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More than 30 years ago Edwards and co-authors proposed a model to describe the statistics of granular packings by an ensemble of equiprobable jammed states. Experimental tests of this model remained scarce so far. We introduce a simple…

When electron correlations are important it is often necessary to use numerical methods to solve the Hamiltonian for a finite system (cluster) "exactly". Unfortunately, such methods are restricted to small systems. We propose to combine the…

Strongly Correlated Electrons · Physics 2009-10-31 Maciej M. Maska

The excited states of polyatomic systems are rather complex, and often exhibit meta-stable dynamical behaviors. Static analysis of reaction pathway often fails to sufficiently characterize excited state motions due to their highly…

Chemical Physics · Physics 2017-08-22 Fang Liu , Likai Du , Dongju Zhang , Jun Gao

Bifurcations in a system of coupled maps are investigated. Using symbolic dynamics it is proven that for coupled shift maps the well known space--time--mixing attractor becomes unstable at a critical coupling strength in favour of a…

chao-dyn · Physics 2016-08-14 Wolfram Just

We apply Coupled Cluster Method to a strongly correlated lattice and develop the Spectral Coupled Cluster equations by finding an approximation to the resolvent operator, that gives the spectral response for an certain class of probe…

Strongly Correlated Electrons · Physics 2012-07-03 Alessandro Mirone

Cluster dynamics and single-particle correlation are simultaneously treated for the description of the ground state of ${}^{12} \mathrm{C} $. The recent development of the antisymmetrized quasi cluster model (AQCM) makes it possible to…

Nuclear Theory · Physics 2021-04-06 Naoyuki Itagaki , Tomoya Naito

We generalize the Aufbau suppressed coupled cluster formalism into the realm of doubly excited states by deriving, implementing, and testing a wave function initialization strategy that allows the zeroth order wave function to match the…

Chemical Physics · Physics 2026-05-11 Qasim Javed , Harrison Tuckman , Eric Neuscamman

Quantum embedding methods have recently developed significantly to model large molecular structures. This work proposes a novel wave function theory in density functional theory (WTF-in-DFT) embedding scheme based on pair-coupled cluster…

Chemical Physics · Physics 2024-01-10 Rahul Chakraborty , Katharina Boguslawski , Paweł Tecmer

Quantum cluster approaches offer new perspectives to study the complexities of macroscopic correlated fermion systems. These approaches can be understood as generalized mean-field theories. Quantum cluster approaches are non-perturbative…

Strongly Correlated Electrons · Physics 2009-11-10 Th. Maier , M. Jarrell , Th. Pruschke , M. H. Hettler

In 2D bosonic systems ultra-soft interactions develop an interesting phenomenology that ultimately leads to the appearance of supersolid phases in free space conditions. While suggested in early theoretical works and despite many further…

Quantum Gases · Physics 2021-07-14 Alejandro Mendoza-Coto , Diogo de Souza Caetano , Rogelio Díaz-Méndez

Density functional theory can be extended to excited states by means of a unified variational approach for passive state ensembles. This extension overcomes the restriction of the typical density functional approach to ground states, and…

Chemical Physics · Physics 2019-07-10 Tim Gould , Stefano Pittalis

The topic of the review is the application of new ideas of unconventional quantum states to the physics of condensed matter, in particular of solid state, in the context of modern field theory. A comparison is made with classical papers on…

Strongly Correlated Electrons · Physics 2019-11-19 V. Yu. Irkhin , Yu. N. Skryabin

We present several coupled-cluster calculations of ground and excited states of 4He and 16O employing methods from quantum chemistry. A comparison of coupled cluster results with the results of exact diagonalization of the hamiltonian in…

The perturbation theory in QED used the new form of ground state as a state of interacted particles is proposed. The mean electromagnetic field of charged elementary particle is calculated. The possibility of elimination the problem with…

Quantum Physics · Physics 2007-05-23 G. M. Filippov

A variant of coupled-cluster theory is described here, wherein the degrees of freedom are fluctuations of fragments between internally correlated states. The effects of intra-fragment correlation on the inter-fragment interaction are…

Chemical Physics · Physics 2019-05-24 Yuhong Liu , Anthony D. Dutoi

An implementation of the coupled-cluster single- and double excitations (CCSD) method on two-dimensional quantum dots is presented. Advantages and limitations are studied through comparison with other high accuracy approaches for two to…

Mesoscale and Nanoscale Physics · Physics 2013-05-30 Erik Waltersson , Eva Lindroth

We introduce an approach to improve single-reference coupled cluster theory in settings where the Aufbau determinant is absent from or plays only a small role in the true wave function. Using a de-excitation operator that can be efficiently…

Chemical Physics · Physics 2024-07-03 Harrison Tuckman , Eric Neuscamman

Generalized Ising models, also known as cluster expansions, are an important tool in many areas of condensed-matter physics and materials science, as they are often used in the study of lattice thermodynamics, solid-solid phase transitions,…

Statistical Mechanics · Physics 2016-06-27 Wenxuan Huang , Daniil Kitchaev , Stephen Dacek , Ziqin Rong , Zhiwei Ding , Gerbrand Ceder

The accurate and efficient description of strongly correlated systems remains an important challenge for computational methods. Doubly occupied configuration interaction (DOCI), in which all electrons are paired and no correlations which…

Chemical Physics · Physics 2016-02-25 Thomas M. Henderson , Ireneusz W. Bulik , Gustavo E. Scuseria

We describe a coupled cluster framework for coupled systems of electrons and phonons. Neutral and charged excitations are accessed via the equation-of-motion version of the theory. Benchmarks on the Hubbard-Holstein model allow us to assess…

Materials Science · Physics 2021-02-03 Alec F. White , Yang Gao , Austin J. Minnich , Garnet Kin-Lic Chan