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Classical density functional theory for finite temperatures is usually formulated in the grand-canonical ensemble where arbitrary variations of the local density are possible. However, in many cases the systems of interest are closed with…

Statistical Mechanics · Physics 2022-04-06 James F. Lutsko

The exact interaction energy of a many-electron system is determined by the electron pair density, which is not well-approximated in standard Kohn-Sham density functional models. Here we study the (complicated but well-defined) exact…

Chemical Physics · Physics 2015-08-07 Huajie Chen , Gero Friesecke

Reduced density matrix functional theory for the case of solids is presented and a new exchange correlation functional based on a fractional power of the density matrix is introduced. We show that compared to other functionals, this…

Materials Science · Physics 2009-11-13 S. Sharma , J. K. Dewhurst , N. N. Lathiotakis , E. K. U. Gross

The closed-form Br\"ukner $G$ matrix for nuclear matter is computed in the $^1S_0$ channel of EFT($\not\!\!\pi$) and renormalized in nonperturbative context. The nuclear medium environment yields additional constraints that are consistent…

Nuclear Theory · Physics 2021-06-04 Ting-Wei Pan , Ji-Feng Yang

Density matrix perturbation theory [Niklasson and Challacombe, Phys. Rev. Lett. 92, 193001 (2004)] is generalized to canonical (NVT) free energy ensembles in tight-binding, Hartree-Fock or Kohn-Sham density functional theory. The canonical…

Chemical Physics · Physics 2015-12-09 Anders M. N. Niklasson , Marc J. Cawkwell , Emanuel H. Rubensson , Elias Rudberg

Any astrophysical object can, in principle, serve as a probe of the interaction between Dark Matter and regular, baryonic matter. This method is based on the potential observable consequences annihilations of captured Dark Matter has on the…

Cosmology and Nongalactic Astrophysics · Physics 2024-02-13 Cosmin Ilie

The exact equations of motion for microscopic density of classical particles number with account of inter-particle interactions and external field in closed form are derived. An integral equation for equilibrium distributions of the…

Statistical Mechanics · Physics 2014-07-18 A. Yu. Zakharov

Different steps leading to the new functional for pairing based on natural orbitals and occupancies proposed in ref. [D. Lacroix and G. Hupin, arXiv:1003.2860] are carefully analyzed. Properties of quasi-particle states projected onto good…

Nuclear Theory · Physics 2011-03-22 Guillaume Hupin , Denis Lacroix

We present a mean-field approach for accurately describing strong correlations via electron number fluctuations and pairings constrained to an active space. Electron number conservation is broken and correct only on average but both spin…

Materials Science · Physics 2013-06-28 Takashi Tsuchimochi , Gustavo E. Scuseria

The solutions of the Wigner-transformed time-dependent Hartree--Fock--Bogoliubov equations are studied in the constant-$\Delta$ approximation. This approximation is known to violate particle-number conservation. As a consequence, the…

Nuclear Theory · Physics 2008-11-26 V. I. Abrosimov , D. M. Brink , A. Dellafiore , F. Matera

The many-body space fractional quantum system is studied using the density matrix method. We give the new results of the Thomas-Fermi model, and obtain the quantum pressure of the free electron gas. We also show the validity of the…

Mathematical Physics · Physics 2011-06-27 Jianping Dong

The Particle Number Projected Generator Coordinate Method is formulated for the pairing Hamiltonian in a detailed way in the projection after variation and the variation after projection methods. The dependence of the wave functions on the…

Superconductivity · Physics 2009-11-11 M. A. Fernandez , J. L. Egido

Density matrices are powerful mathematical tools for the description of closed and open quantum systems. Recently, methods for the direct computation of density matrix elements in scalar quantum field theory were developed based on thermo…

High Energy Physics - Theory · Physics 2025-03-12 Christian Käding , Mario Pitschmann

An efficient approach to calculate approximate pure-state and transition reduced density matrices in the framework of the multireference relativistic Fock-space coupled cluster (FS CC) theory is proposed. The method is based on the…

Computational Physics · Physics 2025-06-12 Alexander V. Oleynichenko , Andrei Zaitsevskii , Leonid V. Skripnikov , Ephraim Eliav

The generalized density matrix (GDM) method is used to calculate microscopically the parameters of the collective Hamiltonian. Higher order anharmonicities are obtained consistently with the lowest order results, the mean field…

Nuclear Theory · Physics 2011-09-23 L. Y. Jia

We consider diagonal matrix elements of local operators between multi-soliton states in finite volume in the sine-Gordon model, and formulate a conjecture regarding their finite size dependence which is valid up to corrections exponential…

High Energy Physics - Theory · Physics 2013-03-14 T. Pálmai , G. Takács

Systems involving N-identical interacting particles under quantum confinement appear in many areas of physics, including chemical, condensed matter, and atomic physics. We discuss a beyondmean- field perturbation method that is applicable…

Atomic Physics · Physics 2007-05-23 W. B. Laing , M. Dunn , J. G. Loeser , D. K. Watson

We develop the number-conserving approach that has previously been used in a single component Bose-Einstein condensed dilute atomic gas, to describe consistent coupled condensate and noncondensate number dynamics, to an $n$-component…

Quantum Gases · Physics 2015-06-18 Peter Mason , Simon Gardiner

A recently developed formalism in which Kohn-Sham calculations are combined with an ``average pair density functional theory'' is reviewed, and some new properties of the effective electron-electron interaction entering in this formalism…

Materials Science · Physics 2009-11-11 Paola Gori-Giorgi , Andreas Savin

The LSDA+U approach to density functional theory is carefully reanalyzed. Its possible link to single-particle Green's function theory is occasionally discussed. A simple and elegant derivation of the important sum rules for the on-site…

Strongly Correlated Electrons · Physics 2009-11-10 H. Eschrig , K. Koepernik , I. Chaplygin