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We present a precise fully relativistic numerical solution of the two-center Coulomb problem. The special case of unit nuclear charges is relevant for the accurate description of the ${\rm H}_2^+$ molecular ion and its isotopologues,…

Quantum Physics · Physics 2022-05-11 O. Kullie , S. Schiller

The Dirac equation for H$_2^+$ is solved numerically by expansion in a basis set of two-center exponential functions, using different kinetic balance schemes. Very high precision (27-32 digits) is achieved, either with the dual kinetic…

Atomic Physics · Physics 2023-05-10 Hugo D. Nogueira , Jean-Philippe Karr

We introduce \texttt{featom}, an open source code that implements a high-order finite element solver for the radial Schr\"odinger, Dirac, and Kohn-Sham equations. The formulation accommodates various mesh types, such as uniform or…

The electronic spectra of light one-electron quasi-molecular compounds H-H$^+$, He$^+$-He$^2+$ and He$^+$-H$^+$ are analyzed. To this end, the two-center Dirac equation is solved by the dual-kinetically balanced finite-basis-set method for…

Atomic Physics · Physics 2025-09-11 D. Solovyev , A. Anikin , A. Danilov , D. Glazov , A. Kotov

A challenging difficulty in solving the radial Dirac eigenvalue problem numerically is the presence of spurious (unphysical) eigenvalues among the correct ones that are neither related to mathematical interpretations nor to physical…

Mathematical Physics · Physics 2011-12-13 Hasan Almanasreh , Sten Salomonson , Nils Svanstedt

The rigorous two-center approach based on the dual-kinetically balanced finite-basis-set expansion is applied to one-electron, heteronuclear diatomic Bi-Au, U-Pb, and Cf-U quasimolecules. The obtained $1\sigma$ ground-state energies are…

The solutions of elliptic problems with a Dirac measure in right-hand side are not H1 and therefore the convergence of the finite element solutions is suboptimal. Graded meshes are standard remedy to recover quasi-optimality, namely…

Numerical Analysis · Mathematics 2015-07-17 Silvia Bertoluzza , Astrid Decoene , Loïc Lacouture , Sébastien Martin

A finite element method using B-splines is presented and compared with a conventional finite element method of Lagrangian type. The efficiency of both methods has been investigated at the example of a coupled non-linear system of Dirac…

Nuclear Theory · Physics 2009-10-31 W. Poeschl

In this chapter we focus first on the theoretical methods and relevant computational approaches to calculate the electronic structure of atoms, molecules, and clusters containing heavy elements for which relativistic effects become…

Chemical Physics · Physics 2021-10-05 Simone Taioli , Stefano Simonucci

Obtaining high-precision guaranteed lower eigenvalue bounds remains difficult, even though the standard high-order conforming finite element (FEM) easily yields extremely sharp upper bounds. Recently developed rigorous approaches using such…

Numerical Analysis · Mathematics 2025-12-30 Xuefeng Liu , Michael Plum

The Dirac equation for H$_2^+$ is solved numerically using an iterative method proposed by Kutzelnigg [Z. Phys. 11, 15 (1989]. The four-component wavefunction is expanded in a newly introduced kinetically balanced exponential basis set. The…

Atomic Physics · Physics 2022-06-15 Hugo D. Nogueira , Vladimir I. Korobov , Jean-Philippe Karr

Using the standard finite element method (FEM) to solve general partial differential equations, the round-off error is found to be proportional to $N^{\beta_{\rm R}}$, with $N$ the number of degrees of freedom (DoFs) and $\beta_{\rm R}$ a…

Numerical Analysis · Mathematics 2022-02-08 Jie Liu , Henk M. Schuttelaars , Matthias Möller

Particle breakage due to collisional interactions plays a vital role in the development of several phenomena in science and engineering. The nonlinear collisional breakage equations (NCBEs) are a significant set of equations in this…

Numerical Analysis · Mathematics 2026-04-14 Arushi Arushi , Naresh Kumar

The adaptive nonconforming Morley finite element method (FEM) approximates a regular solution to the von K\'{a}rm\'{a}n equations with optimal convergence rates for sufficiently fine triangulations and small bulk parameter in the D\"orfler…

Numerical Analysis · Mathematics 2020-11-18 Carsten Carstensen , Neela Nataraj

We present and analyze a linearized finite element method (FEM) for the dynamical incompressible magnetohydrodynamics (MHD) equations. The finite element approximation is based on mixed conforming elements, where Taylor--Hood type elements…

Numerical Analysis · Mathematics 2019-02-20 Huadong Gao , Weifeng Qiu

A simple and reliable finite difference approach is presented for solution of the Dirac equation eigenproblem for states confined in rotationally symmetric systems. The method sets the boundary condition for the spinor wave function…

Mesoscale and Nanoscale Physics · Physics 2019-05-08 B. Szafran , A. Mrenca-Kolasinska , D. Zebrowski

In this paper, we present a finite element method (FEM) framework enhanced by an operator-adapted wavelet decomposition algorithm designed for the efficient analysis of multiscale electromagnetic problems. Usual adaptive FEM approaches,…

Computational Physics · Physics 2026-02-18 F. Şık , F. L. Teixeira , B. Shanker

Thanks to a finite element method, we solve numerically parabolic partial differential equations on complex domains by avoiding the mesh generation, using a regular background mesh, not fitting the domain and its real boundary exactly. Our…

Numerical Analysis · Mathematics 2023-03-22 Michel Duprez , Vanessa Lleras , Alexei Lozinski , Killian Vuillemot

The Morley finite element method (FEM) is attractive for semilinear problems with the biharmonic operator as a leading term in the stream function vorticity formulation of 2D Navier-Stokes problem and in the von K\'{a}rm\'{a}n equations.…

Numerical Analysis · Mathematics 2019-12-19 Carsten Carstensen , Gouranga Mallik , Neela Nataraj

In this paper, we provide a procedure to solve the eigen solutions of Dirac equation with complicated potential approximately. At first, we solve the eigen solutions of a linear Dirac equation with complete eigen system, which approximately…

General Physics · Physics 2017-12-08 Ying-Qiu Gu
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