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Tip-enhanced Raman scattering (TERS) has emerged as a powerful tool to obtain subnanometer spatial resolution fingerprints of atomic motion. Theoretical calculations that can simulate the Raman scattering process and provide an unambiguous…

Chemical Physics · Physics 2023-08-10 Y. Litman , F. P. Bonafé , A. Akkoush , H. Appel , M. Rossi

We present a method for deriving limits on Raman scattering in structured media and exploit it to constrain the maximum Raman signal resulting from a planewave incident on either a single Raman molecule in the vicinity of a structured…

The electromagnetic enhancement for surface enhanced Raman spectroscopy (SERS) of graphene is studied by inserting a layer of Al2O3 between epitaxial graphene and Au nanoparticles. Different excitation lasers are utilized to study the…

The sensitivity of classical Raman spectroscopy methods, such as Coherent Anti-Stokes Raman spectroscopy (CARS) or Stimulated Raman spectroscopy (SRS), is ultimately limited by shot-noise from the stimulating fields. We present the complete…

Optics · Physics 2021-10-22 Yoad Michael , Leon Bello , Michael Rosenbluh , Avi Pe'er

Solid-state single-photon emitters are attractive for realization of integrated quantum systems due to their experimental convenience and scalability. Unfortunately, however, their complex mesoscopic environments cause photons from…

Mesoscale and Nanoscale Physics · Physics 2018-09-03 Smarak Maity , Linbo Shao , Young-Ik Sohn , Srujan Meesala , Bartholomeus Machielse , Edward Bielejec , Matthew Markham , Marko Loncar

Coherent interconversion of signals between optical and mechanical domains is enabled by optomechanical interactions. Extreme light-matter coupling produced by confining light to nanoscale mode volumes can then access single mid-infrared…

Raman-based technologies have enabled many ground-breaking scientific discoveries related to surface science, single molecule chemistry and biology. For example, researchers have identified surface bound molecules by their Raman vibrational…

Optics · Physics 2020-03-12 Xiaoqin Shen , Hyungwoo Choi , Dongyu Chen , Wei Zhao , Andrea M. Armani

Electron Raman scattering (ERS) is investigated in a parabolic semiconductor quantum wire in a transverse magnetic field neglecting by phonon-assisted transitions. The ERS cross-section is calculated as a function of a frequency shift and…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 F. M. Hashimzade , T. G. Ismailov , B. H. Mehdiyev , S. T. Pavlov

The hotspots, which are typically found in nanogaps between metal structures, are critical for the enhancement of the electromagnetic field. Surface-enhanced Raman scattering (SERS), a technique known for its exceptional sensitivity and…

Low-frequency Raman scattering experiments have been performed on thin films consisting of nickel-silver composite nanoparticles embedded in alumina matrix. It is observed that the Raman scattering by the quadrupolar modes, strongly…

Condensed Matter · Physics 2007-05-23 H. Portales , L. Saviot , E. Duval , M. Gaudry , E. Cottancin , M. Pellarin , J. Lerme , M. Broyer

The experimental limitations in the signal enhancement and spatial resolution in spectroscopic imaging have been always a challenging task in the application of near-field spectroscopy for nanostructured materials in the sub-diffraction…

Materials Science · Physics 2018-06-11 A. K. Sivadasan , Avinash Patsha , Achyut Maity , Tapas Kumar Chini , Sandip Dhara

Photo-Induced Enhanced Raman Spectroscopy (PIERS) is a new surface enhanced Raman spectroscopy (SERS) modality with an order-of-magnitude Raman signal enhancement of adsorbed analytes over that of typical SERS substrates. Despite the…

Materials Science · Physics 2021-06-01 Junzhi Ye , Rakesh Arul , Michel K. Nieuwoudt , Junzhe Dong , Wei Gao , M. Cather Simpson

We report on the experimental observation of mirror enhanced directional surface enhanced Raman scattering (SERS) from a self-assembled monolayer of molecules coupled to a nanowire-nanoparticle (NW-NP) junction on a mirror in remote…

Optics · Physics 2021-11-17 Sunny Tiwari , Adarsh B Vasista , Diptabrata Paul , G. V. Pavan Kumar

The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic field on rough metal surfaces are considered. It is…

Optics · Physics 2014-11-17 V. P. Chelibanov , A. M. Polubotko

Raman spectroscopy is a powerful technique to characterize materials. It probes non-destructively chemical composition, crystallinity, defects, strain and coupling phenomena. However, the Raman response of surfaces or thin films is often…

Surface enhanced Raman spectroscopy (SERS) is a precise and non-invasive analytical technique that is widely used in chemical analysis, environmental protection, food processing, pharmaceutics, and diagnostic biology. However, it is still a…

New type of plasmonic nanoparticles - silver octopods that can be synthesized with a variety of shapes - have been demonstrated to show versatile optical response using the discrete dipole approximation. The octopods show a complex behavior…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Ivan I. Naumov , Zhiyong Li , Alexander M. Bratkovsky

Semiconductor-based surface-enhanced Raman spectroscopy (SERS) substrates, as a new frontier in the field of SERS, are hindered by their poor electromagnetic field confinement, and weak light-matter interaction. Metasurfaces, a class of 2D…

Devices possessing the ability to sense both electrically and optically molecular targets are of fundamental and technological interest. Towards this end, it has been shown that covering the ends of gapped gold-nanorod-dimer nanoantennas…

Surface enhanced Raman spectroscopy, is a technique of fundamental importance to analytical science and technology where the amplified Raman spectrum of analytes is used for chemical fingerprinting. Here, we showcase an engineered…

Applied Physics · Physics 2021-06-08 K N Prajapati , Anoop A Nair , S Ravi P Silva , J Mitra