English
Related papers

Related papers: General-order open-shell coupled-cluster method wi…

200 papers

In this chapter we review some examples, methods, and recent results involving comparison of clustering properties of point processes. Our approach is founded on some basic observations allowing us to consider void probabilities and moment…

Probability · Mathematics 2014-05-23 Bartłomiej Błaszczyszyn , D. Yogeshwaran

We describe a generalized scheme for the probability-changing cluster (PCC) algorithm, based on the study of the finite-size scaling property of the correlation ratio, the ratio of the correlation functions with different distances. We…

Statistical Mechanics · Physics 2009-11-07 Yutaka Okabe , Yusuke Tomita , Chiaki Yamaguchi

We consider a new formulation of the stochastic coupled cluster method in terms of the similarity transformed Hamiltonian. We show that improvement in the granularity with which the wavefunction is represented results in a reduction in the…

Chemical Physics · Physics 2016-02-02 Ruth S. T. Franklin , James S. Spencer , Alberto Zoccante , Alex J. W. Thom

Coupled cluster theory is a vital cornerstone of electronic structure theory and is being applied to ever-larger systems. Stochastic approaches to quantum chemistry have grown in importance and offer compelling advantages over traditional…

We present a detailed description of the generalized geometric cluster algorithm for the efficient simulation of continuum fluids. The connection with well-known cluster algorithms for lattice spin models is discussed, and an explicit full…

Statistical Mechanics · Physics 2009-11-11 Jiwen Liu , Erik Luijten

We discuss computational aspects of the spherical coupled-cluster method specific to the nuclear many-body problem. Using chiral nucleon-nucleon interaction at next-to-next-to-next-to leading order (N3LO) with cutoff Lambda = 500MeV, we…

Nuclear Theory · Physics 2015-06-04 Gaute Hagen , Hai Ah Nam

Stepped-wedge cluster randomised trials (SW-CRTs) increasingly evaluate complex interventions, yet methodological guidance for analysing composite endpoints using generalized pairwise comparisons (GPC)remains limited. This work investigates…

The whole enterprise of spin compositions can be recast as simple enumerative combinatoric problems. We show here that enumerative combinatorics (EC)\citep{book:Stanley-2011} is a natural setting for spin composition, and easily leads to…

Mathematical Physics · Physics 2018-01-23 Jerryman Appiahene Gyamfi , Vincenzo Barone

A dynamical formulation of coupled cluster theory is derived using a variational principle. By allowing time-dependent single-particle functions, a high degree of adaptivity is introduced, allowing complex systems to be simulated with high…

Quantum Physics · Physics 2014-11-25 Simen Kvaal

We introduce a novel class of coupled cluster (CC) methods that leverage the seniority concept to enhance efficiency and accuracy in electronic structure calculations. While existing approaches, such as the pair coupled cluster doubles…

This survey concerns probabilistic models motivated by cooperative sequential adsorption (CSA) models. CSA models are widely used in physics and chemistry for modelling adsorption processes in which adsorption rates depend on the spatial…

Probability · Mathematics 2024-01-17 Vadim Shcherbakov

Clustering is a NP-hard problem. Thus, no optimal algorithm exists, heuristics are applied to cluster the data. Heuristics can be very resource-intensive, if not applied properly. For substantially large data sets computational efficiencies…

Databases · Computer Science 2020-03-11 Mujahid Sultan

The paper presents two CLP approaches to 2D angle placements, implemented in CHIP v.5.3. The first is based on the classical (rectangular) cumulative global constraint, the second on the new trapezoidal cumulative global constraint. Both…

Programming Languages · Computer Science 2007-05-23 Tomasz Szczygiel

Mixture models extend the toolbox of clustering methods available to the data analyst. They allow for an explicit definition of the cluster shapes and structure within a probabilistic framework and exploit estimation and inference…

Methodology · Statistics 2025-09-15 Bettina Grün

We propose a new method of adaptive piecewise approximation based on Sinc points for ordinary differential equations. The adaptive method is a piecewise collocation method which utilizes Poly-Sinc interpolation to reach a preset level of…

Numerical Analysis · Mathematics 2022-09-29 Omar Khalil , Hany El-Sharkawy , Maha Youssef , Gerd Baumann

Due to the rapid growth of data and computational resources, distributed optimization has become an active research area in recent years. While first-order methods seem to dominate the field, second-order methods are nevertheless attractive…

Machine Learning · Computer Science 2018-06-21 Celestine Dünner , Aurelien Lucchi , Matilde Gargiani , An Bian , Thomas Hofmann , Martin Jaggi

We consider the sampling of the coupled cluster expansion within stochastic coupled cluster theory. Observing the limitations of previous approaches due to the inherently non-linear behaviour of a coupled cluster wavefunction representation…

Chemical Physics · Physics 2018-08-14 Charles J. C. Scott , Alex J. W. Thom

Spectral clustering is a popular method for effectively clustering nonlinearly separable data. However, computational limitations, memory requirements, and the inability to perform incremental learning challenge its widespread application.…

Machine Learning · Computer Science 2023-11-15 Jo-Chun Chen , Hung-Hsuan Chen

In this article we extend the adaptive cross approximation (ACA) method known for the efficient approximation of discretisations of integral operators to a block-adaptive version. While ACA is usually employed to assemble hierarchical…

Numerical Analysis · Mathematics 2019-05-07 M. Bauer , M. Bebendorf

Spectral clustering and co-clustering are well-known techniques in data analysis, and recent work has extended spectral clustering to square, symmetric tensors and hypermatrices derived from a network. We develop a new tensor spectral…

Social and Information Networks · Computer Science 2016-03-02 Tao Wu , Austin R. Benson , David F. Gleich