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The drying of colloidal suspensions leads to complex deposition patterns, accompanied by instabilities such as cracking and delamination. In this study, we experimentally investigate the coupled influence of particle surface charge and…

Soft Condensed Matter · Physics 2026-01-27 A. Madhav Sai Kumar , A. Hari Govindha , Ranajit Mondal , Kirti Chandra Sahu

When a drop containing colloidal particles evaporates on a surface, a circular stain made of these particles is often observed due to an internal flow toward the contact line. To hinder this effect, several approaches have been proposed…

Soft Condensed Matter · Physics 2016-01-06 François Boulogne , François Ingremeau , Julien Dervaux , Laurent Limat , Howard A. Stone

Spilling tea or coffee leads to a tell-tale circular stain after the droplet dries, known as the "coffee ring effect". The evaporation of suspension droplets is a complex physical process, and predicting and controlling the particle deposit…

In this work, we unravel the role of surface properties of colloidal particles on the formation of supraparticles (clusters of colloidal particles) in a colloidal Ouzo droplet. Self-lubricating colloidal Ouzo droplets are an efficient and…

Effects of substrate temperature, substrate wettability and particles concentration are experimentally investigated for evaporation of a sessile water droplet containing colloidal particles. Time-varying droplet shapes and temperature of…

Fluid Dynamics · Physics 2016-10-21 Nagesh D. Patil , Prathamesh G. Bange , Rajneesh Bhardwaj , Atul Sharma

-- A scientific hurdle in manufacturing solid films by drying colloidal layers is preventing them from fracturing. This paper examines how the drying rate of colloidal liquids influences the particle packing at the nanoscale in correlation…

Soft Condensed Matter · Physics 2016-02-29 Keyvan Piroird , Véronique Lazarus , Georges Gauthier , Arnaud Lesaine , Daniel Bonamy , Cindy Rountree

We demonstrate a novel route of spatially organizing the colloid arrangements on the polymer-grafted substrate by use of self-consistent field and density functional theories. We find that grafting of polymers onto a substrate can…

Soft Condensed Matter · Physics 2007-05-23 Kang Chen , Yu-qiang Ma

Understanding flow patterns and coupled transport phenomena during evaporation of droplets loaded with colloidal particles is central to design technical applications such as organizing proteins/DNA on a solid surface. We review recent…

Soft Condensed Matter · Physics 2019-04-16 Nagesh D. Patil , Rajneesh Bhardwaj

Substrate wettability alteration induced control over crack formation process in thin colloidal films has been addressed in the present study. Colloidal nanosuspension (53nm, mean particle diameter) droplets have been subjected to natural…

We consider the dynamic wetting and dewetting processes of films and droplets of complex liquids on planar surfaces, focusing on the case of colloidal suspensions, where the particle interactions can be sufficiently attractive to cause…

Fluid Dynamics · Physics 2024-11-20 J. Zhang , D. N. Sibley , D. Tseluiko , A. J. Archer

The role of particle shape in evaporation-induced auto-stratification in dispersed colloidal suspensions is explored with molecular dynamics simulations of mixtures of solid spheres, aspherical particles, and hollow spheres. A unified…

Soft Condensed Matter · Physics 2025-02-25 Binghan Liu , Gary S. Grest , Shengfeng Cheng

We computed the self-organisation process of a monodisperse collection of spherical micrometric particles trapped in a two-dimensional (2D) thin liquid film isothermally dried on a chemically inert substrate. The substrate is either flat or…

Soft Condensed Matter · Physics 2009-11-11 F. Lallet , N. Olivi-Tran

We investigate deposit patterns and associated morphology formed after the evaporation of an aqueous droplet containing mono- and bi-dispersed colloidal particles. In particular, the combined effect of substrate heating and particle…

Fluid Dynamics · Physics 2018-07-11 Nagesh D. Patil , Rajneesh Bhardwaj , Atul Sharma

Electrophoretic deposition is a method of choice for generating coatings thanks to its ease of implementation and its ability to produce coatings of relatively large thicknesses in a single step process. While this process also benefits…

Materials Science · Physics 2026-05-01 Rémi Martin , Sandrine Duluard , Céline Merlet

Drying suspensions often leave behind complex patterns of particulates, as might be seen in the coffee stains on a table. Here we consider the dynamics of periodic band or uniform solid film formation on a vertical plate suspended partially…

Soft Condensed Matter · Physics 2014-12-05 C. Nadir Kaplan , Ning Wu , Shreyas Mandre , Joanna Aizenberg , L. Mahadevan

Complex colloidal cluster morphologies are desirable for the fabrication of advanced materials, such as photonic crystals and meta-materials, and can be formed through evaporation-driven packing. By coupling lattice Boltzmann and discrete…

Soft Condensed Matter · Physics 2026-05-07 Junyu Yang , Abhinav Naga , Xitong Zhang , Halim Kusumaatmaja

We explore the influence of particle shape on the behavior of evaporating drops. A first set of experiments discovered that particle shape modifies particle deposition after drying. For sessile drops, spheres are deposited in a ring-like…

Soft Condensed Matter · Physics 2013-08-13 Peter J. Yunker , Tim Still , A. G. Yodh

Dip-coating consists in withdrawing a substrate from a bath to coat it with a thin liquid layer. This process is well-understood for homogeneous fluids, but heterogeneities such as particles dispersed in the liquid lead to more complex…

Soft Condensed Matter · Physics 2022-03-02 Deok-Hoon Jeong , Michael Ka Ho Lee , Virgile Thiévenaz , Martin Z. Bazant , A. Sauret

The phase behavior of colloidal particles embedded in a binary fluid is influenced by wetting layers surrounding each particle. The free energy of the fluid film depends on its morphology, i.e., on size, shape and connectivity. Under rather…

Soft Condensed Matter · Physics 2007-05-23 Uwe Brodatzki , Klaus Mecke

The process of colloidal drying gives way to particle self-assembly in numerous elds including photonics or biotechnology. Yet, the mechanisms and conditions driving the nal particle arrangement in dry colloidal layers remain elusive. Here,…

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