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Boron nitride (BN) is an exceptional material and among its polymorphs, two-dimensional (2D) hexagonal and three-dimensional (3D) cubic BN (h-BN and c-BN) phases are most common. The phase stability regimes of these BN phases are still…

Boron nitride (BN) is a material with outstanding technological promise because of its exceptional thermochemical stability, structural, electronic and thermal conductivity properties, and extreme hardness. Yet, the relative thermodynamic…

Materials Science · Physics 2018-12-13 Claudio Cazorla , Tim Gould

Using atomistic simulations we investigate the thermodynamical properties of a single atomic layer of hexagonal boron nitride (h-BN). The thermal induced ripples, heat capacity, and thermal lattice expansion of large scale h-BN sheets are…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Sandeep Kumar Singh , M. Neek-Amal , S. Costamagna , F. M. Peeters

Polymer composites with thermally conductive nanoscale filler particles, such as graphene and hexagonal boron nitride (h-BN), are promising for certain heat transfer applications. While graphene-polymer composites have been extensively…

Applied Physics · Physics 2017-12-04 Ruimin Ma , Xiao Wan , Teng Zhang , Nuo Yang , Tengfei Luo

Principal characteristics of interlayer interaction and relative motion of hexagonal boron nitride (h-BN) layers are investigated by the first-principles method taking into account van der Waals interactions. Dependences of the interlayer…

Mesoscale and Nanoscale Physics · Physics 2016-04-13 Alexander V. Lebedev , Irina V. Lebedeva , Andrey A. Knizhnik , Andrey M. Popov

We report the mechanical properties of cubic boron nitride (c-BN) and diamond under the combined impact of dynamical pressure and temperature, calculated using ab initio molecular dynamics. Our study revealed a pronounced sensitivity of the…

Materials Science · Physics 2023-12-13 Srihari M. Kastuar , Zhong-Li Liu , Sina Najmaei , Chinedu E. Ekuma

The thermal conductivity of suspended few-layer hexagonal boron nitride (h-BN) was measured using a micro-bridge device with built-in resistance thermometers. Based on the measured thermal resistance values of 11-12 atomic layer h-BN…

Materials Science · Physics 2013-02-18 Insun Jo , Michael Thompson Pettes , Jaehyun Kim , Kenji Watanabe , Takashi Taniguchi , Zhen Yao , Li Shi

The needs for efficient heat removal and superior thermal conduction in nano/micro devices have triggered tremendous studies in low-dimensional materials with high thermal conductivity. Hexagonal boron nitride (h-BN) is believed to be one…

Mesoscale and Nanoscale Physics · Physics 2017-03-03 Xinxia Li , Yaping Yan , Lan Dong , Jie Guo , Adili Aiyiti , Xiangfan Xu , Baowen Li

We show that carbon-doped hexagonal boron nitride (h-BN) has extraordinary properties with many possible applications. We demonstrate that the substitution-induced impurity states, associated with carbon atoms, and their interactions…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Hyoungki Park , Amita Wadehra , John W. Wilkins , Antonio H. Castro Neto

In this paper we have theoretically found the activation energy ($420.38kJ/mol$) for the transformation from hBN to cBN in the microscopic viewpoint. We have introduced an analytical formula representing the dependence of nucleus formation…

Materials Science · Physics 2015-03-19 Su-Gon Kim , Yong-Sob Ri , Gwang-Il Jon , Song-Jin Im

Hexagonal boron nitride (h-BN) is unique among two-dimensional materials, with a large band gap (~6 eV) and high thermal conductivity (>400 W/m/K), second only to diamond among electrical insulators. Most electronic studies to date have…

We reported the basal-plane thermal conductivity in exfoliated bilayer hexagonal boron nitride h-BN that was measured using suspended prepatterned microstructures. The h-BN sample suitable for thermal measurements was fabricated by…

Mesoscale and Nanoscale Physics · Physics 2016-06-28 Chengru Wang , Jie Guo , Lan Dong , Adili Aiyiti , Xiangfan Xu , Baowen Li

Noting the structural relationships between phases of carbon and boron carbide with phases of boron nitride and boron subnitride, we investigate their mutual solubilities using a combination of first principles total energies supplemented…

Materials Science · Physics 2016-04-13 Hantao Zhang , Sanxi Yao , Michael Widom

A superhard boron nitride phase dubbed as Z-BN is proposed as possible intermediate phase between h-BN and zinc blende BN (c-BN), and investigated using first-principles calculations within the framework of the density functional theory.…

Materials Science · Physics 2012-06-12 Chaoyu He , L. Z. Sun , C. X. Zhang , Xiangyang Peng , K. W. Zhang , Jianxin Zhong

Two-dimensional hexagonal boron nitride (hBN) has attracted large attentions as platforms for realizations for integrated nanophotonics and collective effort has been focused on the spin defect centers. Here, the temperature dependence of…

We study the interfacial thermal conductance of grain boundaries (GBs) between monolayer graphene and hexagonal boron nitride (h-BN) sheets using a combined atomistic approach. First, realistic samples containing graphene/h-BN GBs with…

Materials Science · Physics 2022-01-03 Haikuan Dong , Petri Hirvonen , Zheyong Fan , Ping Qian , Yanjing Su , Tapio Ala-Nissila

Hexagonal boron nitride (h-BN) is a prominent member in the growing family of two-dimensional materials with potential applications ranging from being an atomically smooth support for other 2D materials to templating growth of molecular…

Boron nitride (BN) is a structurally versatile insulator since it can be found in several crystalline structures with interesting mechanical and electrical properties, making this material attractive for technological applications. Seeking…

Submonolayer h-BN was grown on Ni foil in ultra-high vacuum by the diffusion and precipitation method and the growth process was studied by x-ray photoelectron spectroscopy. Formation of h-BN started to be observed at 600 C. All through the…

Mesoscale and Nanoscale Physics · Physics 2019-07-03 Satoru Suzuki , Yuichi Haruyama

A new interlayer force-field for layered hexagonal boron nitride (h-BN) based structures is presented. The force-field contains three terms representing the interlayer attraction due to dispersive interactions, repulsion due to anisotropic…

Materials Science · Physics 2014-03-13 Itai Leven , Ido Azuri , Leeor Kronik , Oded Hod
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