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Next-generation lithium-ion batteries with silicon anodes have positive characteristics due to higher energy densities compared to state-of-the-art graphite anodes. However, the large volume expansion of silicon anodes can cause high…

Numerical Analysis · Mathematics 2024-04-03 R. Schoof , G. F. Castelli , W. Dörfler

The simulation of non-equilibrium electron distributions is essential for capturing light-metal interactions and therefore the study of photoabsorption, photocatalysis, laser ablation, and many other phenomena. Current methodologies, such…

Materials Science · Physics 2025-03-13 M. Uehlein , H. T. Snowden , C. Seibel , T. Held , S. T. Weber , R. J. Maurer , B. Rethfeld

Conventional lithium-ion batteries, and many next-generation technologies, rely on organic electrolytes with multiple solvents to achieve the desired physicochemical and interfacial properties. The complex interplay between these properties…

Soft Condensed Matter · Physics 2023-03-06 Zachary A. H. Goodwin , Michael McEldrew , Boris Kozinsky , Martin Z. Bazant

Accurate state of temperature (SOT) estimation for batteries is crucial for regulating their temperature within a desired range to ensure safe operation and optimal performance. The existing measurement-based methods often generate noisy…

Systems and Control · Electrical Eng. & Systems 2025-03-18 Myisha A. Chowdhury , Qiugang Lu

We formulate the continuum field equations and constitutive equations that govern deformation, stress, and electric current flow in a Li-ion half-cell. The model considers mass transport through the system, deformation and stress in the…

Computational Physics · Physics 2011-08-01 Allan F. Bower , Pradeep R. Guduru , Vijay A. Sethuraman

In this paper, a core-shell enhanced single particle model for iron-phosphate battery cells is formulated, implemented, and verified. Starting from the description of the positive and negative electrodes charge and mass transport dynamics,…

Systems and Control · Electrical Eng. & Systems 2022-09-26 Gabriele Pozzato , Aki Takahashi , Xueyan Li , Donghoon Lee , Johan Ko , Simona Onori

Polymer electrolytes (PEs) are promising candidates for use in next-generation high-voltage batteries, as they possess advantageous elastic and electrochemical properties. However, PEs still suffer from low ionic conductivity and need to be…

Understanding the performance of electrochemical energy storage systems requires probing the electrochemical properties at each layer and interface during cell operation. While traditional onboard and operando methods can measure impedance,…

Chemical Physics · Physics 2025-08-13 Divya Chalise , Sean D. Lubner , Sumanjeet Kaur , Venkat Srinivasan , Ravi S Prasher

Lithium-ion batteries are widely used in electric vehicles and grid energy storage systems. Compared to cylindrical batteries, prismatic cells are the primary choice because of their advantage for dense packing. However, thermal runaway and…

Applied Physics · Physics 2024-07-23 Mehdi V. Bozorg , Juan F. Torres

The penetrations of lithium-ion batteries in transport, energy and communication systems are increasing rapidly. A meticulous model applicable for precise in-situ monitoring and convenient online controlling is in sought to bridge the gap…

Systems and Control · Electrical Eng. & Systems 2022-03-22 Yuxuan Gu , Jianxiao Wang , Yuanbo Chen , Zhongwei Deng , Hongye Guo , Kedi Zheng , Qixin Chen

A precise understanding of solvation is essential for rational search and design of electrolytes that can meet performance demands in Li-ion and beyond Li-ion batteries. In the context of Li-O$_2$ batteries, ion pairing is decisive in…

We consider the mathematical treatment of a system of nonlinear partial differential equations based on a model, proposed in 1972 by J. Newman, in which the coupling between the Lithium concentration, the phase potentials and temperature in…

Analysis of PDEs · Mathematics 2022-02-23 Jesús Ildefonso Díaz , David Gómez-Castro , Angel Manuel Ramos

Li+ transport within a solid electrolyte interphase (SEI) in lithium ion batteries has challenged molecular dynamics (MD) studies due to limited compositional control of that layer. In recent years, experiments and ab initio simulations…

Chemical Physics · Physics 2018-01-29 Ajay Muralidharan , Mangesh I. Chaudhari , Lawrence R. Pratt , Susan B. Rempe

We present a coupled continuum formulation for the electrostatic, chemical, thermal and mechanical processes in battery materials. Our treatment applies on the macroscopic scale, at which electrodes can be modelled as porous materials made…

Chemical Physics · Physics 2017-07-25 Zhenlin Wang , Jason B. Siegel , Krishna Garikipati

Lithium-ion batteries rely on particulate porous electrodes to realize high performance, especially the fast-charging capability. To minimize the particle-wise reaction heterogeneities that may lead to local hot spots, deeper understandings…

Materials Science · Physics 2022-04-15 Shubham Agrawal , Peng Bai

This study examines the steady state characteristics of work extraction in a two cell and three cell quantum battery interacting with multiple thermal reservoirs. Employing the quantum master equation framework within the Born-Markov…

Quantum Physics · Physics 2025-02-11 Maryam Hadipour , Soroush Haseli

With the popularity of electric vehicles, the demand for lithium-ion batteries is increasing. Temperature significantly influences the performance and safety of batteries. Battery thermal management systems can effectively control the…

Machine Learning · Computer Science 2026-01-07 Zheng Liu , Yuan Jiang , Yumeng Li , Pingfeng Wang

We introduce a non-isothermal phase-field crystal model including heat flux and thermal expansion of the crystal lattice. The thermal compatibility condition, as well as a positive entropy-production property, is derived analytically and…

Materials Science · Physics 2025-01-23 Maik Punke , Marco Salvalaglio , Axel Voigt , Steven M. Wise

Lithium-ion batteries exhibit complex nonlinear dynamics, resulting from diffusion and phase transformations coupled to ion intercalation reactions. Using the recently developed Cahn-Hilliard reaction (CHR) theory, we investigate a simple…

Chemical Physics · Physics 2014-02-13 Yi Zeng , Martin Z. Bazant

Ensuring solid-state lithium batteries perform well across a wide temperature range is crucial for their practical use. Molecular dynamics (MD) simulations can provide valuable insights into the temperature dependence of the battery…

Materials Science · Physics 2024-03-22 Zicun Li , Jianxing Huang , Xinguo Ren , Jinbin Li , Ruijuan Xiao , Hong Li