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Lead-free halide double perovskites are promising stable and non-toxic alternatives to methylammonium lead iodide in the field of photovoltaics. In this context, the most commonly used double perovskite is Cs$_2$AgBiBr$_6$, due to its…

Materials Science · Physics 2022-08-29 Elisabetta Landini , Karsten Reuter , Harald Oberhofer

Light emission and detection are the two fundamental attributes of optoelectronic communication systems. Until now, both functions have been demonstrated using the p-n diode which is exploited across a wide range of applications. However,…

Lead-free halide double perovskites are promising alternatives to Pb-based semiconductors, but their discovery is challenging because structural formability, thermodynamic stability, band-gap placement, optical-transition strength,…

Lead halide perovskite solar cells have recently emerged as a very promising photovoltaic technology due to their excellent power conversion efficiencies; however, the toxicity of lead and the poor stability of perovskite materials remain…

Materials Science · Physics 2017-03-10 Xiaolei Li , Xiangli Zhong , Yue Hu , Bochao Li , Yusong Sheng , Yang Zhang , Chao Weng , Ming Feng , Hongwei Han , Jinbin Wang

Perovskite oxide based thin film gas sensors have long been considered as potential alternatives to commonly investigated binary metal oxides based sensors. BiFeO3, which is a prototype of p-type perovskite based semiconducting oxides, has…

Materials Science · Physics 2019-01-24 Arindam Bala , S. B. Majumder , Moumita Dewan , Ayan Roy Chaudhuri

Single crystals of Cs2BiAgBr6 lead-free perovskite were grown by crystallization from supersaturated solution. According to characterization by XRD and EBSD methods the double perovskite single crystal are of the cubic Fm-3m symmetry with…

Lead halide perovskites have emerged as promising materials for optoelectronic applications due to their exceptional properties. In the all-inorganic CsPbBr3 perovskites, ferroelastic domains formed during phase transitions enhance bulk…

Perovskite-based optoelectronic devices have shown great promise for solar conversion and other optoelectronic applications, but their long-term performance instability is regarded as a major obstacle to their widespread deployment.…

Halide double perovskites with alternating silver and pnictogen cations are an emerging family of photoabsorber materials with robust stability and band gaps in the visible range. However, the nature of optical excitations in these systems…

Materials Science · Physics 2021-02-12 Raisa-Ioana Biega , Marina R. Filip , Linn Leppert , Jeffrey B. Neaton

Perylene bisimides (PBIs) are organic dyes with photoluminescence quantum yields (PLQY) close to unity in solution and great thermal and photo-chemical stability. These features alongside the tunability of their solid-state packing…

In the search for high-temperature superconductivity in hydrides, a plethora of multi-hydrogen superconductors have been theoretically predicted, and some have been synthesized experimentally under ultrahigh pressures of several hundred…

Lead-halide perovskites are highly promising for various optoelectronic applications including laser devices. However, fundamental photophysics describing the lasing behaviour in this material family have not been investigated…

Lead halide perovskites possess high photoluminescence (PL) efficiency and strong electron-phonon interactions, and therefore the optical cooling using up-conversion PL has been expected. We investigate anti-Stokes PL from green-luminescent…

Layered hybrid perovskites containing larger organic cations have demonstrated superior environmental stability, but the presence of these insulating spacers also strengthens the exciton binding energy, which contributes to reduced carrier…

In the search for stable lead (Pb) free perovskites, Vacancy ordered double perovskite (VODP), A$_2$BX$_6$ has emerged as a promising class of materials for solar harvesting owing to their nontoxicity, better stability, and unique…

Materials Science · Physics 2023-09-13 Supriti Ghorui , Jiban Kangsabanik , M. Aslam , Aftab Alam

Vacancy ordered halide perovskites have been extensively investigated as promising lead-free alternatives to halide perovskites for various opto-electronic applications. Among these Cs$_{2}$TiBr$_{6}$ has been reported as a stable absorber…

Materials Science · Physics 2023-06-28 B. Cucco , G. Bouder , L. Pedesseau , C. Katan , J. Even , M. Kepenekian , G. Volonakis

Hybrid organic-inorganic halide perovskites have emerged as a disruptive new class of materials, exhibiting optimum properties for a broad range of optoelectronic applications, most notably for photovoltaics. The first report of highly…

Materials Science · Physics 2018-08-21 Marina R. Filip , George Volonakis , Feliciano Giustino

Heterovalent substitution of toxic lead is an increasingly popular design strategy to obtain environmentally sustainable variants of the exciting material class of halide perovskites. Perovskite nanocrystals (NCs) obtained through…

Materials Science · Physics 2023-01-24 Fiona Treber , Kilian Frank , Bert Nickel , Carola Lampe , Alexander S. Urban

We report a comparative study of temperature-dependent photoluminescence and structural dynamics of two perovskite semiconductors, the chalcogenide BaZrS$_3$ (BZS) and the halide CsPbBr$_3$ (CPB). These materials have similar crystal…

Materials Science · Physics 2024-04-16 K. Ye , M. Menahem , T. Salzillo , F. Knoop , B. Zhao , S. Niu , O. Hellman , J. Ravichandran , R. Jaramillo , O. Yaffe

Organolead halide perovskites have attracted substantial attention due to their excellent physical properties, which enable them to serve as the active material in emerging hybrid solid-state solar cells. Here we investigate the…

Materials Science · Physics 2015-10-28 Feng Li , Chun Ma , Hong Wang , Weijin Hu , Weili Yu , Arif D. Sheikh , Tom Wu