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Surface plasmons in a centrosymmetric metal nanocrystal have been perceived as achiral, based on the quantum-mechanical theory of molecular optical activity. The one-electron theory is insufficient to describe optical activity in crystals,…

Mesoscale and Nanoscale Physics · Physics 2018-03-02 Jong-Won Park

Chiral fields with large optical chirality are very important in chiral molecules analysis, sensing and other measurements. Plasmonic nanostructures have been proposed to realize such super chiral fields for enhancing weak chiral signals.…

Optics · Physics 2015-09-14 Xiaorui Tian , Yurui Fang , Mengtao Sun

A chiral near field with a highly contorted electromagnetic field builds a bridge to match the chiral molecules and light wavelengths with large size differences. It significantly enhances the circular dichroism of chiral molecules and has…

Optics · Physics 2022-03-23 Li Hu , Zhiguang Sun , Yingdong Nie , Yingzhou Huang , Yurui Fang

Optical activity is a fundamental phenomenon originating from the chiral nature of crystals and molecules. While intrinsic chiroptical responses of ordinary chiral materials to circularly polarized light are relatively weak, they can be…

Nanophotonic platforms in theory uniquely enable < femtomoles of chiral biological and pharmaceutical molecules to be detected, through the highly localised changes in the chiral asymmetries of the near-fields that they induce. However,…

We theoretically investigate light matter interactions for chiral molecules in the presence of non-chiral nanoantennas. Isotropic nanostructures supporting optical-frequency electric or magnetic dipoles are sufficient to locally enhance the…

Mesoscale and Nanoscale Physics · Physics 2013-06-14 Aitzol Garcia-Etxarri , Jennifer A. Dionne

The interaction of radiation with chiral molecular films is not macroscopically invariant under mirror reflections and, accordingly, chiroptical effects exist which affect the spatial symmetry of the radiation profile and which nearly…

Optics · Physics 2021-10-05 Alessandro Ciattoni

Metal nanostructures act as powerful optical antennas[1, 2] because collective modes of the electron fluid in the metal are excited when light strikes the surface of the nanostructure. These excitations, known as plasmons, can have…

Mesoscale and Nanoscale Physics · Physics 2011-04-04 Daniel R. Ward , Falco Hueser , Fabian Pauly , Juan Carlos Cuevas , Douglas Natelson

When circularly polarized light interacts with a nanostructure, the optical response depends on the geometry of the structure. If the nanostructure is chiral (i.e., it cannot be superimposed on its mirror image), then its optical response,…

Mirror symmetry is among the most fundamental concepts of physics and its spontaneous breaking at the molecular level allows chiral molecules to exist in two enantiomers that are mirror images of each other. The majority of chiro-optical…

Optics · Physics 2021-09-29 Alessandro Ciattoni

Particle plasmons in metal nanoparticles have primarily been investigated through the use of local optical response approximations. However, as nanoparticle size approaches the average distance of electrons to the metal surface, mesoscopic…

Optics · Physics 2023-06-28 Weixiang Ye

We perform a study of the achievable field enhancement of plasmonic cascade nanolenses in the quantum and classical regimes, and explore the limits enforced at larger sizes by retardation and at smaller sizes by nonlocality and other…

Optics · Physics 2017-12-25 Jamie M. Fitzgerald , Vincenzo Giannini

In this work we study the strong confinement effects on the electromagnetic response of metallic nanoparticles. We calculate the field enhancement factor for nanospheres of various radii by using optical constants obtained from both…

Mesoscale and Nanoscale Physics · Physics 2018-02-20 Mario Zapata-Herrera , Jefferson Flórez , Angela Camacho , Hanz Y. Ramirez

We review the basic physics behind light interaction with plasmonic nanoparticles. The theoretical foundations of light scattering on one metallic particle (a plasmonic monomer) and two interacting particles (a plasmonic dimer) are…

Optics · Physics 2012-08-22 Dmitry N. Chigrin , Christian Kremers , Sergei V. Zhukovsky

Molecular chirality plays an important role in chemistry and biology, allows control of biological interactions, affects drugs efficacy and safety, and promotes synthesis of new materials. In general, chirality manifests itself in optical…

Optics · Physics 2026-04-10 Yuanyang Xie , Alexey V. Krasavin , Anatoly V. Zayats

We present the design and optical characterization of a plasmonic metasurface engineered to exhibit strong polarization anisotropy under both linearly and circularly polarized light. The metasurface consists of geometrically asymmetric gold…

Chirality is a concept that one object is not superimposable on its mirror image by translation and rotation. In particular, chiral plasmonics have been widely investigated due to their excellent optical chiral properties, and have led to…

Optics · Physics 2023-07-18 Yuqing Cheng , Mengtao Sun

Prospects of using metal hole arrays for the enhanced optical detection of molecular chirality in nanosize volumes are investigated. Light transmission through the holes filled with an optically active material is modeled and the activity…

We theoretically examine the spatiotemporal evolution of enhanced near-field optical chirality (OC) in both plasmonic and dielectric nanospheres when excited by ultrashort optical pulses. We demonstrate distinct spatiotemporal variations in…

Optics · Physics 2024-10-08 Ankit Kumar Singh , Jer-Shing Huang

Based on experimental and simulation methods we helped develop, we are advancing mechanistic understanding of how self-assembled NC metamaterials can produce distinctive near- and far-field optical properties not readily achievable in…

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