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Complexation between anionic and cationic polyelectrolytes results in solid-like precipitates or liquid-like coacervate depending on the added salt in the aqueous medium. However, the boundary between these polymer-rich phases is quite…
This paper is concerned with the diffusion of a fluid through a viscoelastic solid undergoing large deformations. Using ideas from the classical theory of mixtures and a thermodynamic framework based on the notion of maximization of the…
Turbulent flows have been used for millennia to mix solutes; a familiar example is stirring cream into coffee. However, many energy, environmental, and industrial processes rely on the mixing of solutes in porous media where confinement…
Thermal greases, often used as thermal interface materials, are complex paste-like mixtures composed of a base polymer in which dense metallic (or ceramic) filler particles are dispersed to improve the heat transfer properties of the…
Yielding behavior in amorphous solids has been investigated in computer simulations employing uniform and cyclic shear deformation. Recent results characterise yielding as a discontinuous transition, with the degree of annealing of glasses…
Many key environmental, industrial, and energy processes rely on controlling fluid transport within subsurface porous media. These media are typically structurally heterogeneous, often with vertically-layered strata of distinct…
We investigate the elastoviscoplastic flow through porous media by numerical simulations. We solve the Navier-Stokes equations combined with the elastoviscoplastic model proposed by Saramito for the stress tensor evolution. In this model,…
We study the flow of a thixotropic fluid around a cylinder. The rheology of the fluid is described by means of a structural viscoplastic model based on the Bingham constitutive equation, regularised using the Papanastasiou regularisation.…
In order to study the viscoelastic properties of certain complex fluids which are described in terms of a multiconnected transient network we have developed a convenient model system composed of microemulsion droplets linked by telechelic…
In soft amorphous materials, shear cessation after large shear deformation leads to structures having residual shear stress. The origin of these states and the distribution of the local shear stresses within the material is not well…
Active materials are media for which deformations can occur in absence of loads, given an external stimulus. Two approaches to the modeling of such materials are mainly used in literature, both based on the introduction of a new tensor: an…
Mechanical deformation of amorphous solids can be described as consisting of an elastic part in which the stress increases linearly with strain, up to a yield point at which the solid either fractures or starts deforming plastically. It is…
Experimental measurements of the response of a two dimensional system of plastic beads subjected to steady shear are reported. The beads float at the surface of a fluid substrate and are subjected to a slow, steady-shear in a Couette…
Subjected to compressive stresses, soft polymers with stiffness gradients can display various buckling patterns. These compressive stresses can have different origins, like mechanical forces, temperature changes, or, for hydrogel materials,…
The polyconvexity of a strain-energy function is nowadays increasingly presented as the ultimate material stability condition for an idealized elastic response. While the mathematical merits of polyconvexity are clearly understood, its…
Applicability of associated plasticity for particulate materials such as soils does not yield satisfactory results when Coulomb's theory of shear strength of soils is assumed, and the yield function derived accordingly is used to define…
We simulate a dense athermal suspension of soft particles sheared between hard walls of a prescribed roughness profile, using a method that fully accounts for the fluid mechanics of the solvent between the particles, and between the…
The sliding of non-Newtonian drops down planar surfaces results in a complex, entangled balance between interfacial forces and non linear viscous dissipation, which has been scarcely inspected. In particular, a detailed understanding of the…
Cauchy-elastic solids include hyper-elasticity and a subset of elastic materials for which the stress does not follow from a scalar strain potential. More in general, hypo-elastic materials are only defined incrementally and comprise…
Starch solutions, which are strongly non-Newtonian, show a surface instability, when subjected to a load. A droplet of the fluid is sandwiched between two glass plates and a weight varying from 1 to 5 kgs. is placed on the top plate. The…