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The conformational behavior of a coarse-grained finite polymer chain near an attractive spherical surface was investigated by means of multicanonical Monte Carlo computer simulations. In a detailed analysis of canonical equilibrium data…

Soft Condensed Matter · Physics 2018-01-03 Handan Arkin , Wolfhard Janke

The demand for innovative synthetic polymers with improved properties is high, but their structural complexity and vast design space hinder rapid discovery. Machine learning-guided molecular design is a promising approach to accelerate…

Soft Condensed Matter · Physics 2024-10-07 Gabriel Vogel , Jana M. Weber

The ability of a feed-forward neural network to learn and classify different states of polymer configurations is systematically explored. Performing numerical experiments, we find that a simple network model can, after adequate training,…

Soft Condensed Matter · Physics 2017-04-14 Qianshi Wei , Roger G. Melko , Jeff Z. Y. Chen

We consider a $\mathcal{PT}$-symmetric chain (ladder-shaped) system governed by the discrete nonlinear Schr\"odinger equation where the cubic nonlinearity is carried solely by two central "rungs" of the ladder. Two branches of scattering…

Pattern Formation and Solitons · Physics 2015-06-22 Jennie D'Ambroise , Stefano Lepri , Boris A. Malomed , Panayotis G. Kevrekidis

We study uniform 3-star polymers with one branch tethered to an attractive surface and another branch pulled by a force away from the surface. Each branch of the 3-star lattice is modelled as a self-avoiding walk on the simple cubic lattice…

Statistical Mechanics · Physics 2019-05-30 C J Bradly , A L Owczarek

In electromagnetism, acoustics, and quantum mechanics, scattering problems can routinely be solved numerically by virtue of perfectly matched layers (PMLs) at simulation domain boundaries. Unfortunately, the same has not been possible for…

Computational Physics · Physics 2018-02-07 Andre Diatta , Muamer Kadic , Martin Wegener , Sebastien Guenneau

We present Monte Carlo computer simulations for melts of semiflexible randomly knotted and randomly concatenated ring polymers on the fcc lattice and in slit confinement. Through systematic variation of the slit width at fixed melt density,…

Soft Condensed Matter · Physics 2023-07-06 Mattia Alberto Ubertini , Angelo Rosa

Structural defects within amorphous packings of symmetric particles can be characterized using a machine learning approach that incorporates structure functions of radial distances and angular arrangement. This yields a scalar field,…

Soft Condensed Matter · Physics 2019-03-06 Matt Harrington , Andrea J. Liu , Douglas J. Durian

A machine learning approach is presented to accelerate the computation of block polymer morphology evolution for large domains over long timescales. The strategy exploits the separation of characteristic times between coarse-grained…

Chemical Physics · Physics 2023-09-01 Hyun Park , Boyuan Yu , Juhae Park , Ge Sun , Emad Tajkhorshid , Juan J. de Pablo , Ludwig Schneider

The spatial correlations of entangled polymer dynamics are examined by molecular dynamics simulations and neutron spin-echo spectroscopy. Due to the soft nature of topological constraints, the initial spatial decays of intermediate…

We have used kinetic Monte Carlo simulations to study the kinetics of unfolding of cross-linked polymer chains under mechanical loading. As the ends of a chain are pulled apart, the force transmitted by each crosslink increases until it…

Biological Physics · Physics 2009-11-10 Kilho Eom , Dmitrii E Makarov , Gregory J. Rodin

We revisit the classical problem of a polymer confined in a slit in both of its static and dynamic aspects. We confirm a number of well known scaling predictions and analyse their range of validity by means of comprehensive Molecular…

Machine Learning (ML) techniques are revolutionizing the way to perform efficient materials modeling. Nevertheless, not all the ML approaches allow for the understanding of microscopic mechanisms at play in different phenomena. To address…

Materials Science · Physics 2022-06-22 Udaykumar Gajera , Loriano Storchi , Danila Amoroso , Francesco Delodovici , Silvia Picozzi

We present a Monte Carlo simulation of a polymer nematic for varying volume fractions, concentrating on the structure function of the sample. We achieve nematic ordering with stiff polymers made of spherical monomers that would otherwise…

Soft Condensed Matter · Physics 2009-10-28 Randall D. Kamien , Gary S. Grest

Reinforcement of elastomers by colloidal nanoparticles is an important application where microstructure needs to be understood - and if possible controlled - if one wishes to tune macroscopic mechanical properties. Here the…

Soft Condensed Matter · Physics 2007-05-23 Julian Oberdisse , Peter Hine , Wim Pyckhout-Hintzen

Vitrimer is an emerging class of sustainable polymers with self-healing capabilities enabled by dynamic covalent adaptive networks. However, their limited molecular diversity constrains their property space and potential applications.…

Machine learning offers promising tools to develop surrogate models for polymer structure-property relations. Surrogate models can be built upon existing polymer data and are useful for rapidly predicting the properties of unknown polymers.…

Soft Condensed Matter · Physics 2023-08-22 Agrim Babbar , Sriram Ragunathan , Debirupa Mitra , Arnab Dutta , Tarak. K Patra

The Monte Carlo carbyne model is modified to investigate the glass transition of the semi-flexible entangled polymer chains. The stochastic bombardment between monomers are monitored by Metropolis algorithm with help of the consideration of…

Computational Physics · Physics 2018-10-17 C. H. Wong , L. Xue , E. A. Buntov , A. F. Zatsepin

The tube model is a central concept in polymer physics, and allows to reduce the complex many-filament problem of an entangled polymer solution to a single filament description. We investigate the probability distribution function of…

Soft Condensed Matter · Physics 2009-08-12 Hauke Hinsch , Erwin Frey

In this paper we present simulations of a surface-adsorbed polymer subject to an elongation force. The polymer is modelled by a self-avoiding walk on a regular lattice. It is confined to a half-space by an adsorbing surface with attractions…

Statistical Mechanics · Physics 2007-05-23 J. Krawczyk , T. Prellberg , A. Rechnitzer , A. L. Owczarek