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Related papers: Enzymatic Mpemba Effect: Slowing of biochemical re…

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The Mpemba effect is a counter-intuitive relaxation phenomenon, where a system prepared at a hot temperature cools down faster than an identical system initiated at a cold temperature when both are quenched to an even colder bath. Such…

Statistical Mechanics · Physics 2019-07-03 Israel Klich , Oren Raz , Ori Hirschberg , Marija Vucelja

We examine the stochastic dynamics of two enzymes that are mechanically coupled to each other, e.g., through an elastic substrate or a fluid medium. The enzymes undergo conformational changes during their catalytic cycle, which itself is…

Statistical Mechanics · Physics 2021-11-16 Jaime Agudo-Canalejo , Tunrayo Adeleke-Larodo , Pierre Illien , Ramin Golestanian

The Mpemba effect (MpE), where a far-from-equilibrium state of a system relaxes faster compared to a state closer to it, is a well-known counterintuitive phenomenon in classical and quantum systems. Various system-specific theories have…

Quantum Physics · Physics 2025-12-11 Gourab Das

Enzymes have been recently found to exhibit enhanced diffusion due to their catalytic activities. A recent experiment [C. Riedel et al., Nature 517, 227 (2015)] has found evidence that suggests this phenomenon might be controlled by the…

Biomolecules · Quantitative Biology 2015-09-30 Ramin Golestanian

The so-called Mpemba effect, i.e. the observation that the warmer of two otherwise identical systems cools faster when both are refrigerated in the same thermal reservoir, is a hotly debated topic in condensed mater physics and statistical…

Materials Science · Physics 2019-09-11 A. Gijón , A. Lasanta , E. R. Hernández

The Mpemba effect is a counterintuitive physical phenomenon where a hot system cools faster than a warm one. In recent years, theoretical analyses of the Mpemba effect have been developed for microscopic systems and experimentally verified.…

Statistical Mechanics · Physics 2025-03-12 Tan Van Vu , Hisao Hayakawa

We explore the role of activity in the occurrence of the Mpemba effect within a system of an active colloid diffusing in a potential landscape devoid of metastable minimum. The Mpemba effect is characterized by a phenomenon where a hotter…

Statistical Mechanics · Physics 2025-05-27 Apurba Biswas , R. Rajesh

The cytoplasm of a living cell is crowded with several macromolecules of different shapes and sizes. Molecular diffusion in such a medium becomes anomalous due to the presence of macromolecules and diffusivity is expected to decrease with…

Statistical Mechanics · Physics 2009-11-13 Manish Agrawal , S. B. Santra , Rajat Anand , Rajaram Swaminathan

The Mpemba effect is a fingerprint of the anomalous relaxation phenomenon wherein an initially hotter system equilibrates faster than an initially colder system when both are quenched to the same low temperature. Experiments on a single…

Statistical Mechanics · Physics 2023-08-16 Apurba Biswas , R. Rajesh , Arnab Pal

The Mpemba effect, where a hotter system can equilibrate faster than a cooler one, has long been a subject of fascination in classical physics. In the past few years, significant theoretical and experimental progress has been made in…

Statistical Mechanics · Physics 2025-09-10 Filiberto Ares , Pasquale Calabrese , Sara Murciano

In this work we study, at the single molecular level, the thermodynamic and dynamic characteristics of an enzymatic reaction comprising a rate limiting step. We investigate how the stability of the enzyme-state stationary probability…

Subcellular Processes · Quantitative Biology 2015-05-20 Moisés Santillán

Slow relaxation processes spanning widely separated timescales pose fundamental challenges for probing steady-state properties and engineering functional quantum systems, such as quantum heat engines and quantum computing devices. We…

Quantum Physics · Physics 2025-10-20 Ruicheng Bao , Zhonghuai Hou

Mpemba effect refers to the counterintuitive phenomenon of a hotter system equilibrating faster than a colder system when both are quenched to the same low temperature. For a Brownian particle trapped in a piece-wise linear single well…

Statistical Mechanics · Physics 2023-05-12 Apurba Biswas , R. Rajesh

The Mpemba effect was originally referred to as the faster icing of a higher-temperature system than a lower-temperature system, and was later generalized to anomalous decays of both classical and quantum observables to equilibrium states.…

Quantum Physics · Physics 2024-10-15 Xuanhua Wang , Jin Wang

The Mpemba effect, an example of anomalous thermal relaxations, occurs when a system prepared at a hot temperature overtakes an identical system prepared at a warm temperature and cools down faster to the environment's temperature. We study…

Statistical Mechanics · Physics 2023-08-10 Saikat Bera , Matthew R. Walker , Marija Vucelja

The Mpemba effect is a phenomenon in which an initially hotter sample cools sooner. In this paper, we show the emergence of a non-monotonic Mpemba-like effect in a molecular binary mixture immersed in a viscous gas. Namely, a crossover in…

Soft Condensed Matter · Physics 2021-06-10 Rubén Gómez González , Vicente Garzó

The Mpemba effect refers to systems whose thermal relaxation time is a non-monotonic function of the initial temperature. Thus, a system that is initially hot cools to a bath temperature more quickly than the same system, initially warm. In…

Statistical Mechanics · Physics 2021-03-31 Raphaël Chétrite , Avinash Kumar , John Bechhoefer

The Mpemba effect and its inverse can be understood as a result of nonequilibrium thermodynamics. In polymers, changes of state are generally non-equilibrium processes. However, the Mpemba effect has been rarely reported in the…

Soft Condensed Matter · Physics 2023-04-28 Jinghua Liu , Jingqing Li , Binyuan Liu , Ian W. Hamley , Shichun Jiang

Mpemba effect refers to the counterintuitive result that, when quenched to a low temperature, a system at higher temperature may equilibrate faster than one at intermediate temperatures. This effect has recently been demonstrated in driven…

Statistical Mechanics · Physics 2020-07-27 Apurba Biswas , V . V. Prasad , O. Raz , R. Rajesh

Several different enzymes display an apparent diffusion coefficient that increases with the concentration of their substrate. Moreover, their motion becomes directed in substrate gradients. Currently, there are several competing models for…

Biological Physics · Physics 2020-09-23 Giovanni Giunta , Hamid Seyed-Allaei , Ulrich Gerland
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