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Molecular polaritons are hybrid light-matter states that emerge when a molecular transition strongly interacts with photons in a resonator. At optical frequencies, this interaction unlocks a way to explore and control new chemical phenomena…

We demonstrate strong coupling between molecular excited states and surface plasmon modes of a slit array in a thin metal film. The coupling manifests itself as an anti-crossing behavior of the two newly formed polaritons. As the coupling…

Mesoscale and Nanoscale Physics · Physics 2012-08-17 Adi Salomon , Robert J. Gordon , Yehiam Prior , Tamar Seideman , Maxim Sukharev

Polaritons are the collective excitations of many atoms dressed by resonant photons, which can be used to explain the slow light propagation with the mechanism of electromagnetically induced transparency. As quasi-particles, these…

Quantum Physics · Physics 2009-11-13 Lan Zhou , Jing Lu , D. L. Zhou , C. P. Sun

The concept of modifying molecular dynamics in strongly coupled exciton-polariton systems is an emerging topic in photonics due to its potential to produce customized chemical systems with tailored photophysical properties. However, before…

Materials Science · Physics 2020-10-09 Bin Liu , Vinod M. Menon , Matthew Y. Sfeir

Molecular polaritons are hybrid light-matter states that enable the exploration of potential cavity-modified chemistry. The development of dynamical, first-principles approaches for simulating molecular polaritons is important for…

Chemical Physics · Physics 2025-07-18 Millan F. Welman , Tao E. Li , Sharon Hammes-Schiffer

An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…

Chemical Physics · Physics 2024-06-19 Lorenz S. Cederbaum

A light-matter hybrid quasiparticle, called a polariton, is formed when molecules are strongly coupled to an optical cavity. Recent experiments have shown that polariton chemistry can manipulate chemical reactions. Polariton chemistry is a…

Chemical Physics · Physics 2024-01-11 Xinyang Li , Nicholas Lubbers , Sergei Tretiak , Kipton Barros , Yu Zhang

Unitarity cutting rules for the multiplicity of cut Pomerons, or topological cross sections, have been obtained within the framework of nonlinear k_t factorisation. Proper account for the color coupled channel aspects of the problem leads…

High Energy Physics - Phenomenology · Physics 2008-09-05 W. Schäfer

Gas-phase molecules are a promising platform through which to elucidate the mechanisms of action and scope of polaritons for optical control of chemistry. Polaritons arise from the strong coupling of a dipole-allowed molecular transition…

Chemical Physics · Physics 2024-08-20 Jane C. Nelson , Marissa L. Weichman

For the model Hamiltonian describing the electron-nuclear dynamics of a quantum dot, we obtained an exact expression for the limiting nuclear polarization as a function of the number of groups of equivalent nuclei. It is shown that the…

Mesoscale and Nanoscale Physics · Physics 2008-01-10 G. G. Kozlov

A novel, optimized numerical method of modeling of an exciton-polariton superfluid in a semiconductor microcavity was proposed. Exciton-polaritons are spin-carrying quasiparticles formed from photons strongly coupled to excitons. They…

Quantum Gases · Physics 2017-04-26 Oksana Voronych , Adam Buraczewski , Michał Matuszewski , Magdalena Stobińska

Exciton-polaritons - hybrid light-matter quasiparticles - can undergo Bose-Einstein-like condensation at elevated temperatures owing to their lower effective mass. This becomes even more pronounced in the context of molecular polariton…

Strong coupling between molecular excitations and quantized electromagnetic fields in optical cavities provides a powerful means to control the physical and chemical properties of molecular systems. Here, we study electron transfer (ET)…

Chemical Physics · Physics 2026-03-02 Takumi Hidaka , Tomohiro Fukushima , Nguyen Thanh Phuc

Ultracold atoms uniformly filling an optical lattice can be treated like an artificial crystal. An implementation including the atomic occupation of a single excited atomic state can be represented by a two-component Bose-Hubbard model. Its…

Quantum Gases · Physics 2013-07-31 Hashem Zoubi , Helmut Ritsch

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

Chemical Physics · Physics 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

Building on earlier work, the dipole subtraction formalism for photonic corrections is extended to various photon--fermion splittings where the resulting collinear singularities lead to corrections that are enhanced by logarithms of small…

High Energy Physics - Phenomenology · Physics 2008-11-26 Stefan Dittmaier , Alois Kabelschacht , Tobias Kasprzik

We study the photodissociation chemistry of a quantum degenerate gas of bosonic triatomic $ABC$ molecules, assuming two open rearrangement channels ($AB+C$ or $A+BC$). The equations of motion are equivalent to those of a parametric…

Condensed Matter · Physics 2009-11-07 M. G. Moore , A. Vardi

We explore a new fashion, named energy-resolved population image (EPI), to represent on an equal footing the temporary electronic transition and nuclear motion during laser-molecular interaction. By using the EPI we have intuitively…

Atomic and Molecular Clusters · Physics 2015-06-19 Kunlong Liu , Pengfei Lan , Cheng Huang , Qingbin Zhang , Peixiang Lu

Organic polaritons resulting from the strong hybridisation between photons and matter excitations have arisen as a suitable platform to device light-matter technological interfaces at room temperature. Despite their inherent complexity,…

Quantum vorticity in polariton systems has been traditionally investigated within the frame of many-body phenomena under the mean-field or coherent approaches. In the present work, we show that the fully quantized picture describes richer…