Related papers: Compressibility and volume variations due to compo…
In this paper, we extend our study of mass transport in multicomponent isothermal fluids to the incompressible case. For a mixture, incompressibility is defined as the independence of average volume on pressure, and a weighted sum of the…
The standard definition of particle number fluctuations based on point-like particles neglects the excluded volume effect. This leads to a large and systematic finite-size scaling and an unphysical surface term in the isothermal…
The isothermal compressibility of water is essential to understand its anomalous properties. We compute it by ab initio molecular dynamics simulations of 200 molecules at five densities, using two different van der Waals density…
We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…
In Physica A vol 387(24) (2008) pp6079-6094 [1], a kinetic equation for gas flows was proposed that leads to a set of four macroscopic conservation equations, rather than the traditional set of three equations. The additional equation…
We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…
When a fluid is constrained to a fixed, finite volume, the conditions for liquid-vapor equilibrium are different from the infinite volume or constant pressure cases. There is even a range of densities for which no bubble can form, and the…
A classical model for water-gas flows in porous media is considered. The degenerate coupled system of equations obtained by mass conservation is usually approximated by finite volume schemes in the oil reservoir simulations. The convergence…
In this paper we discuss the incompressible limit for multicomponent fluids in the isothermal ideal case. Both a direct limit-passage in the equation of state and the low Mach-number limit in rescaled PDEs are investigated. Using the…
The compressibility equation of state for a multicomponent fluid of particles interacting via an infinitely narrow and deep potential, is considered within the mean spherical approximation (MSA). It is shown that for a class of models…
We explore the nature of glass-formation in variable spatial dimensionality ($d$) based on the generalized entropy theory, a synthesis of the Adam-Gibbs model with direct computation of the configurational entropy of polymer fluids using an…
We consider a system of partial differential equations describing mass transport in a multicomponent isothermal compressible fluid. The diffusion fluxes obey the Fick-Onsager or Maxwell-Stefan closure approach. Mechanical forces result into…
Compressible flow varies from ideal-gas behavior at high pressures where molecular interactions become important. Density is described through a cubic equation of state while enthalpy and sound speed are functions of both temperature and…
The general fluctuation theory is reviewed with special attention to the role played by different ensembles, and is extended to incorporate stationary metastable states obtained in the long time limit. The fluctuation in a quantity depends…
Equations of radial motion of a gas bubble in a compressible viscous liquid have been modified to account for compressibility at the bubble boundary. A new bubble boundary equation has been derived, including a new term resulted from liquid…
We consider a model describing the steady flow of compressible heat-conducting chemically-reacting multi-component mixture. We show the existence of strong solutions under the additional assumption that the mixture is sufficiently dense. We…
We present a technique that allows to obtain certain results in the compressible fluid theory: in particular, it is a nonexistence result for the highly decreasing at infinity solutions to the Navier-Stokes equations, the construction of…
This paper investigates the asymptotic behavior of the Helmholtz free energy of mixtures at small compressibility. We start from a general representation for the local free energy that is valid in stable subregions of the phase diagram. On…
Although density functional theory provides reliable predictions for the static properties of simple fluids under confinement, a theory of comparative accuracy for the transport coefficients has yet to emerge. Nonetheless, there is evidence…
Rayleigh-Taylor instability in a compressible fluid is reconsidered. The density is allowed to vary with pressure under the barotropy assumption. For the case with equal speeds of sound in the two superposed fluids, in order to give a…