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The bulk photovoltaic effect (BPVE) generates a direct current photocurrent under uniform irradiation and is a nonlinear optical effect traditionally studied in non-centrosymmetric materials. The two main origins of BPVE are the shift and…

Mesoscale and Nanoscale Physics · Physics 2025-03-03 Ying-Ming Xie , Naoto Nagaosa

Heterostructures based on atomically thin semiconductors are considered a promising emerging technology for the realization of ultrathin and ultralight photovoltaic solar cells on flexible substrates. Much progress has been made in recent…

The bulk photovoltaic effect (BPVE) -- generation of electric currents by light in noncentrosymmetric materials in the absence of electric fields and gradients -- has been intensively investigated in the end of the last century. The…

Mesoscale and Nanoscale Physics · Physics 2019-11-28 Boris Sturman

We employ first-principles calculations to investigate the ferroelectric properties and the bulk photovoltaic effect (BPVE) of antimony sulfur iodide (SbSI). The BPVE enables direct sunlight-to-electricity conversion in homogeneous…

Materials Science · Physics 2025-06-13 Giuseppe Cuono , Subhadeep Bandyopadhyay , Andrea Droghetti , Silvia Picozzi

The bulk photovoltaic effect (BPVE) has attracted an increasing interest due to its potential to overcome the efficiency limit of traditional photovoltaics, and much effort has been devoted to understanding its underlying physics. However,…

Materials Science · Physics 2022-01-05 Zhenbang Dai , Andrew M. Rappe

The bulk photovoltaic effect (BPVE), a manifestation of broken centrosymmetry, has attracted interest as a probe of the symmetry and quantum geometry of materials, and for use in novel optoelectronic devices. Despite its bulk nature, the…

The bulk photovoltaic effect (BPVE) refers to current generation due to illumination by light in a homogeneous bulk material lacking inversion symmetry. In addition to the intensively studied shift current, the ballistic current, which…

Materials Science · Physics 2021-05-05 Zhenbang Dai , Aaron M. Schankler , Lingyuan Gao , Liang Z. Tan , Andrew M. Rappe

The connection between noncentrosymmetric materials' structure, electronic structure, and bulk photovoltaic performance remains not well understood. In particular, it is still unclear which photovoltaic (PV) mechanism(s) are relevant for…

Materials Science · Physics 2015-05-20 Fenggong Wang , Andrew M. Rappe

Layered transition metal dichalcogenide semiconductors are interesting for photovoltaics owing to their high solar absorbance and efficient carrier diffusion. Tungsten diselenide (WSe$_2$), in particular, has emerged as a promising solar…

We argue that the layer electric polarization of noncentrosymmetric layered heterostructures can be generically controlled by light yielding a layer photovoltaic effect (LPE). The LPE possesses a rich phenomenology and can arise from myriad…

Mesoscale and Nanoscale Physics · Physics 2025-01-29 Oles Matsyshyn , Ying Xiong , Arpit Arora , Justin C. W. Song

Integrated photodetectors are crucial for their high speed, sensitivity, and efficient power consumption. In these devices, photocurrent generation is primarily attributed to the photovoltaic (PV) effect, driven by electron hole…

Materials Science · Physics 2024-10-18 Da Xu , Qiushi Liu , Boqun Liang , Ning Yu , Xuezhi Ma , Yaodong Xu , Takashi Taniguchi , Roger K. Lake , Ruoxue Yan , Ming Liu

We study the bulk photovoltaic effect (BPVE) in Dirac and Weyl semimetals under two-frequency light irradiation. We show that the BPVE emerges for centrosymmetric Dirac and Weyl semimetals in the presence of light fields with frequencies…

Mesoscale and Nanoscale Physics · Physics 2025-01-15 Yuya Ikeda , Sota Kitamura , Takahiro Morimoto

Spontaneous polarization and bulk photovoltaic effect (BPVE) are two concomitant physical properties in ferroelectric materials. The flipping of ferroelectric order usually accompanies with the switching of BPVE as both of them are reversed…

Materials Science · Physics 2022-07-04 Rui-Chun Xiao , Yang Gao , Hua Jiang , Wei Gan , Changjin Zhang , Hui Li

The top-down synthesis of inherently ferroelectric semiconductors and their integration with traditional material platforms have the potential to enable new low power logic devices, and to harness the bulk photoelectric effect for more…

Converting light into steady currents and spin-currents in two-dimensional (2D) platform is essential for future energy harvesting and spintronics. We show that the giant and modulable bulk photovoltaic effects (BPVEs) can be achieved in…

Materials Science · Physics 2023-01-10 Liang Liu , Weikang Liu , Bin Cheng , Bin Cui , Jifan Hu

Achieving low contact resistance in advanced quantum electronic devices remains a critical challenge. With the growing demand for faster and energy-efficient devices, 2D contact engineering offers a promising solution. Beyond graphene,…

Semiconducting 2D materials, such as molybdenum disulfide (MoS2) and other members of the transition metal dichalcogenide family, have emerged as promising materials for applications in high performance nanoelectronics that exhibit…

Applied Physics · Physics 2019-05-24 David Maeso , Andres Castellanos-Gomez , Nicolas Agraït , Gabino Rubio-Bollinger

Energy states below the bandgap of a semiconductor, such as trap states or charge transfer states in organic donor acceptor blends, can contribute to light absorption. Due to their low number density or ultrasmall absorption cross-section,…

Applied Physics · Physics 2019-11-27 Christina Kaiser , Stefan Zeiske , Paul Meredith , Ardalan Armin

Bulk photovoltaic effect is a non-linear response in noncentrosymmetric materials that converts light into DC current. In this work, we investigate the optical linear and non-linear responses in a chalcopyrite semiconductor ZnGeP$_2$. We…

Materials Science · Physics 2024-10-15 Banasree Sadhukhan

The implementation of a wide range of novel concepts for next-generation high-efficiency solar cells is based on nanostructures with configuration-tunable optoelectronic properties. On the other hand, effective nano-optical light-trapping…

Materials Science · Physics 2018-04-04 Urs Aeberhard