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Quantum simulation of many-body quantum systems using Rydberg-atom platforms has become of extreme interest in the last years. The possibility to realize spin Hamiltonians and the accurate control at the single atom level paved the way for…

Quantum Physics · Physics 2025-06-17 Francesco Perciavalle , Davide Rossini , Juan Polo , Oliver Morsch , Luigi Amico

Excited states of molecules lie in the heart of photochemistry and chemical reactions. The recent development in quantum computational chemistry leads to inventions of a variety of algorithms that calculate the excited states of molecules…

Quantum Physics · Physics 2020-11-05 Hiroki Kawai , Yuya O. Nakagawa

We propose a simple procedure to produce energy eigenstates of a Hamiltonian with discrete eigenvalues. We use ancilla qubits and quantum entanglement to separate an energy eigenstate from the other energy eigenstates. We exhibit a few…

Quantum Physics · Physics 2024-01-04 Kazuto Oshima

We propose two experimental schemes for producing coherent-state superpositions which approximate different nonclassical states conditionally in traveling optical fields. Although these setups are constructed of a small number of linear…

Quantum Physics · Physics 2018-02-21 Emese Molnar , Peter Adam , Gabor Mogyorosi , Matyas Mechler

The calculation of excited state energies of electronic structure Hamiltonians has many important applications, such as the calculation of optical spectra and reaction rates. While low-depth quantum algorithms, such as the variational…

Quantum Physics · Physics 2019-07-03 Oscar Higgott , Daochen Wang , Stephen Brierley

The ultimate miniaturization of electronic devices will likely require local and coherent control of single electronic wavefunctions. Wavefunctions exist within both physical real space and an abstract state space with a simple geometric…

Mesoscale and Nanoscale Physics · Physics 2009-04-21 Christopher R. Moon , Christopher P. Lutz , Hari C. Manoharan

We suggest a way to produce higher-energy superposition states in a circular system of quantum wells. This is inspired by a link to convergence results for geometric transformations of polygons using circulant Hermitian matrices.

Quantum Physics · Physics 2017-12-22 Dimitris Vartziotis , Benjamin Himpel , Markus Pfeil

Using a single, harmonically trapped $^9$Be$^+$ ion, we experimentally demonstrate a technique for generation of arbitrary states of a two-level particle confined by a harmonic potential. Rather than engineering a single Hamiltonian that…

Variational quantum algorithms are emerging as promising candidates for near-term practical applications of quantum information processors, in the field of quantum chemistry. We implement the variational quantum eigensolver algorithm to…

Quantum Physics · Physics 2024-07-02 Dileep Singh , Shashank Mehendale , Arvind , Kavita Dorai

A method is presented in which the ground-state subspace is projected out of a Hamiltonian representation. As a result of this projection, an effective Hamiltonian is constructed where its ground-state coincides with an excited-state of the…

Quantum Physics · Physics 2023-08-14 P. Jouzdani , S. Bringuier , M. Kostuk

We present and discuss a wide-range hydrogen equation of state model based on a consistent set of ab initio simulations including quantum protons and electrons. Both the process of constructing this model and its predictions are discussed…

We present a novel method for improving the quantum simulation of the ground state energy of molecules. We perform a pre-processing step classically, which reduces the dimensionality of the problem by generating a custom mapping which…

Quantum Physics · Physics 2023-03-03 Kaur Kristjuhan , Mark Nicholas Jones

In this letter we present an experimental realization of the quantum mechanics textbook example of two interacting electronic quantum states that hybridize forming a molecular state. In our particular realization, the quantum states…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 M. R. Graeber , M. Weiss , D. Keller , S. Oberholzer , C. Schoenenberger

A method for generating a mesoscopic superposition state of the collective spin variable of a gas of atoms is proposed. The state consists of a superposition of the atomic spins pointing in two slightly different directions. It is obtained…

Quantum Physics · Physics 2009-11-10 S. Massar , E. S. Polzik

Recently, it has been shown that the ground-state energy of a quantum many-body system can be written in terms of cumulants. In this paper we show that the energies of excited states can be expressed similarly. These representations are…

Condensed Matter · Physics 2007-05-23 T. Schork , P. Fulde

According to energy band theory, ground states of a normal conductor and insulator can be obtained by filling electrons individually into energy levels, without any restrictions. It fails when the electron-electron correlation is taken into…

Strongly Correlated Electrons · Physics 2021-12-30 K. L. Zhang , Z. Song

It is exponentially hard to simulate quantum systems by classical algorithms, while quantum computer could in principle solve this problem polynomially. We demonstrate such an quantum-simulation algorithm on our NMR system to simulate an…

Quantum Physics · Physics 2009-07-22 Jiangfeng Du , Nanyang Xu , Xinhua Peng , Pengfei Wang , Sanfeng Wu , Dawei Lu

We construct a Hamiltonian for the generation of arbitrary pure states of the quantized electromagnetic field. The proposition is based upon the fact that a unitary transformation for the generation of number states has been already found.…

Quantum Physics · Physics 2009-10-31 A. Vidiella-Barranco , J. A. Roversi

We report the first electronic structure calculation performed on a quantum computer without exponentially costly precompilation. We use a programmable array of superconducting qubits to compute the energy surface of molecular hydrogen…

The computation of excited electronic states is an important application for quantum computers. In this work, we simulate the excited state spectra of four aromatic heterocycles on IBM superconducting quantum computers, focusing on active…

Quantum Physics · Physics 2023-09-19 Maria A. Castellanos , Mario Motta , Julia E. Rice
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