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We present an accurate approach to compute X-ray photoelectron spectra based on the $GW$ Green's function method, that overcomes shortcomings of common density functional theory approaches. $GW$ has become a popular tool to compute valence…

Chemical Physics · Physics 2020-03-11 Dorothea Golze , Levi Keller , Patrick Rinke

We reexamine the improved effective vector boson approximation which is based on two-vector-boson luminosities $\mathrm{\mathbf{L}}_{\rm pol}$ for the computation of weak gauge-boson hard scattering subprocesses $V_1 V_2\to {\cal W}$ in…

High Energy Physics - Phenomenology · Physics 2016-04-06 Werner Bernreuther , Long Chen

We investigate optical absorption spectra obtained through time-dependent density functional theory (TD-DFT) based on nonempirical hybrid functionals that are designed to correctly reproduce the dielectric function. The comparison with…

Materials Science · Physics 2020-08-17 Alexey Tal , Peitao Liu , Georg Kresse , Alfredo Pasquarello

The nuclear physics input from the 3He(alpha,gamma)7Be cross section is a major uncertainty in the fluxes of 7Be and 8B neutrinos from the Sun predicted by solar models and in the 7Li abundance obtained in big-bang nucleosynthesis…

We develop an extension of the variational quantum eigensolver (VQE) algorithm - multistate, contracted VQE (MC-VQE) - that allows for the efficient computation of the transition energies between the ground state and several low-lying…

Quantum Physics · Physics 2019-06-19 Robert M. Parrish , Edward G. Hohenstein , Peter L. McMahon , Todd J. Martinez

We present a scalable implementation of the $GW$ approximation using Gaussian atomic orbitals to study the valence and core ionization spectroscopies of molecules. The implementation of the standard spectral decomposition approach to the…

Chemical Physics · Physics 2021-12-06 Daniel Mejia-Rodriguez , Alexander Kunitsa , Edoardo Aprà , Niranjan Govind

Alchemical binding free energy (BFE) calculations offer an efficient and thermodynamically rigorous approach to in silico binding affinity predictions. As a result of decades of methodological improvements and recent advances in computer…

Statistical Mechanics · Physics 2021-07-13 Pengfei Li , Zhijie Li , Yu Wang , Huaixia Dou , Brian K. Radak , Woody Sherman , Huafeng Xu

The many-body expansion (MBE) is an efficient tool which has a long history of use for calculating interaction energies, binding energies, lattice energies, and so on. In the past, applications of MBE to correlation energy have been…

Strongly Correlated Electrons · Physics 2021-08-11 Vibin Abraham , Nicholas Mayhall

Within the framework of many-body perturbation theory based on Green's functions, the $GW$ approximation has emerged as a pivotal method for computing quasiparticle energies and excitation spectra. However, its high computational cost and…

Chemical Physics · Physics 2025-12-25 Yueyang Zhang , Wei Wu , Peifeng Su

The recent developments of quantum computing present potential novel pathways for quantum chemistry, as the increased computational power of quantum computers could be harnessed to naturally encode and solve electronic structure problems.…

Quantum Physics · Physics 2024-03-01 Lila Cadi Tazi , Alex J. W. Thom

Molecule-optimized basis sets, based on approximate natural orbitals, are developed for accelerating the convergence of quantum calculations with strongly correlated (multi-referenced) electrons. We use a low-cost approximate solution of…

Chemical Physics · Physics 2014-02-12 Gergely Gidofalvi , David A. Mazziotti

We present a first-principles method for relaxing a material's geometry in an optically excited state. This method, based on the Bethe-Salpeter equation, consists of solving coupled equations for exciton wavefunctions and atomic…

Computational Physics · Physics 2022-12-29 Mao Yang , Claudia Draxl

We present a complete prescription for the numerical calculation of surface Green's functions and self-energies of semi-infinite quasi-onedimensional systems. Our work extends the results of Sanvito et al. [1] generating a robust algorithm…

Materials Science · Physics 2007-12-11 Ivan Rungger , Stefano Sanvito

Energy dispersive X-ray (EDX) spectrum imaging yields compositional information with a spatial resolution down to the atomic level. However, experimental limitations often produce extremely sparse and noisy EDX spectra. Under such…

First principles calculations based on density functional theory are having an incerasing impact on our understanding of molecule-surface interactions. For example, calculations of the multi-dimensional potential energy surface have…

Materials Science · Physics 2007-05-23 O. Gulseren , D. M. Bird , S. E. Humphreys

Helium atom is the simplest many-body electronic system provided by nature. The exact solution to the Schr\"odinger equation is known for helium ground and excited states, and represents a workbench for any many-body methodology. Here, we…

Atomic Physics · Physics 2017-04-26 Jing Li , Markus Holzmann , Ivan Duchemin , Xavier Blase , Valerio Olevano

We investigate the electromagnetic properties of the deuteron such as the charge and magnetic form factors by solving the Bethe-Salpeter equation (BSE) with the separable ansatz. In solving the deuteron bound state solution to the BSE, we…

Nuclear Theory · Physics 2007-05-25 Y. Manabe , A. Hosaka , H. Toki

Development of resource-friendly quantum algorithms remains highly desirable for noisy intermediate-scale quantum computing. Based on the variational quantum eigensolver (VQE) with unitary coupled cluster ansatz, we demonstrate that…

The purpose of this paper is twofold. The first purpose is to find a fully Poincare invariant solution of the Bethe-Salpeter equation for excited quarkonia, however, the second, in fact, major focus is on the relevance of the space-time…

High Energy Physics - Phenomenology · Physics 2014-07-14 Vladimir Sauli

We discuss a variational calculation for nuclear shell-model calculations and propose a new procedure for the energy-variance extrapolation (EVE) method using a sequence of the approximated wave functions obtained by the variational…