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The electronic band structures of two-dimensional materials are significantly different from those of their bulk counterparts, due to quantum confinement and strong modifications of electronic screening. An accurate determination of…

Mesoscale and Nanoscale Physics · Physics 2020-07-08 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

Coulomb interactions that occur in electronic structure calculations are correlated by allowing basis function components of the interacting densities to polarize, thereby reducing the magnitude of the interaction. Exchange integrals of…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

The multipole expansion is a key tool in the study of light-matter interactions. All the information about the radiation of and coupling to electromagnetic fields of a given charge-density distribution is condensed into few numbers: The…

Optics · Physics 2018-05-08 R. Alaee , C. Rockstuhl , I. Fernandez-Corbaton

We extend density matrix embedding theory to periodic systems, resulting in an electronic band structure method for solid-state materials. The electron correlation can be captured by means of a local impurity model using various choices of…

Strongly Correlated Electrons · Physics 2019-09-27 Hung Q. Pham , Matthew R. Hermes , Laura Gagliardi

With the aim of describing real-time electron dynamics, we introduce an adiabatic approximation for the equation of motion of the one-body reduced-density matrix (one-matrix). The eigenvalues of the one-matrix, which represent the…

Strongly Correlated Electrons · Physics 2012-09-18 Ryan Requist , Oleg Pankratov

We investigate truncation schemes to reduce the computational cost of calculating correlations by the generator coordinate method based on mean-field wave functions. As our test nuclei, we take examples for which accurate calculations are…

Nuclear Theory · Physics 2009-11-10 M. Bender , G. Bertsch , P. -H. Heenen

We give a detailed description of a recently proposed first principles approach to the electronic structure of strongly correlated materials. The method combines the GW approximation with dynamical mean field theory. It is designed to…

Strongly Correlated Electrons · Physics 2007-05-23 Ferdi Aryasetiawan , Silke Biermann , Antoine Georges

The dipole approximation is employed to describe interactions between atoms and radiation. It essentially consists of neglecting the spatial variation of the external field over the atom. Heuristically, this is justified by arguing that the…

Mathematical Physics · Physics 2018-04-04 Lea Boßmann , Robert Grummt , Martin Kolb

This work identifies geometric effects on dynamics due to nonadiabatic couplings in Born Oppenheimer systems and provides a systematic method for deriving corrections to mixed quantum-classical methods. Specifically, an exact path integral…

Chemical Physics · Physics 2007-05-23 Vinod Krishna

We analyze the entanglement between electronic and nuclear motions in molecular wave functions, by using different widely used ansatzes in molecular Hamiltonian models (H$^+_2$ in 1D and the Shin-Metiu model); namely, i) Born-Oppenheimer…

Quantum Physics · Physics 2025-11-13 Juan F. P. Mosquera , Jose Luis Sanz-Vicario

In this work, we present the first implementation of the transcorrelated electronic Hamiltonian in an optimization procedure for matrix product states by the density matrix renormalization group (DMRG) algorithm. In the transcorrelation…

Chemical Physics · Physics 2022-08-30 Alberto Baiardi , Michał Lesiuk , Markus Reiher

One-hundred-nm-scale electronic structure calculations were carried out on the K supercomputer by our original simulation code ELSES (http://www.elses.jp/) The present paper reports preliminary results of transport calculations for…

Materials Science · Physics 2016-12-21 Hiroto Imachi , Seiya Yokoyama , Takami Kaji , Yukiya Abe , Tomofumi Tada , Takeo Hoshi

Graph-based linear scaling electronic structure theory for quantum-mechanical molecular dynamics simulations is adapted to the most recent shadow potential formulations of extended Lagrangian Born-Oppenheimer molecular dynamics, including…

Chemical Physics · Physics 2023-03-08 Christian F. A. Negre , Michael E. Wall , Anders M. N. Niklasson

A new modelling approach for the analysis of weighted networks with ordinal/polytomous dyadic values is introduced. Specifically, it is proposed to model the weighted network connectivity structure using a hierarchical multilayer…

Methodology · Statistics 2019-08-05 Alberto Caimo , Isabella Gollini

We propose an algorithm for generating explicit solutions of multiparametric mixed-integer convex programs to within a given suboptimality tolerance. The algorithm is applicable to a very general class of optimization problems, but is most…

Optimization and Control · Mathematics 2019-06-12 Danylo Malyuta , Behcet Acikmese

Modeling the wave nature of light and the propagation and diffraction of electromagnetic fields is crucial for the accurate simulation of many phenomena, yet wave simulations are significantly more computationally complex than classical…

Optics · Physics 2025-08-26 Shlomi Steinberg , Matt Pharr

Transmission matrices, mapping the propagation of light from one end of the tissue to the other, form an important mathematical tool in the analysis of tissue scattering and the design of wavefront shaping systems. To understand the…

Optics · Physics 2025-04-01 Anat Levin , Marina Alterman

The logistic map is a paradigmatic dynamical system originally conceived to model the discrete-time demographic growth of a population, which shockingly, shows that discrete chaos can emerge from trivial low-dimensional non-linear dynamics.…

Chaotic Dynamics · Physics 2016-04-20 Alexandre L'Her , Pablo Amil , Nicolas Rubido , Arturo C. Marti , Cecilia Cabeza

The quantitative description of correlated electron materials remains a modern computational challenge. We demonstrate a numerical strategy to simulate correlated materials at the fully ab initio level beyond the solution of effective…

Superconductivity · Physics 2022-09-19 Zhi-Hao Cui , Huanchen Zhai , Xing Zhang , Garnet Kin-Lic Chan

We investigate a simple and robust scheme for choosing the phases of adiabatic electronic states smoothly (as a function of geometry) so as to maximize the performance of ab initio non-adiabatic dynamics methods. Our approach is based upon…

Chemical Physics · Physics 2019-09-26 Zeyu Zhou , Zuxin Jin , Tian Qiu , Andrew M. Rappe , Joseph Eli Subotnik