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Accurate band gap prediction in semiconductors is crucial for materials science and semiconductor technology advancements. This paper extends the Perdew-Burke-Ernzerhof (PBE) functional for a wide range of semiconductors, tackling the…

Materials Science · Physics 2024-08-01 Satadeep Bhattacharjee , Namitha Anna Koshi , Seung-Cheol Lee

We solve the Dyson equation for atoms and diatomic molecules within the GW approximation, in order to elucidate the effects of self-consistency on the total energies and ionization potentials. We find GW to produce accurate energy…

Materials Science · Physics 2015-03-30 Adrian Stan , Nils Erik Dahlen , Robert van Leeuwen

Quantum spin Hall (QSH) insulators have attracted intensive experimental and theoretical studies due to their beneficial applications in spintronic devices. Density functional theory (DFT) meets challenges when describing the electronic…

Materials Science · Physics 2024-06-19 Li Yin , Hong Tang , Adrienn Ruzsinszky

Self-consistent theory of electron localization in disordered systems is generalized for the case of interacting electrons. We propose and critically compare a number of possible self-consistency schemes which take into account the lowest…

Condensed Matter · Physics 2008-02-03 E. Z. Kuchinskii , M. V. Sadovskii , V. G. Suvorov

Block copolymers provide a wonderful platform in studying the soft condensed matter systems. Many fascinating ordered structures have been discovered in bulk and confined systems. Among various theories, the self-consistent field theory…

Soft Condensed Matter · Physics 2019-05-01 Huayi Wei , Ming Xu , Wei Si , Kai Jiang

By recasting the non-linear frequency-dependent $GW$ quasiparticle equation into a linear eigenvalue problem, we explain the appearance of multiple solutions and unphysical discontinuities in various physical quantities computed within the…

Chemical Physics · Physics 2022-06-16 Enzo Monino , Pierre-François Loos

While in strongly correlated materials one often focuses on local electronic correlations, the influence of non-local exchange and correlation effects beyond band-theory can be pertinent in systems with more extended orbitals. Thus in many…

Strongly Correlated Electrons · Physics 2015-03-24 Jan M. Tomczak

Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

Chemical Physics · Physics 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller

The question of spatial locality of electronic correlations beyond GW approximation is one of the central issues of the famous combination of GW and dynamical mean field theory, GW+DMFT. In this work, the above question is addressed…

Strongly Correlated Electrons · Physics 2021-09-08 Andrey L. Kutepov

Many-body perturbation theory in the GW approximation is a useful method for describing electronic properties associated with charged excitations. A hierarchy of GW methods exists, starting from non-self-consistent G0W0, through partial…

The Kohn-Sham gaps of density functional theory (DFT) obtained in terms of local density approximation (LDA) or generalized gradient approximation (GGA) cannot be directly linked to the fundamental gaps of semiconductors, but in engineering…

Materials Science · Physics 2024-09-17 Hanli Cui , Shengxin Yang , Jun-Hui Yuan , Li-Heng Li , Fan Ye , Jinhai Huang , Kan-Hao Xue , Xiangshui Miao

While the periodic equation-of-motion coupled-cluster (EOM-CC) method promises systematic improvement of electronic band gap calculations in solids, its practical application at the singles and doubles level (EOM-CCSD) is hindered by severe…

A technique allowing for a perturbative treatment of nonlocal corrections to the single-site dynamical mean-field theory (DMFT) in finite dimensions is developed. It is based on the observation that in the case of strong electron…

Strongly Correlated Electrons · Physics 2008-06-02 V. I. Tokar , R. Monnier

We have proposed a method for correcting the Kohn-Sham eigen energies in the density functional theory (DFT) based on the Koopmans theorem using Wannier functions. The method provides a general approach applicable for molecules and solids…

Computational Physics · Physics 2015-03-02 Jie Ma , Lin-Wang Wang

The DFT-1/2 method in density functional theory [L. G. Ferreira et al., Phys. Rev. B 78, 125116 (2008)] aims to provide accurate band gaps at the computational cost of semilocal calculations. The method has shown promise in a large number…

Materials Science · Physics 2019-03-04 Jan Doumont , Fabien Tran , Peter Blaha

The fully self-consistent GW approximation is an established method for electronic structure calculations. Its most serious deficiency is known to be an incorrect prediction of the dielectric response. In this work we examine the GW…

Strongly Correlated Electrons · Physics 2017-05-24 Kris Van Houcke , Igor S. Tupitsyn , Andrey S. Mishchenko , Nikolay V. Prokof'ev

In effective single-electron theories, self-interaction manifests itself through the unphysical dependence of the energy of an electronic state as a function of its occupation, which results in important deviations from the ideal Koopmans…

Materials Science · Physics 2009-01-20 I. Dabo , M. Cococcioni , N. Marzari

Systems of adatoms on semiconductor surfaces display competing ground states and exotic spectral properties typical of two-dimensional correlated electron materials which are dominated by a complex interplay of spin and charge degrees of…

Strongly Correlated Electrons · Physics 2015-06-12 Philipp Hansmann , Thomas Ayral , Loig Vaugier , Philipp Werner , Silke Biermann

Many-body perturbation theory methods, such as the $G_0W_0$ approximation, are able to accurately predict quasiparticle (QP) properties of several classes of materials. However, the calculation of the QP band structure of two-dimensional…

Materials Science · Physics 2022-06-23 Alberto Guandalini , Pino D'Amico , Andrea Ferretti , Daniele Varsano

The theoretical understanding of emergent phenomena in quantum materials is one of the greatest challenges in condensed matter physics. In contrast to simple materials such as noble metals and semiconductors, macroscopic properties of…

Strongly Correlated Electrons · Physics 2016-08-30 Sangkook Choi , Andrey Kutepov , Kristjan Haule , Mark van Schilfgaarde , Gabriel Kotliar
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