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We develop an efficient algorithm, coordinate descent FCI (CDFCI), for the electronic structure ground state calculation in the configuration interaction framework. CDFCI solves an unconstrained non-convex optimization problem, which is a…

Chemical Physics · Physics 2019-07-03 Zhe Wang , Yingzhou Li , Jianfeng Lu

An efficient excited state method, named xCDFCI, in the configuration interaction framework, is proposed. xCDFCI extends the unconstrained nonconvex optimization problem in coordinate descent full configuration interaction~(CDFCI) to a…

Chemical Physics · Physics 2023-08-23 Zhe Wang , Zhiyuan Zhang , Jianfeng Lu , Yingzhou Li

CDFCI is a shared-memory parallel numerical program for computing low-lying eigenpairs of large-scale, non-relativistic fermionic Hamiltonians. The software is designed to handle a broad class of many-body quantum models, including both ab…

Computational Physics · Physics 2026-05-08 Yuejia Zhang , Zhe Wang , Jianfeng Lu , Yingzhou Li

Full configuration interaction (FCI) solvers are limited to small basis sets due to their expensive computational costs. An optimal orbital selection for FCI (OptOrbFCI) is proposed to boost the power of existing FCI solvers to pursue the…

Chemical Physics · Physics 2020-09-01 Yingzhou Li , Jianfeng Lu

We consider gradient descent and quasi-Newton algorithms to optimize the full configuration interaction (FCI) ground state wavefunction starting from an arbitrary reference state $|0 \rangle$. We show that the energies obtained along the…

Chemical Physics · Physics 2021-02-03 Carlos A. Jiménez-Hoyos

In this paper we propose a parallel coordinate descent algorithm for solving smooth convex optimization problems with separable constraints that may arise e.g. in distributed model predictive control (MPC) for linear network systems. Our…

Optimization and Control · Mathematics 2014-11-19 Ion Necoara , Dragos Clipici

Recently, a new distributed implementation of the full configuration interaction (FCI) method has been reported [Gao et al. J. Chem Theory Comput. 2024, 20, 1185]. Thanks to a hybrid parallelization scheme, the authors were able to compute…

We present NECI, a state-of-the-art implementation of the Full Configuration Interaction Quantum Monte Carlo algorithm, a method based on a stochastic application of the Hamiltonian matrix on a sparse sampling of the wave function. The…

We propose an efficient deterministic method to calculate the full configuration interaction (FCI) ground state energy. This method leverages the sparseness of the Lanczos basis vectors that span the Krylov subspace associated with the…

Chemical Physics · Physics 2024-01-08 Lijun Wang

A new large-scale parallel multiconfigurational self-consistent field (MCSCF) implementation in the open-source NWChem computational chemistry code is presented. The generalized active space (GAS) approach is used to partition large…

Chemical Physics · Physics 2026-01-06 Konstantinos D. Vogiatzis , Dongxia Ma , Jeppe Olsen , Laura Gagliardi , Wibe de Jong

We present a detailed benchmark comparing two state-of-the-art phase-field implementations for simulating alloy solidification under experimentally relevant conditions. The study investigates the directional solidification of Al-3wt%Cu…

Materials Science · Physics 2026-04-30 Jiefu Tian , David Montiel , Kaihua Ji , Trevor Lyons , Jason Landini , Katsuyo Thornton , Alain Karma

In this work we propose a novel approach to solve the Schr\"{o}dinger equation which combines projection onto the ground state with a path-filtering truncation scheme. The resulting projector configuration interaction (PCI) approach…

Chemical Physics · Physics 2016-06-29 Tianyuan Zhang , Francesco A. Evangelista

Multi-view image compression (MIC) aims to achieve high compression efficiency by exploiting inter-image correlations, playing a crucial role in 3D applications. As a subfield of MIC, distributed multi-view image compression (DMIC) offers…

Computer Vision and Pattern Recognition · Computer Science 2026-03-05 Haotian Zhang , Feiyue Long , Yixin Yu , Jian Xue , Haocheng Tang , Tongda Xu , Zhenning Shi , Yan Wang , Siwei Ma , Jiaqi Zhang

This work explores the ability of classical electronic structure methods to efficiently represent (compress) the information content of full configuration interaction (FCI) wave functions. We introduce a benchmark set of four hydrogen model…

Chemical Physics · Physics 2020-08-20 Nicholas H. Stair , Francesco A. Evangelista

Incremental full configuration interaction (iFCI) is polynomial-cost approach to the FCI limit of electronic structure. This article introduces the many-body basis set amelioration (MBBSA) method, which is designed to allow iFCI to be…

Chemical Physics · Physics 2025-03-12 Jeffrey P Hatch , Alan E Rask , Duy-Khoi Dang , Paul M Zimmerman

We develop a multi-dimensional, parallelized domain decomposition strategy (DDC) for mass-transfer particle tracking (MTPT) methods. These methods are a type of Lagrangian algorithm for simulating reactive transport and are able to be…

Selected configuration interaction (sCI) methods including second-order perturbative corrections provide near full CI (FCI) quality energies with only a small fraction of the determinants of the FCI space. Here, we introduce both a…

Chemical Physics · Physics 2018-08-09 Yann Garniron , Anthony Scemama , Emmanuel Giner , Michel Caffarel , Pierre-François Loos

The semistochastic heat-bath configuration interaction (SHCI) method is a selected configuration interaction plus perturbation theory method that has provided near-full configuration interaction (FCI) levels of accuracy for many systems…

Chemical Physics · Physics 2021-11-30 Yuan Yao , Emmanuel Giner , Tyler A. Anderson , Julien Toulouse , C. J. Umrigar

Inter-cell interference (ICI) suppression is critical for multi-cell multi-user networks. In this paper, we investigate advanced precoding techniques for coordinated multi-point (CoMP) with downlink coherent joint transmission, an effective…

Signal Processing · Electrical Eng. & Systems 2024-03-29 Xinyu Bian , Yuhao Liu , Yizhou Xu , Tianqi Hou , Wenjie Wang , Yuyi Mao , Jun Zhang

We propose a novel approach to solving input- and state-constrained parametric mixed-integer optimal control problems using Differentiable Predictive Control (DPC). Our approach follows the differentiable programming paradigm by learning an…

Systems and Control · Electrical Eng. & Systems 2025-06-25 Ján Boldocký , Shahriar Dadras Javan , Martin Gulan , Martin Mönnigmann , Ján Drgoňa
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