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The $\Delta$NO two-electron density matrix (2-RDM) and energy expression are derived from a multideterminantal wave function. The approximate $\Delta$NO 2-RDM is combined with an on-top density functional and a double-counting correction to…

Chemical Physics · Physics 2022-03-14 Ismael A. Elayan , Rishabh Gupta , Joshua W. Hollett

Effective interactions between charged particles dispersed in an electrolyte are most commonly modeled using the Derjaguin-Landau-Verwey-Overbeek (DLVO) potential, where the ions in the suspension are coarse-grained out at mean-field level.…

Soft Condensed Matter · Physics 2025-10-23 Thijs ter Rele , Gerardo Campos-Villalobos , René van Roij , Marjolein Dijkstra

We study a lattice version of the local density approximation (LDA) based on Behte ansatz (BALDA). Contrary to what happens in Density Functional Theory (DFT) in the continuum and despite its name, BALDA displays some very non-local…

Strongly Correlated Electrons · Physics 2015-06-11 Zu-Jian Ying , Valentina Brosco , José Lorenzana

To address the impact of electron correlations in the linear and non-linear response regimes of interacting many-electron systems exposed to time-dependent external fields, we study one-dimensional (1D) systems where the interacting problem…

Other Condensed Matter · Physics 2011-08-17 N. Helbig , J. I. Fuks , I. V. Tokatly , H. Appel , E. K. U. Gross , A. Rubio

We show how one can construct \alert{a simple} exchange functional by extending the well-know local-density approximation (LDA) to finite uniform electron gases. This new generalized local-density approximation (GLDA) functional uses only…

Chemical Physics · Physics 2017-05-01 Pierre-François Loos

A non-perturbative scheme, based on the functional generalization of the Callan-Symanzik equation is developed to treat the Coulomb interaction in an electron gas. The one-particle irreducible vertex functions are shown to satisfy an…

Strongly Correlated Electrons · Physics 2011-07-19 Sebastiao Correia , Janos Polonyi , Jean Richert

The capability of density-functional theory to deal with the ground-state of strongly correlated low-dimensional systems, such as semiconductor quantum dots, depends on the accuracy of functionals developed for the exchange and correlation…

Strongly Correlated Electrons · Physics 2009-02-25 S. Pittalis , E. Rasanen , C. Proetto , E. K. U. Gross

We examine the density-density correlation function in the Tomonaga-Luttinger liquid state for the one-dimensional extended Hubbard model with the on-site Coulomb repulsion $U$ and the intersite repulsion $V$ at quarter filling. By taking…

Strongly Correlated Electrons · Physics 2015-05-14 S. Nishimoto , M. Tsuchiizu

An electrodynamical coupled cluster (CC) methodology starting from a covariant formalism and an equal time approximation, and finally based on the Dirac-Fock picture of the electron and positron fields and Coulomb gauge, is given here. The…

Atomic Physics · Physics 2019-04-30 Sambhu N. Datta

We derive a simple analytical expression for the level correlation function of an integrable system. It accounts for both the lack of correlations at smaller energy scales and for global rigidity (level number conservation) at larger…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 R. A. Serota , J. M. A. S. P. Wickramasinghe

Using time-dependent current-density functional theory, we derive analytically the dynamical exchange-correlation correction to the DC conductance of nanoscale junctions. The correction pertains to the conductance calculated in the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Na Sai , Michael Zwolak , Giovanni Vignale , Massimiliano Di Ventra

We discuss the recently proposed LDA'+DMFT approach providing consistent parameter free treatment of the so called double counting problem arising within the LDA+DMFT hybrid computational method for realistic strongly correlated materials.…

Strongly Correlated Electrons · Physics 2015-06-11 I. A. Nekrasov , N. S. Pavlov , M. V. Sadovskii

Within the Poisson-Boltzmann (PB) approach electrolytes in contact with planar, spherical, and cylindrical electrodes are analyzed systematically. The dependences of their capacitance $C$ on the surface charge density $\sigma$ and the ionic…

Soft Condensed Matter · Physics 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

A new scheme of first-principles computation for strongly correlated electron systems is proposed. This scheme starts from the local-density approximation (LDA) at high-energy band structure, while the low-energy effective Hamiltonian is…

Materials Science · Physics 2007-05-23 Yoshiki Imai , Igor V. Solovyev , Masatoshi Imada

In one-dimensional (1D) systems, electronic interactions lead to a breakdown of Fermi liquid theory and the formation of a Tomonaga-Luttinger Liquid (TLL). The strength of its many-body correlations can be quantified by a single…

Quantum dot (QD) assemblies are nanostructured networks made from aggregates of QDs and feature improved charge and energy transfer efficiencies compared to discrete QDs. Using first-principles many-body perturbation theory, we…

Materials Science · Physics 2022-10-25 Sandip Aryal , Joseph Frimpong , Zhen-Fei Liu

A simple model is proposed for the direct correlation function (DCF) for simple fluids consisting of a hard-core contribution, a simple parametrized core correction, and a mean-field tail. The model requires as input only the free energy of…

Statistical Mechanics · Physics 2007-10-08 James F. Lutsko

We study $(m)$-type connected correlation functions of OPE blocks with respect to one spatial region in two dimensional conformal field theory. We find logarithmic divergence for these correlation functions. We justify the logarithmic…

High Energy Physics - Theory · Physics 2020-01-16 Jiang Long

Local density approximation (LDA) to the density functional theory (DFT) has continuous derivative of total energy as a number of electrons function and continuous exchange-correlation potential, while in exact DFT both should be…

Strongly Correlated Electrons · Physics 2010-06-28 V. I. Anisimov , A. V. Kozhevnikov , M. A. Korotin , A. V. Lukoyanov , D. A. Khafizullin

We present a simulation method to study electrolyte solutions in a dielectric slab geometry using a modified 3D Ewald summation. The method is fast and easy to implement, allowing us to rapidly resum an infinite series of image charges. In…

Soft Condensed Matter · Physics 2015-08-12 Alexandre P. dos Santos , Yan Levin