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Electrostatic interactions play an important role in numerous self-assembly phenomena, including colloidal aggregation. Although colloids typically have a dielectric constant that differs from the surrounding solvent, the effective…

Soft Condensed Matter · Physics 2018-09-17 Kipton Barros , Erik Luijten

The mechanisms of electrostatic interactions between two charged dielectric spheres inside a polarizable medium have been investigated, in terms of hypothetical effective dipoles that depict how the positive and negative charge in each…

Soft Condensed Matter · Physics 2025-02-06 Yanyu Duan , Zecheng Gan , Ho-Kei Chan

During the last 3 years, our group has investigated extensively the complexation mechanism between neutral-polyelectrolyte block copolymers with oppositely charged species. These species are surfactant micelles, multivalent counterions and…

Soft Condensed Matter · Physics 2007-05-23 J. -F. Berret , P. Herve , M. Morvan , K. Yokota , M. Destarac , J. Oberdisse , I. Grillo , R. Schweins

In this review, we address the issue of the electrostatic complexation between charged-neutral diblock copolymers and oppositely charged nanocolloids. We show that nanocolloids such as surfactant micelles and iron oxide magnetic…

Soft Condensed Matter · Physics 2011-02-01 J. -F. Berret

Electrostatics in the solution phase is governed by free electrical charges such as ions, as well as by bound charges that arise when a polarizable medium responds to an applied field. In a local medium, described by a constant dielectric…

Soft Condensed Matter · Physics 2025-02-04 Ali Behjatian , Ralf Blossey , Madhavi Krishnan

Industrial as well as natural aggregation of fine particles is believed to be associated with electrostatics. Yet like charges repel, so it is unclear how similarly treated particles aggregate. To resolve this apparent contradiction, we…

Soft Condensed Matter · Physics 2018-12-24 A. F. V. Matias , T. Shinbrot , N. A. M. Araujo

We consider a model of colloidal spherical particles carrying a permanent dipole moment which is laterally shifted out of the particles' geometrical centres, i.e. the dipole vector is oriented perpendicular to the radius vector of the…

Soft Condensed Matter · Physics 2015-11-04 Arzu B. Yener , Sabine H. L. Klapp

Colloidal particles can self-assemble into various ordered structures in fluid flows that have potential applications in biomedicine, materials synthesis and encryption. These dynamic processes are also of fundamental interest for probing…

Soft Condensed Matter · Physics 2017-01-31 Yu Abe , Bo Zhang , Leonardo Gordillo , Alireza Mohammad Karim , Lorraine F. Francis , Xiang Cheng

Attractive dipole interactions can be induced between equally charged soft nanoparticles under the influence of AC electric fields. The combination of charge repulsion and dipole attraction, along with different screening responses from an…

Soft Condensed Matter · Physics 2025-10-16 Carlos Eduardo Estanislau , Thiago Colla , Christos N. Likos

This paper builds on two previous works, Lindgren et al. J. Comp. Phys. 371, 712-731 (2018) and Quan et al. arXiv:1807.05384 (2018), to devise a new method to solve the problem of calculating electrostatic interactions in a system composed…

Soft Condensed Matter · Physics 2019-02-20 Eric B. Lindgren , Chaoyu Quan , Benjamin Stamm

Engineered nanoparticles made from noble metals, rare-earth oxides or semiconductors are emerging as the central constituents of future nanotech developments. In this review, a survey of the complexing strategies between nanoparticles and…

Materials Science · Physics 2011-08-25 J. -P. Chapel , J. -F. Berret

We report the presence of a correlation between the bulk and interfacial properties of electrostatic coacervate complexes. Complexes were obtained by co-assembly between cationic-neutral diblocks and oppositely charged surfactant micelles…

Soft Condensed Matter · Physics 2007-10-12 Ling Qi , Jean-Paul Chapel , Jean-Christophe Castaing , Jerome Fresnais , Jean-Francois Berret

We perform numerical simulations to study self-assembly of nanoparticles mediated by an elastic planar surface. We show how the nontrivial elastic response to deformations of these surfaces leads to anisotropic interactions between the…

Soft Condensed Matter · Physics 2012-01-04 Andela Šarić , Angelo Cacciuto

In the study of colloidal, biological and electrochemical systems, it is customary to treat surfaces, macromolecules and electrodes as homogeneously charged. This simplified approach is proven successful in most cases, but fails to describe…

Soft Condensed Matter · Physics 2022-08-04 Ram M. Adar , David Andelman , Haim Diamant

The emergence of hydrodynamic bend instabilities in ordered suspensions of active particles is widely observed across diverse living and synthetic systems, and is considered to be governed by dipolar active stresses generated by the…

Soft Condensed Matter · Physics 2026-01-09 Sameer Kumar , Niels de Graaf Sousa , Amin Doostmohammadi

The standard Maxwell formulation of the problem of polarized dielectrics suffers from a number of difficulties, both conceptual and practical. These difficulties are particularly significant in the case of liquid interfaces, where the…

Soft Condensed Matter · Physics 2015-06-18 Dmitry V. Matyushov

Recent experimental utilization of liquid substrate in the production of two-dimensional crystals, such as graphene, together with a general interest in amorphous materials, raises the following question: is it beneficial to use a liquid…

Statistical Mechanics · Physics 2022-03-14 Deborah Schwarcz , Stanislav Burov

Monopole-like electrostatic interactions are ubiquitous in biology and condensed matter, but they are often screened by counter-ions and cannot be switched from attractive to repulsive. In colloidal science, where the prime goal is to…

Soft Condensed Matter · Physics 2020-01-06 Ye Yuan , Qingkun Liu , Bohdan Senyuk , Ivan I. Smalyukh

In biological and synthetic materials, many important processes involve charges that are present in a medium with spatially varying dielectric permittivity. To accurately understand the role of electrostatic interactions in such systems, it…

Soft Condensed Matter · Physics 2013-09-30 Vikram Jadhao , Francisco J. Solis , Monica Olvera de la Cruz

The method of image charges is a powerful and elegant technique in electrostatics, commonly used to determine the electric field generated by point charges near conductors of various shapes. While standard problems focus on single charges…

Classical Physics · Physics 2025-12-02 Farhang Loran , Saman Moghimi-Araghi
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