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Quantum chemistry has been viewed as one of the potential early applications of quantum computing. Two techniques have been proposed for electronic structure calculations: (i) the variational quantum eigensolver and (ii) the…

Quantum Physics · Physics 2021-04-19 Christina Daniel , Diksha Dhawan , Dominika Zgid , James K. Freericks

In this paper, we consider the Markov-Chain Monte Carlo (MCMC) approach for random sampling of combinatorial objects. The running time of such an algorithm depends on the total mixing time of the underlying Markov chain and is unknown in…

Discrete Mathematics · Computer Science 2016-09-15 Steffen Rechner , Annabell Berger

MCMC algorithms offer empirically efficient tools for sampling from a target distribution $\pi(x) \propto \exp(-V(x))$. However, on the theory side, MCMC algorithms suffer from slow mixing rate when $\pi(x)$ is non-log-concave. Our work…

Machine Learning · Computer Science 2024-01-17 Xiang Cheng , Bohan Wang , Jingzhao Zhang , Yusong Zhu

Hybrid quantum systems with different particle species are fundamental in quantum materials and quantum information science. In this work, we establish a rigorous theoretical framework proving that, given access to an unknown spin-boson…

Quantum Physics · Physics 2025-05-01 Lixing Zhang , Ze-Xun Lin , Prineha Narang , Di Luo

While quantum simulation is one of the most promising applications of modern quantum devices, accessible simulation times are fundamentally limited by finite coherence times due to omnipresent noise. Based on the ideas of relational…

Quantum Physics · Physics 2025-09-03 Sebastian Gemsheim , Felix Fritzsch

We present a detailed study of the quantum dissipative dynamics of a charged particle in a magnetic field. Our focus of attention is the effect of dissipation on the low- and high-temperature behavior of the specific heat at constant…

Statistical Mechanics · Physics 2015-05-14 S. Dattagupta , Jishad Kumar , S. Sinha , P. A. Sreeram

We study the computational complexity of Markov chain Monte Carlo (MCMC) methods for high-dimensional Bayesian linear regression under sparsity constraints. We first show that a Bayesian approach can achieve variable-selection consistency…

Statistics Theory · Mathematics 2015-06-01 Yun Yang , Martin J. Wainwright , Michael I. Jordan

The Hidden Markov Model (HMM) is a widely-used statistical model for handling sequential data. However, the presence of missing observations in real-world datasets often complicates the application of the model. The EM algorithm and Gibbs…

Machine Learning · Statistics 2026-01-06 Dongrong Li , Tianwei Yu , Xiaodan Fan

We consider the computational task of sampling a bit string $x$ from a distribution $\pi(x)=|\langle x|\psi\rangle|^2$, where $\psi$ is the unique ground state of a local Hamiltonian $H$. Our main result describes a direct link between the…

Quantum Physics · Physics 2023-11-09 Sergey Bravyi , Giuseppe Carleo , David Gosset , Yinchen Liu

Monte Carlo methods are essential tools for Bayesian inference. Gibbs sampling is a well-known Markov chain Monte Carlo (MCMC) algorithm, extensively used in signal processing, machine learning, and statistics, employed to draw samples from…

Computation · Statistics 2017-12-21 Luca Martino , Victor Elvira , Gustau Camps-Valls

Path integral quantum Monte Carlo (PIMC) is a method for estimating thermal equilibrium properties of stoquastic quantum spin systems by sampling from a classical Gibbs distribution using Markov chain Monte Carlo. The PIMC method has been…

Quantum Physics · Physics 2021-02-22 Elizabeth Crosson , Aram W. Harrow

For a graph $G$, let $Z(G,\lambda)$ be the partition function of the monomer-dimer system defined by $\sum_k m_k(G)\lambda^k$, where $m_k(G)$ is the number of matchings of size $k$ in $G$. We consider graphs of bounded degree and develop a…

Data Structures and Algorithms · Computer Science 2013-09-05 Marc Lelarge , Hang Zhou

Simulating quantum many-body systems (QMBS) is one of the long-standing, highly non-trivial challenges in condensed matter physics and quantum information due to the exponentially growing size of the system's Hilbert space. To date, tensor…

Quantum Physics · Physics 2026-02-06 Belal Abouraya , Jirawat Saiphet , Fedor Jelezko , Ressa S. Said

Markov jump processes (MJPs) are continuous-time stochastic processes widely used in a variety of applied disciplines. Inference for MJPs typically proceeds via Markov chain Monte Carlo, the state-of-the-art being a uniformization-based…

Computation · Statistics 2020-04-14 Boqian Zhang , Vinayak Rao

Quantum systems in thermal equilibrium are described using Gibbs states. The correlations in such states determine how difficult it is to describe or simulate them. In this article, we show that if the Gibbs state of a quantum system…

Quantum Physics · Physics 2025-10-08 Andreas Bluhm , Ángela Capel , Antonio Pérez-Hernández

Hybrid quantum-classical algorithms provide ways to use noisy intermediate-scale quantum computers for practical applications. Expanding the portfolio of such techniques, we propose a quantum circuit learning algorithm that can be used to…

We consider Markov chain Monte Carlo (MCMC) algorithms for Bayesian high-dimensional regression with continuous shrinkage priors. A common challenge with these algorithms is the choice of the number of iterations to perform. This is…

Methodology · Statistics 2021-07-13 Niloy Biswas , Anirban Bhattacharya , Pierre E. Jacob , James E. Johndrow

Gain-dissipative platforms consisting of lasers, optical parametric oscillators and nonequilibrium condensates operating at the condensation/coherence threshold have been recently proposed as efficient analog simulators of 2-local spin…

Disordered Systems and Neural Networks · Physics 2021-02-10 Nikita Stroev , Natalia G. Berloff

Quantum Monte Carlo method with operator-loop update is a powerful technique that has been extensively used with great success in condensed matter physics. It enables one to sample from thermal and ground states of local Hamiltonians of…

Quantum Physics · Physics 2025-09-29 Chaithanya Rayudu , Jun Takahashi

Gibbs sampling is a crucial computational technique used in physics, statistics, and many other scientific fields. For classical Hamiltonians, the most commonly used Gibbs sampler is the Metropolis algorithm, known for having the Gibbs…

Quantum Physics · Physics 2024-06-25 Jiaqing Jiang , Sandy Irani