Related papers: Photokinetics of Photothermal Reactions
Based on our experience in kinetic modeling of coupled multiple metabolic pathways we propose a generic rate equation for the dynamical modeling of metabolic kinetics. Its symmetric form makes the kinetic parameters (or functions) easy to…
Traditional mathematical models of photosynthesis are based on mass action kinetics of light reactions. This approach requires the modeller to enumerate all the possible state combinations of the modelled chemical species. This leads to…
Thermodynamics is accepted as a universal truth, encompassing all macroscopic objects. Therefore, it is surprising to find that, within our current understanding, the photovoltaic effect has so far eluded the first and second laws of…
In this work, the rate law for inhomogeneous concentration distributions has been formulated, by applying spatial integration over the products of species concentrations. Reaction rates for typical reactions have been investigated by…
Recent experiments claimed that the enhancement of catalytic reaction rates occurs via the reduction of activation barriers driven by non-equilibrium (``hot'') electrons in plasmonic metal nanoparticles. These experiments place plasmonic…
Current formulations of nonequilibrium thermodynamics of open chemical reaction networks only consider chemostats as free-energy sources sustaining nonequilibrium behaviours. Here, we extend the theory to include incoherent light as a…
This paper studies a mathematical formalism of nonequilibrium thermodynamics for chemical reaction models with $N$ species, $M$ reactions, and general rate law. We establish a mathematical basis for J. W. Gibbs' macroscopic chemical…
The illumination of catalytic surfaces with a continuous or pulsed stream of photons dynamically modulates surface chemistry for faster rates, higher conversion, or product selectivity control. To establish fundamental principles of dynamic…
There is current interest in developing photoactive materials that deform on illumination and can thus be used for photomechanical actuation. This is attractive since it can be affected at a distance, different frequencies can be used to…
Harnessing strong light-matter interactions to control chemical reactions in confined electromagnetic fields offers a promising route toward deepening our understanding of chemical dynamics at the collective quantum-mechanical level, with…
The kinetics of the photochromic reaction of oxygen-containing rare-earth hydrides is commonly described by an exponential function assuming a single-step process. In this paper, we elaborate on the origin of the photochromic effect in…
Radiation reaction (but, more generally, fluctuations and dissipation) occurs when a system interacts with a heat bath, a particular case being the interaction of an electron with the radiation field. We have developed a general theory for…
Photoluminescence (PL) is a fundamental light-matter interaction in which absorbed photons are re-emitted, playing a key role in science and engineering. It is commonly modeled by introducing a non-zero chemical potential into Planck's law…
Photoluminescence (PL) is a light matter quantum interaction associated with the chemical potential of light formulated by the Generalized Planck's law. Without knowing the inherent temperature dependence of chemical potential, the…
Mathematical models of photosynthesis-irradiance relationships in phytoplankton are used to compute integrated water-column photosynthetic rates and predict primary production. Models typically ignore an important phenomenon observed in…
Reliable photo-nuclear reaction rates at the stellar conditions are essential to understand the origin of the heavy stable neutron-deficient isotopes between $^{74}$Se and $^{196}$Hg-p-nuclei, however, many reaction rates of relevance still…
We summarize and to discuss briefly the geometrical practice of modeling attitudes so far popular in treating reaction kinetics of solid-state processes. The model equations existing in the literature have been explored to describe the…
All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory which accounts for interactions between chemical species within a…
Reaction-diffusion processes play an important role in a variety of physical, chemical, and biological systems. Conventionally, the kinetics of these processes are described by the law of mass action. However, there are various cases where…
The methodology for modeling grain-surface chemistry has been greatly improved by taking into account the grain size and fluctuation effects. However, the reaction rate coefficients currently used in all practical models of gas-grain…