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Spontaneous electric polarization of solid ferroelectrics follows aligning directions of crystallographic axes. Domains of differently oriented polarization are separated by domain walls (DWs), which are predominantly flat and run along…

Soft Condensed Matter · Physics 2023-03-01 Priyanka Kumari , Bijaya Basnet , Hao Wang , Oleg D. Lavrentovich

The newly-discovered ferroelectric nematic liquid crystal exhibits a variety of unique defect phenomena. The depolarization field in the material favors spontaneous spatial variations in polarization, manifesting in diverse forms such as…

Soft Condensed Matter · Physics 2025-07-17 Maxim O. Lavrentovich , Priyanka Kumari , Oleg D. Lavrentovich

Domain walls in ferroelectrics exhibit a plethora of phases and functionalities not found in the bulk. The interplay of electrostatic, chemical, topological, and distortive inhomogeneities at the walls can be so complex, however, that this…

Mesoscale and Nanoscale Physics · Physics 2017-02-23 Gabriele De Luca , Marta D. Rossell , Jakob Schaab , Nathalie Viart , Manfred Fiebig , Morgan Trassin

Surface interactions are responsible for many properties of condensed matter, ranging from crystal faceting to the kinetics of phase transitions. Usually, these interactions are polar along the normal to the interface and apolar within the…

We report the experimental determination of the structure and response to applied electric field of the lower-temperature nematic phase of the previously reported calamitic compound 4-[(4-nitrophenoxy)carbonyl]phenyl2,4-dimethoxybenzoate…

To minimize their electrostatic energy, insulating ferroelectric films tend to break up into nanoscale ``Kittel'' domains of opposite polarization that are separated by uncharged 180$^\circ$ domain walls. Here, I report on self-consistent…

Mesoscale and Nanoscale Physics · Physics 2022-10-14 W. A. Atkinson

Ferroelectric nematic liquid crystals are polar fluids characterized by microscopic orientational ordering and macroscopic spontaneous polarizations. Within these fluids, walls that separate domains of different polarizations are…

Soft Condensed Matter · Physics 2024-06-21 Shengzhu Yi , Zening Hong , Zhongjie Ma , Chao Zhou , Miao Jiang , Xiang Huang , Mingjun Huang , Satoshi Aya , Rui Zhang , Qi-Huo Wei

Using the self-consistent Landau-Ginzburg-Devonshire approach we simulate and analyze the spontaneous formation of the domain structure in thin ferroelectric films covered with the surface screening charge of the specific nature…

Charge manipulation and fabrication of stable domain patterns in ferroelectric materials by scanning probe microscopy open up broad avenues for the development of tunable electronics. Harnessing the polarization energy and electrostatic…

Materials Science · Physics 2021-02-08 S. Kondovych , A. Gruverman , I. Luk'yanchuk

A promising approach in designing composite materials with unusual physical behavior combines solid nanostructures and orientationally ordered soft matter at the mesoscale. Such composites not only inherit properties of their constituents…

Soft Condensed Matter · Physics 2017-01-19 Andrew J. Hess , Qingkun Liu , Ivan I. Smalyukh

Domain walls are the topological defects that mediate polarization reversal in ferroelectrics, and they may exhibit quite different geometric and electronic structures compared to the bulk. Therefore, a detailed atomic-scale understanding…

Materials Science · Physics 2017-01-12 Meng Ye , David Vanderbilt

We consider a typical heterostructure domain patterned ferroelectric film/ultra thin dielectric layer/ semiconductor, where the semiconductor can be an electrolyte, paraelectric or multi layered graphene. Unexpectedly we have found that the…

The properties of a ferroelectric, (001)-oriented, thin film clamped to a substrate are investigated analytically and numerically. The emphasis is on the tetragonal, polydomain, ferroelectric phase, using a three domain structure, as is…

Materials Science · Physics 2019-02-08 E. P. Houwman , K. Vergeer , G. Koster , G. Rijnders

We show that, contrary to common belief, the depolarizing electric field generated by bound charges at thin-film surfaces can have a substantial impact on the domain structure of an improper ferroelectric with topological defects. In…

Materials Science · Physics 2025-10-16 Aaron Merlin Müller , Amadé Bortis , Arkadiy Simonov , Manfred Fiebig , Thomas Lottermoser

Elastic constants of splay K_11, twist K_22, and bend K_33 of nematic liquid crystals are often assumed to be equal to each other in order to simplify the theoretical description of complex director fields. Here we present examples of how…

Soft Condensed Matter · Physics 2024-03-19 Oleg D. Lavrentovich

When subjected to electro-mechanical loading, ferroelectrics see their polarization evolve through the nucleation and evolution of domains. Existing mesoscale phase-field models for ferroelectrics are typically based on a gradient-descent…

Materials Science · Physics 2023-05-10 Laurent Guin , Dennis Kochmann

Domain walls in ferroelectric oxides provide fertile ground for the development of next-generation nanotechnology. Examples include domain-wall-based memory, memristors, and diodes, where the unusual electronic properties and the quasi-2D…

Ferroelectric nematics present properties promising for applications, which strongly depend on the confinement conditions and the presence of defects. In this work, we have observed and analysed textures in the cells with homogeneous…

Soft Condensed Matter · Physics 2024-01-04 Vladimira Novotna , Lubor Lejcek , Natalia Podoliak

The conductance of domain wall structures consisting of either stripes or cylindrical domains in multi-axial ferroelectric-semiconductors is analyzed. The effects of the domain size, wall tilt and curvature, on charge accumulation, are…

Topological spin and polar textures have fascinated people in different areas of physics and technologies. However, the observations are limited in magnetic and solid-state ferroelectric systems. Ferroelectric nematic is the first…

Soft Condensed Matter · Physics 2022-12-22 Jidan Yang , Yu Zou , Wentao Tang , Jinxing Li , Mingjun Huang , Satoshi Aya
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