupole deformation have a non-zero electric octupole moment, electric dipole moment (EDM), Schiff moment and magnetic quadrupole moment (MQM) in the intrinsic frame which rotates with the nucleus. In a state with definite…

High Energy Physics - Phenomenology · Physics 2022-06-29 V. V. Flambaum , A. J. Mansour

Machine learning methods have nowadays become easy-to-use tools for constructing high-dimensional interatomic potentials with ab initio accuracy. Although machine learned interatomic potentials are generally orders of magnitude faster than…

Computational Physics · Physics 2021-02-24 Yaolong Zhang , Ce Hu , Bin Jiang

Electron correlation effects are essential for an accurate ab initio description of molecules. A quantitative a priori knowledge of the single- or multi-reference nature of electronic structures as well as of the dominant contributions to…

Quantum Physics · Physics 2012-12-18 Katharina Boguslawski , Paweł Tecmer , Örs Legeza , Markus Reiher

Precision measurements of $\beta$-decay observables offer the possibility to search for deviations from the Standard Model. A possible discovery of such deviations requires accompanying first-principles calculations. Here we compute the…

Statistical learning algorithms are finding more and more applications in science and technology. Atomic-scale modeling is no exception, with machine learning becoming commonplace as a tool to predict energy, forces and properties of…

Chemical Physics · Physics 2020-12-09 Félix Musil , Michele Ceriotti

The molecular dipole moment ($\boldsymbol{\mu}$) is a central quantity in chemistry. It is essential in predicting infrared and sum-frequency generation spectra, as well as induction and long-range electrostatic interactions. Furthermore,…

Chemical Physics · Physics 2020-10-14 Max Veit , David M. Wilkins , Yang Yang , Robert A. DiStasio , Michele Ceriotti

Electronic coherences are key to understanding and controlling photo-induced molecular transformations. We identify a crucial quantum-mechanical feature of electron-nuclear correlation, the projected nuclear quantum momenta, essential to…

Chemical Physics · Physics 2024-11-13 Evaristo Villaseco Arribas , Neepa T. Maitra

The electric quadrupole moment of $^{49}$Sc was measured by collinear laser spectroscopy at CERN-ISOLDE to be $Q_{\rm s}=-0.159(8)$ $e$b, and a nearly tenfold improvement in precision was reached for the electromagnetic moments of…

Neutral molecules with sufficiently large dipole moments can bind electrons in diffuse nonvalence orbitals with most of their charge density far from the nuclei, forming so-called dipole-bound anions. Because long-range correlation effects…

Chemical Physics · Physics 2018-10-30 Hongxia Hao , James Shee , Shiv Upadhyay , Can Ataca , Kenneth D. Jordan , Brenda M. Rubenstein

We develop a framework that allows to calculate integrated properties of the nuclear response from first principles. Using the ab initio in-medium similarity renormalization group (IMSRG), we calculate the expectation values of moment…

Nuclear Theory · Physics 2025-11-10 Andrea Porro , Achim Schwenk , Alexander Tichai

Neutron stars are compact objects of large interest in the nuclear astrophysics community. The extreme conditions present in such systems impose big challenges to our current microscopic models of nuclear structure. Equation of states (EoS)…

Nuclear Theory · Physics 2022-03-01 Ronaldo V. Lobato , Emanuel V. Chimanski , Carlos A. Bertulani

The exploration of nuclear mass or binding energy, a fundamental property of atomic nuclei, remains at the forefront of nuclear physics research due to limitations in experimental studies and uncertainties in model calculations,…

Nuclear Theory · Physics 2024-06-26 Esra Yüksel , Derya Soydaner , Hüseyin Bahtiyar

Recently supervised machine learning has been ascending in providing new predictive approaches for chemical, biological and materials sciences applications. In this Perspective we focus on the interplay of machine learning algorithm with…

Machine-learning of atomic-scale properties amounts to extracting correlations between structure, composition and the quantity that one wants to predict. Representing the input structure in a way that best reflects such correlations makes…

Chemical Physics · Physics 2021-02-02 Michael J. Willatt , Félix Musil , Michele Ceriotti

Machine learning has recently emerged as a promising approach for studying complex phenomena characterized by rich datasets. In particular, data-centric approaches lend to the possibility of automatically discovering structures in…

This review presents some of the challenges in constructing models of atomic nuclei starting from theoretical descriptions of the strong interaction between nucleons. The focus is on statistical computing and methods for analyzing the link…

Nuclear Theory · Physics 2019-12-06 Andreas Ekström

Data-driven techniques are increasingly used to replace electronic-structure calculations of matter. In this context, a relevant question is whether machine learning (ML) should be applied directly to predict the desired properties or be…

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