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Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…

Chemical Physics · Physics 2025-05-16 Thomas Schnappinger , Markus Kowalewski

The coherent strong coupling of molecules with confined light fields to create polaritons - part matter, part light - is opening exciting opportunities ranging from extended exciton transport and inter-molecular energy transfer to modified…

The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…

The differential response of chiral molecules to incident left- and right- handed circularly polarized light is used for sensing the handedness of molecules. Currently, significant effort is directed towards enhancing weak differential…

We design, in a most simple way, Fabry-Perot cavities with longitudinal chiral modes by sandwiching between two smooth metallic silver mirrors a layer of polystyrene made planar chiral by torsional shear stress. We demonstrate that the…

Optics · Physics 2021-05-19 Jérôme Gautier , Minghao Li , Thomas W. Ebbesen , Cyriaque Genet

We investigate Jahn-Teller (JT) polaritons, which emerge from the interaction of the two normal-incidence electromagnetic modes with perpendicular polarizations in a Fabry-Perot cavity resonator with JT active systems. These JT polaritons…

Chemical Physics · Physics 2023-06-21 Krishna Nandipati , Oriol Vendrell

In recent years tremendous progress in the field of light-matter interactions has unveiled that strong coupling to the modes of an optical cavity can alter chemistry even at room temperature. Despite these impressive advances, many…

Chemical Physics · Physics 2020-05-20 Dominik Sidler , Michael Ruggenthaler , Heiko Appel , Angel Rubio

Chirality, the absence of mirror symmetry, is a fundamental molecular property with far-reaching consequences from chemistry to biology. Yet enantiosensitive optical responses are very weak. Here, we introduce a theoretical framework in…

Optics · Physics 2026-01-12 Yang-Cheng Ye , Panpan Zhang , Ajay Jha , Fulu Zheng , Hong-Guang Duan

Molecular strong coupling offers exciting prospects in physics, chemistry and materials science. Whilst attention has been focused on developing realistic models for the molecular systems, the important role played by the entire photonic…

A criterion for strong coupling between two quantum emitters and a single resonant light mode in a cavity is presented. The criterion takes into account the escape of cavity photons and the spontaneous emission of the emitters, which are…

Quantum Physics · Physics 2015-06-05 Nicolás Quesada

We present a microscopic semi-analytical theory for the description of organic molecules interacting strongly with a cavity mode. Exciton-vibration coupling within the molecule and exciton-cavity interaction are treated on an equal footing…

Mesoscale and Nanoscale Physics · Physics 2016-11-15 Ning Wu , Johannes Feist , Francisco J. Garcia-Vidal

We propose a method to separate enantiomers using parity violation in the Casimir-Polder potential between chiral mirrors and chiral molecules. The proposed setup involves a molecular beam composed of chiral molecules passing through a…

Quantum Physics · Physics 2019-01-21 Fumika Suzuki , Takamasa Momose , Stefan Yoshi Buhmann

Polaritonic chemistry exploits strong light-matter coupling between molecules and confined electromagnetic field modes to enable new chemical reactivities. In systems displaying this functionality, the choice of the cavity determines both…

Optics · Physics 2022-08-25 Jacopo Fregoni , Francisco J. García-Vidal , Johannes Feist

Chiral-induced spin selectivity (CISS) is a phenomenon in which electron spins are polarized as they are transported through chiral molecules, and the spin polarization depends on the handedness of the chiral molecule. In this study, we…

Mesoscale and Nanoscale Physics · Physics 2023-02-09 Nguyen Thanh Phuc

Plasmonic chirality exhibits great potential for novel nanooptical devices due to the generation of a strong chiroptical response. Previous reports on plasmonic chirality explanations are mainly based on phase retardation and coupling. We…

Mesoscale and Nanoscale Physics · Physics 2016-05-05 Li Hu , Yingzhou Huang , Yurui Fang

The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an…

Quantum Physics · Physics 2016-06-09 Felipe Herrera , Frank C. Spano

We present a combined analytical and numerical study for coherent terahertz control of a single molecular polariton, formed by strongly coupling two rotational states of a molecule with a single-mode cavity. Compared to the bare molecules…

Quantum Physics · Physics 2023-02-08 Li-Bao Fan , Chuan-Cun Shu , Daoyi Dong , Jun He , Niels E. Henriksen , Franco Nori

We investigate the coupling between a quantized electromagnetic field in a cavity resonator and a Coulomb interacting electronic system in a nanostructure in an external magnetic field. Effects caused by the geometry of the electronic…

Mesoscale and Nanoscale Physics · Physics 2012-03-15 Olafur Jonasson , Chi-Shung Tang , Hsi-Sheng Goan , Andrei Manolescu , Vidar Gudmundsson

Modifications of Casimir-Polder interactions due to confinement inside a cylindrical cavity and due to curvature in- and outside the cavity are studied. We consider a perfectly conducting cylindrical shell with a single particle (atom or…

Statistical Mechanics · Physics 2015-06-23 Pablo Rodriguez-Lopez , Thorsten Emig , Ehsan Noruzifar , Roya Zandi

Strong coupling between light and matter generates hybrid polariton modes. We present a continuum formalism that expresses the polariton modes in terms of light and matter densities of states (DOS). We derive exact expressions for the light…

Materials Science · Physics 2024-12-03 Suman Gunasekaran , Ryan F. Pinard , Andrew J. Musser