Related papers: Organic compounds in metallic hydrogen
The formation of a Pd atomic chain in a hydrogen atmosphere was investigated by measurements of conductance and vibrational spectroscopy of a single molecular junction, and the theoretical calculation. While atomic chains were not formed…
An overview is given of the chemical processes that occur in primordial systems under the influence of radiation, metal abundances and dust surface reactions. It is found that radiative feedback effects differ for UV and X-ray photons at…
As building blocks of dust, rocky planets, and even complex life, the chemical elements heavier than hydrogen (H) and helium (He) - called "metals" in astronomy - play an essential role in our Universe and its evolution. Up to Fe and Ni,…
The metallic regime of the hydrogen plasma is studied by ab initio Molecular Dynamics simulations, for classical protons and fully degenerate electrons, in the strong coupling regime of the protons. The breakdown of linear screening…
Water absorption in the metal-organic framework (MOF) material Cu-BTC, up to a concentration of 3.5 H$_2$O per Cu ion, is studied via density functional theory at the meta-GGA+U level. The stable arrangements of water molecules show chains…
Molecular hydrogen (H$_2$) plays a critical role in astrophysical processes from galaxy evolution to the formation of planets. While the dominant formation channel in the interstellar medium is considered as dust-catalyzed H$_2$ formation,…
Knowledge of the behavior of hydrogen in metal hydrides is the key for understanding their electronic properties. So far, no experimental methods exist to access these properties beyond 100 GPa, where high-Tc superconductivity emerges.…
The origin of dark matter in galactic halos, one of the deepest unsolved problems in astrophysics, may find an unexpected contribution from the quantum mechanics of ordinary atomic hydrogen. We show that quantum entanglement and coherence…
We comment on a recent paper published by McWilliams et al claiming that high-pressure/high-temperature hydrogen is a semi-conductor or semi-metal, in conflict with all earlier measurements on this system which show that it is metallic. We…
In a hierarchical cosmogony present-day galaxies build up by continuous merging of smaller structures. At a redshift of three the matter content of a typical present-day galaxy is split into about ten individual protogalactic clumps.…
In this paper we use observations of molecular tracers in metal rich and alpha-enhanced galaxies to study the effect of abundance changes on molecular chemistry. We selected a sample of metal rich spiral and star bursting objects from the…
The interaction between hydrogen atoms and carbon nanoparticles is a fundamental process governing the properties of carbonaceous materials in environments ranging from combustion systems to the interstellar medium. This study investigates…
The optical filaments found in many cooling flows in galaxy clusters consist of low density ($\sim 10^3 \pcc$) cool ($\sim 10^3$ K) gas surrounded by significant amounts of cosmic-ray and magnetic-field energy. Their spectra show…
Accurate and predictive computations of the quantum-mechanical behavior of many interacting electrons in realistic atomic environments are critical for the theoretical design of materials with desired properties, and require solving the…
Molecular hydrogen is the most abundant molecule in the universe. A large fraction of H2 forms by association of hydrogen atoms adsorbed on polycyclic aromatic hydrocarbons (PAHs), where formation rates depend crucially on the H sticking…
An intriguing fact about cosmic gas clouds is that they all appear to have neutral (atomic) hydrogen column densities smaller than 10^{22} cm^{-2}. Observations of damped Ly-alpha (DLA) absorption systems further indicate that the maximum…
Methylated polycyclic aromatic hydrocarbons (PAHs) have been hypothesised to be present in the interstellar medium (ISM) through their 3.4 and 6.9 $\mu$m absorption bands. To investigate the hydrogenation of these methylated PAHs, the…
The recent detection of the hydrocarbon anion C6H- in the interstellar medium has led us to investigate the synthesis of hydrocarbon anions in a variety of interstellar and circumstellar environments. We find that the anion/neutral…
Here we investigate how small amounts of hydrogen (much smaller than the mass of the exoplanet) above a magma ocean on a rocky exoplanet may modify the atmospheric chemistry and atmospheric escape.We use a chemical model of a magma ocean…
The chemical composition of stars with extremely low metal contents (taking ``metals'' to mean all elements other than hydrogen and helium) provides us with information on the masses of the stars that produced the first metals. Such a…