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Recent findings suggest Mars may have been a clement environment for the emergence of life, and may even have compared favorably to Earth in this regard. These findings have revived interest in the hypothesis that prebiotically important…
A key challenge in origin-of-life studies is understanding the environmental conditions on early Earth under which abiogenesis occurred. While some constraints do exist (e.g., zircon evidence for surface liquid water), relatively few…
We present and validate a new network of atmospheric thermo-chemical and photo-chemical sulfur reactions. We use a 1-D chemical kinetics model to investigate these reactions as part of a broader HCNO chemical network in a series of hot and…
Ancient hydrology is recorded by sedimentary rocks on Mars. The most voluminous sedimentary rocks that formed during Mars' Hesperian period are sulfate-rich rocks, explored by the $Opportunity$ rover from 2004-2012 and soon to be…
Sulfur chemistry plays a central role in controlling the atmospheric structure, cloud formation, and composition of Venus and Venus-like exoplanets. However, key reactions involving ground- and excited-state sulfur species remain poorly…
Sulfur chemistry in the formation process of low-mass stars and planets remains poorly understood. The protoplanetary disks (PPDs) are the birthplace of planets and its distinctive environment provides an intriguing platform for…
The nature and abundance of sulfur chemistry in protoplanetary disks (PPDs) may impact the sulfur inventory on young planets and therefore their habitability. PPDs also present an interesting test bed for sulfur chemistry models, since each…
CaSO4 minerals (i.e. gypsum, anhydrite and bassanite) are widespread in natural and industrial environments. During the last several years, a number of studies have revealed that nucleation in the CaSO4-H2O system is non-classical, where…
The detection of SO2 in both WASP-39 b and WASP-107 b recently brought more attention to the modeling of photochemistry in exoplanets. However, sulfur kinetics data is lacking in the literature for the full C/H/O/N/S system. The networks…
Reconciling the geology of Mars with models of atmospheric evolution remains a major challenge. Martian geology is characterized by past evidence for episodic surface liquid water, and geochemistry indicating a slow and intermittent…
The recent discovery of liquid water-related sulphates on Mars is of great astrobiological interest. UV radiation experiments, using natural Ca and Fe sulphates (gypsum, jarosite), coming from two selected areas of SE Spain (Jaroso…
We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial…
Using the Socrates photolysis scheme, we present newly calculated photolysis rates under modern Earth atmospheric conditions for species directly relevant to Earth and species relevant to different atmospheric compositions. We compare to a…
Late-stage Ca-sulfate-filled fractures are common on Mars. Notably, the Shenandoah formation in the western edge of Jezero crater preserves a variety of Ca-sulfate minerals in the fine-grained siliciclastic rocks explored by the…
Recent reports suggest that chemical reaction rates can change when reactants are placed inside an optical cavity. These effects have been attributed to the hybridization of molecular vibrational modes with cavity modes into polaritons, but…
The illumination of catalytic surfaces with a continuous or pulsed stream of photons dynamically modulates surface chemistry for faster rates, higher conversion, or product selectivity control. To establish fundamental principles of dynamic…
There are many open questions about prebiotic chemistry in both planetary and exoplanetary environments. The increasing number of known exoplanets and other ultra-cool, substellar objects has propelled the desire to detect life and…
Relative abundances of refractory elements in planets are commonly assumed to reflect those of their host stars. However, because elements are classified according to their behaviour in the solar nebula, this implicitly assumes condensation…
Context. The outer Milky Way has a lower metallicity than our solar neighbourhood, but still many molecules are detected in the region. Molecular line ratios can serve as probes to better understand the chemistry and physics in these…
We study the spectrum of a planetary atmosphere to derive detectable features in low resolution of different global geochemical cycles on exoplanets - using the sulphur cycle as our example. We derive low resolution detectable features for…