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Related papers: Excited State Properties from the Bethe--Salpeter …

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Like adiabatic time-dependent density-functional theory (TD-DFT), the Bethe-Salpeter equation (BSE) formalism of many-body perturbation theory, in its static approximation, is "blind" to double (and higher) excitations, which are…

Chemical Physics · Physics 2021-06-14 Enzo Monino , Pierre-François Loos

The Bethe-Salpeter equation (BSE) combined with the Green's function GW method has successfully transformed into a robust computational tool to describe light-matter interactions and excitation spectra for molecules, solids, and materials…

Chemical Physics · Physics 2025-04-18 Christof Holzer , Yannick J. Franzke

The Bethe-Salpeter equation (BSE) formalism is steadily asserting itself as a new efficient and accurate tool in the ensemble of computational methods available to chemists in order to predict optical excitations in molecular systems. In…

Chemical Physics · Physics 2020-08-26 Xavier Blase , Ivan Duchemin , Denis Jacquemin , Pierre-François Loos

Inspired by Grimme's simplified Tamm-Dancoff density functional theory approach [S. Grimme, J. Chem. Phys. \textbf{138}, 244104 (2013)], we describe a simplified approach to excited state calculations within the GW approximation to the…

Mesoscale and Nanoscale Physics · Physics 2021-09-10 Yeongsu Cho , Sylvia J. Bintrim , Timothy C. Berkelbach

The Bethe-Salpeter equation (BSE) is a reliable model for estimating the absorption spectra in molecules and solids on the basis of accurate calculation of the excited states from first principles. This challenging task includes calculation…

Numerical Analysis · Mathematics 2016-05-04 Peter Benner , Venera Khoromskaia , Boris N. Khoromskij

The $GW$-Bethe-Salpeter Equation (BSE) method is promising for calculating the low-lying excited states of molecular systems. So far, it has only been applied to rather small molecules, and in the commonly implemented diagonal…

Chemical Physics · Physics 2022-08-10 Arno Förster , Lucas Visscher

We present a first-principles method for relaxing a material's geometry in an optically excited state. This method, based on the Bethe-Salpeter equation, consists of solving coupled equations for exciton wavefunctions and atomic…

Computational Physics · Physics 2022-12-29 Mao Yang , Claudia Draxl

Excitonic effects in optical spectra and electron-hole pair excitations are described by solutions of the Bethe-Salpeter equation (BSE) that accounts for the Coulomb interaction of excited electron-hole pairs. Although for the computation…

Other Condensed Matter · Physics 2008-08-20 F. Fuchs , C. Rödl , A. Schleife , F. Bechstedt

Here, we build on the works of Scuseria (et al.) http://dx.doi.org/10.1063/1.3043729 and Berkelbach https://doi.org/10.1063/1.5032314 to show connections between the Bethe-Salpeter equation (BSE) formalism combined with the $GW$…

Chemical Physics · Physics 2022-12-19 Raúl Quintero-Monsebaiz , Enzo Monino , Antoine Marie , Pierre-François Loos

The combination of the many-body Green's function $GW$ approximation and the Bethe-Salpeter equation (BSE) formalism has shown to be a promising alternative to time-dependent density-functional theory (TD-DFT) for computing vertical…

Chemical Physics · Physics 2020-06-05 Pierre-François Loos , Anthony Scemama , Ivan Duchemin , Denis Jacquemin , Xavier Blase

The GW plus Bethe-Salpeter equation (GW-BSE) formalism is a well-established approach for calculating excitation energies and optical spectra of molecules, nanostructures, and crystalline materials. We implement GW-BSE in the CP2K code and…

Computational Physics · Physics 2026-05-29 Maximilian Graml , Jan Wilhelm

Variational calculations of excited electronic states are carried out by finding saddle points on the surface that describes how the energy of the system varies as a function of the electronic degrees of freedom. This approach has several…

Chemical Physics · Physics 2023-02-15 Yorick L. A. Schmerwitz , Gianluca Levi , Hannes Jónsson

Open-shell systems such as magnetic molecules or defects with a triplet ground state are challenging to describe in electronic structure methods, but are of great interest for quantum information applications. We demonstrate a spin-flip…

Materials Science · Physics 2022-07-12 Bradford A. Barker , David A. Strubbe

Excited-state quantum phase transitions depend on and reveal the structure of the whole spectrum of many-body systems. While they are theoretically well understood, finding suitable signatures and detect them in actual experiments remains…

Quantum Gases · Physics 2022-01-19 Josep Cabedo , Alessio Celi

Many-body Green's functions theory within the GW approximation and the Bethe-Salpeter Equation (BSE) is implemented in the open-source VOTCA-XTP software, aiming at the calculation of electronically excited states in complex molecular…

We review the Bethe-Salpeter equation (BSE) approach to the calculation of electronic excitation energies of molecular systems. We recall the general Green's function many-theory formalism and give the working equations of the BSE approach…

Chemical Physics · Physics 2013-04-05 Elisa Rebolini , Julien Toulouse , Andreas Savin

We present an energy-specific Bethe-Salpeter equation (BSE) implementation for efficient core and valence optical spectrum calculations. In energy-specific BSE, high-lying excitation energies are obtained by constructing trial vectors and…

Materials Science · Physics 2025-01-29 Christopher Hillenbrand , Jiachen Li , Tianyu Zhu

Computing the $GW$ quasiparticle bandstructure and Bethe-Salpeter Equation (BSE) absorption spectra for materials with spin-orbit coupling has commonly been done by treating $GW$ corrections and spin-orbit coupling as separate perturbations…

An ab initio approach is presented for studying the collective excitations in excitonic insulators, charge/spin density waves and superconductors. We derive the Bethe-Salpeter-Equation for the particle-hole excitations in the quasiparticle…

Materials Science · Physics 2026-01-09 Fengyuan Xuan , Jiexi Song , Zhiyuan Sun

We apply the renormalized singles (RS) Green's function in the Bethe-Salpeter equation (BSE)/$GW$ approach to predict accurate neutral excitation energies of molecular systems. The BSE calculations are performed on top of the…

Chemical Physics · Physics 2022-10-26 Jiachen Li , Dorothea Golze , Weitao Yang
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