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The study of light-matter interaction has seen a resurgence in recent years, stimulated by highly controllable, precise, and modular experiments in cavity quantum electrodynamics (QED). The achievement of strong coupling, where the coupling…

We introduce crystal polaritons, hybrid excitations formed when the collective excitations of a periodic quantum-emitter array strongly couple to the resonant Bloch modes of a metasurface. This realizes a cavity-QED platform in which…

Since the photon box gedanken experiments of several of the founding fathers of modern physics, considerable progress has been made in differentiating the quantum and classical worlds. In this pursuit, the cavity as an open quantum system…

Quantum Physics · Physics 2014-12-02 Nathan D. Poulin

Strong light-matter coupling gives rise to polaritons - hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article surveys the main architectures…

Collective light-matter interactions have been used to control chemistry and energy transfer, yet accessible approaches that combine ab initio methodology with large many-body quantum optical systems are missing due to the fast increase in…

Quantum Physics · Physics 2024-08-27 Frieder Lindel , Dominik Lentrodt , Stefan Yoshi Buhmann , Christian Schäfer

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

Chemical Physics · Physics 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

Recent observations of gravitational waves from binary mergers of black holes or neutron stars and the rapid development of ultra-intense lasers lead strong field physics to a frontier of new physics in the 21st century. Strong gravity…

General Relativity and Quantum Cosmology · Physics 2019-06-03 Sang Pyo Kim

Polaritonic chemistry is an interdisciplinary emerging field that presents several challenges and opportunities in chemistry, physics, and engineering. A systematic review of polaritonic response theory is presented, following a chemical…

Chemical Physics · Physics 2023-05-08 Matteo Castagnola , Rosario R. Riso , Alberto Barlini , Enrico Ronca , Henrik Koch

Strong light-matter interactions in both the single-emitter and collective strong coupling regimes attract significant attention due to emerging quantum and nonlinear optics applications, as well as opportunities for modifying…

Mesoscale and Nanoscale Physics · Physics 2019-09-11 Tuomas P. Rossi , Timur Shegai , Paul Erhart , Tomasz J. Antosiewicz

We investigate the coupling of different quantum-embedding approaches with a third molecular-mechanics layer, which can be either polarizable or non-polarizable. In particular, such a coupling is discussed for the multilevel families of…

Chemical Physics · Physics 2020-12-11 Linda Goletto , Tommaso Giovannini , Sarai D. Folkestad , Henrik Koch

Introducing low-energy effective Hamiltonians is usual to grasp most correlations in quantum many-body problems. For instance, such effective Hamiltonians can be treated at the mean-field level to reproduce some physical properties of…

Quantum Gases · Physics 2025-01-09 Raphaël Photopoulos , Antoine Boulet

Recently we have proposed an effective Hartree-Fock (EHF) theory for the electrons of the muonic molecules that is formally equivalent to the HF theory within the context of the Nuclear-Electronic Orbital theory [Phys. Chem. Chem. Phys. 20,…

Atomic and Molecular Clusters · Physics 2018-06-21 Mohammad Goli , Shant Shahbazian

In the Horndeski's most general scalar-tensor theories the equations of scalar density perturbations are derived in the presence of non-relativistic matter minimally coupled to gravity. Under a quasi-static approximation on sub-horizon…

General Relativity and Quantum Cosmology · Physics 2015-05-30 Antonio De Felice , Tsutomu Kobayashi , Shinji Tsujikawa

We present a formulation of Laplace-transformed atomic orbital-based second-order M{\o}ller-Plesset perturbation theory (MP2) energies for two-component Hamiltonians in the Kramers-restricted formalism. This low-order scaling technique can…

Chemical Physics · Physics 2017-05-18 Benjamin Helmich-Paris , Michal Repisky , Lucas Visscher

In this work, we develop a theoretical description of the collective behavior of interacting dipolar planar rotors by using time independent perturbation theory and a small angle quadratic approximation. The ground state properties for both…

Chemical Physics · Physics 2026-04-21 Estêvão V. B. de Oliveira , Muhammad Shaeer Moeed , Pierre-Nicholas Roy

The `XIIIth Quark Confinement and the Hadron Spectrum' conference (Confinement 2018) contained a `Round Table Discussion' on the status of the determinations of the strong coupling $\alpha_s(m_Z)$ as well as prospects for future…

High Energy Physics - Phenomenology · Physics 2018-12-17 Antonio Pich , Juan Rojo , Rainer Sommer , Antonio Vairo

Conventional weak-coupling Rayleigh-Schr\"odinger perturbation theory suffers from problems that arise from resonant coupling of successive orders in the perturbation series. Multiple-scale analysis, a powerful and sophisticated…

High Energy Physics - Theory · Physics 2009-10-30 Carl M. Bender , Luis M. A. Bettencourt

In strongly coupled field theories, perturbation theory cannot be employed to study the low-energy spectrum. Thus, non-perturbative techniques are required. We employ the variational method, a rigorous, non-perturbative approach which…

High Energy Physics - Lattice · Physics 2024-09-27 M. Rovira , A. Parreño , R. J. Perry

In computational chemistry of molecular materials, strong static correlation effects appear when electronic states, often involving the ground state, become quasi-degenerate, as occurs, for example, in bond-breaking processes. Such…

Chemical Physics · Physics 2026-03-20 Braden M. Weight , Zheng Pei , Sergei Tretiak

We consider a one-dimensional effective quantum electrodynamics (QED) model of the relativistic hydrogen-like atom using delta-potential interactions. We discuss the general exact theory and the Hartree-Fock approximation. The present…

Mathematical Physics · Physics 2023-06-27 Timothée Audinet , Julien Toulouse