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A new perturbative approach to canonical equation-of-motion coupled-cluster theory is presented using coupled-cluster perturbation theory. A second-order M{\o}ller-Plesset partitioning of the Hamiltonian is used to obtain the well known…

Chemical Physics · Physics 2015-07-09 Jason N. Byrd , Varun Rishi , Ajith Perera , Rodney J. Bartlett

We present a new linear scaling method for the energy minimization step of semiempirical and first-principles Hartree-Fock and Kohn-Sham calculations. It is based on the self-consistent calculation of the optimum localized orbitals of any…

Materials Science · Physics 2009-11-10 Luis Seijo , Zoila Barandiaran

This paper presents the first application of the direct parametrisation method for invariant manifolds to a fully coupled multiphysics problem involving the nonlinear vibrations of deformable structures subjected to an electrostatic field.…

Numerical Analysis · Mathematics 2023-12-25 Attilio Frangi , Alessio Colombo , Alessandra Vizzaccaro , Cyril Touzé

Mesoscopic theory for self-assembling systems near a planar confining surface is developed. Euler- Lagrange (EL) equations and the boundary conditions (BC) for the local volume fraction and the correlation function are derived from the DFT…

Statistical Mechanics · Physics 2020-01-03 A. Ciach

The present article is concerned with the use of approximations in the calculation of the many-body density of states (MBDS) of a system with total energy E, composed by N bosons. In the mean-field framework, an integral expression for…

Statistical Mechanics · Physics 2014-11-17 Alexandre Dias Ribeiro

For adaptive mixed finite element methods (AMFEM), we first introduce the data oscillation to analyze, without the restriction that the inverse of the coefficient matrix of the partial differential equations (PDEs) is a piecewise polynomial…

Numerical Analysis · Mathematics 2011-01-07 Shaohong Du , Xiaoping Xie

A Block Structure Preserving Model Order Reduction approach is proposed for Integral Equations methods based on the Augmented Electric Field Integral Equation. This approach allows for representing the unknown fields with dedicated…

Computational Engineering, Finance, and Science · Computer Science 2025-11-18 Riccardo Torchio , Sebastian Schöps , Francesco Lucchini

We present and analyze results of the relativistic coupled-cluster calculation of energies, hyperfine constants, and dipole matrix elements for the $2s$, $2p_{1/2}$, and $2p_{3/2}$ states of Li atom. The calculations are complete through…

Atomic Physics · Physics 2011-07-13 A. Derevianko , S. G. Porsev , K. Beloy

A formalism for energy-dependent many-body perturbation theory (MBPT), previously indicated in our recent review articles (Lindgren et al., Phys.Rep. 389,161(2004), Can.J.Phys. 83,183(2005)), is developed in more detail. The formalism…

Quantum Physics · Physics 2009-11-13 Ingvar Lindgren , Sten Salomonson , Daniel Hedendahl

In the present work, a multi-scale framework for neural network enhanced methods is proposed for approximation of function and solution of partial differential equations (PDEs). By introducing the multi-scale concept, the total solution of…

Numerical Analysis · Mathematics 2022-09-07 Xiaodan Ren

This paper gives a systematic method for constructing an N-body potential, approximating the true potential, that accurately captures meso-scale behavior of the chemical or biological system using pairwise potentials coming from…

Chemical Physics · Physics 2016-05-19 Gunjan S. Thakur , Ryan Mohr , Igor Mezić

In this second part of our series on the recently proposed many-body expanded full configuration interaction (MBE-FCI) method, we introduce the concept of multideterminantal expansion references. Through theoretical arguments and numerical…

Chemical Physics · Physics 2019-09-23 Janus J. Eriksen , Jürgen Gauss

From a mathematical perspective, the extraordinary properties of metamaterials are often reflected in the coefficients of the governing partial differential equations (PDEs). These coefficients may fall outside the assumptions of classical…

Numerical Analysis · Mathematics 2026-05-22 Eric T. Chung , Patrick Ciarlet , Xingguang Jin , Changqing Ye

This paper applies the Bayesian Model Averaging (BMA) statistical ensemble technique to estimate small molecule solvation free energies. There is a wide range of methods available for predicting solvation free energies, ranging from…

Biomolecules · Quantitative Biology 2016-12-16 Luke J. Gosink , Christopher C. Overall , Sarah M. Reehl , Paul D. Whitney , David L. Mobley , Nathan A. Baker

A multi-modal multi-objective optimization problem is a special kind of multi-objective optimization problem with multiple Pareto subsets. In this paper, we propose an efficient multi-modal multi-objective optimization algorithm based on…

Neural and Evolutionary Computing · Computer Science 2020-04-22 Yiming Peng , Hisao Ishibuchi

By partitioning the electron density into subsystem contributions, the Frozen Density Embedding (FDE) formulation of subsystem DFT has recently emerged as a powerful tool for reducing the computational scaling of Kohn--Sham DFT. To date,…

Materials Science · Physics 2015-06-22 Alessandro Genova , Davide Ceresoli , Michele Pavanello

The introduction of Physics-informed Neural Networks (PINNs) has led to an increased interest in deep neural networks as universal approximators of PDEs in the solid mechanics community. Recently, the Deep Energy Method (DEM) has been…

Computational Engineering, Finance, and Science · Computer Science 2022-01-26 Jan N. Fuhg , Nikolaos Bouklas

In this work, the development and implementation of the effective stochastic potential (ESP) method is presented to perform efficient conformational sampling of molecules. The overarching goal of this work is to alleviate the computational…

Chemical Physics · Physics 2018-08-01 Jeremy A. Scher , Michael G. Bayne , Amogh Srihari , Shikha Nangia , Arindam Chakraborty

X-ray photoelectron spectroscopy (XPS) measures core-electron binding energies (CEBEs) to reveal element-specific insights into chemical environment and bonding. Accurate theoretical CEBE prediction aids XPS interpretation but requires…

Chemical Physics · Physics 2024-08-13 Anton Morgunov , Henry K. Tran , Oinam Romesh Meitei , Yu-Che Chien , Troy Van Voorhis

In this paper, we consider the offline and online Constraint Energy Minimizing Generalized Mul- tiscale Finite Element Method (CEM-GMsFEM) for high-contrast linear elasticity problem. Offline basis construction starts with an auxiliary…

Numerical Analysis · Mathematics 2018-09-12 Shubin Fu , Eric T. Chung