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The many-body expansion (MBE) is an efficient tool which has a long history of use for calculating interaction energies, binding energies, lattice energies, and so on. In the past, applications of MBE to correlation energy have been…

Strongly Correlated Electrons · Physics 2021-08-11 Vibin Abraham , Nicholas Mayhall

Fragmentation methods such as the many-body expansion (MBE) are a common strategy to model large systems by partitioning energies into a hierarchy of decreasingly significant contributions. The number of fragments required for chemical…

Chemical Physics · Physics 2017-09-13 Kun Yao , John E. Herr , John Parkhill

Coarse-grained (CG) molecular dynamics (MD) simulations can simulate large molecular complexes over extended timescales by reducing degrees of freedom. A critical step in CG modeling is the selection of the CG mapping algorithm, which…

Soft Condensed Matter · Physics 2025-07-23 Soumya Mondal , Subhanu Halder , Debarchan Basu , Sandeep Kumar , Tarak Karmakar

In molecular and biological sciences, experiments are expensive, time-consuming, and often subject to ethical constraints. Consequently, one often faces the challenging task of predicting desirable properties from small data sets or…

Machine Learning · Computer Science 2023-01-09 Nicole Hayes , Ekaterina Merkurjev , Guo-Wei Wei

Strategies for machine-learning(ML)-accelerated discovery that are general across materials composition spaces are essential, but demonstrations of ML have been primarily limited to narrow composition variations. By addressing the scarcity…

Mechanistic understanding and rational design of complex chemical systems depend on fast and accurate predictions of electronic structures beyond individual building blocks. However, if the system exceeds hundreds of atoms, first-principles…

Chemical Physics · Physics 2026-04-13 Siqi Chen , Zhiqiang Wang , Yili Shen , Xianqi Deng , Xi Cheng , Cheng-Wei Ju , Jun Yi , Guo Ling , Dieaa Alhmoud , Hui Guan , Zhou Lin

In this study, we utilize the many-body expansion (MBE) framework to decompose electronic structures into fragments by incrementing the virtual orbitals. Our work aims to accurately solve the ground and excited state energies of each…

Chemical Physics · Physics 2023-10-09 Enhua Xu , Yuma Shimomoto , Seiichiro L. Ten-no , Takashi Tsuchimochi

This paper introduces an algorithm for the detection of change-points and the identification of the corresponding subsequences in transient multivariate time-series data (MTSD). The analysis of such data has become more and more important…

Signal Processing · Electrical Eng. & Systems 2023-04-05 Jonas Köhne , Lars Henning , Clemens Gühmann

We introduce techniques for analysing the structure of quantum states of many-body localized (MBL) spin chains by identifying correlation clusters from pairwise correlations. These techniques proceed by interpreting pairwise correlations in…

Disordered Systems and Neural Networks · Physics 2022-02-16 Kévin Hémery , Frank Pollmann , Adam Smith

Due to the wide range of timescales that are present in macromolecular systems, hierarchical multiscale strategies are necessary for their computational study. Coarse-graining (CG) allows to establish a link between different system…

Accurate virtual high-throughput screening (VHTS) of transition metal complexes (TMCs) remains challenging due to the possibility of high multi-reference (MR) character that complicates property evaluation. We compute MR diagnostics for…

Understanding the applicability and limitations of electronic-structure methods needs careful and efficient comparison with accurate reference data. Knowledge of the quality and errors of electronic-structure calculations is crucial to…

We present a wide-reaching revamp of the generalized many-body expanded full configuration interaction (MBE-FCI) method. First, we outline how to automatize the selection of reference active spaces whereby the inherent bias introduced…

Chemical Physics · Physics 2024-06-18 Jonas Greiner , Jürgen Gauss , Janus J. Eriksen

Constructing a chemically diverse dataset while avoiding sampling bias is critical to training efficient and generalizable force fields. However, in computational chemistry and materials science, many common dataset generation techniques…

Machine Learning · Computer Science 2025-09-17 Hong Sun , Joshua A. Vita , Amit Samanta , Vincenzo Lordi

Molecular-orbital-based machine learning (MOB-ML) provides a general framework for the prediction of accurate correlation energies at the cost of obtaining molecular orbitals. We demonstrate the importance of preserving physical…

Chemical Physics · Physics 2021-03-17 Tamara Husch , Jiace Sun , Lixue Cheng , Sebastian J. R. Lee , Thomas F. Miller

Unsupervised multimodal change detection is a practical and challenging topic that can play an important role in time-sensitive emergency applications. To address the challenge that multimodal remote sensing images cannot be directly…

Computer Vision and Pattern Recognition · Computer Science 2023-02-08 Hongruixuan Chen , Naoto Yokoya , Chen Wu , Bo Du

The rational tailoring of transition metal complexes is necessary to address outstanding challenges in energy utilization and storage. Heterobimetallic transition metal complexes that exhibit metal-metal bonding in stacked "double decker"…

Materials Science · Physics 2021-08-02 Michael G. Taylor , Aditya Nandy , Connie C. Lu , Heather J. Kulik

The necessary decarbonization efforts in energy sectors entail the integration of flexibility assets, as well as increased levels of uncertainty for the planning and operation of power systems. To cope with this in a cost-effective manner,…

Systems and Control · Electrical Eng. & Systems 2024-09-25 Stefan Borozan , Spyros Giannelos , Paola Falugi , Alexandre Moreira , Goran Strbac

To accelerate exploration of chemical space, it is necessary to identify the compounds that will provide the most additional information or value. A large-scale analysis of mononuclear octahedral transition metal complexes deposited in an…

The Macroscopic Fundamental Diagram is a popular tool used to describe traffic dynamics in an aggregated way, with applications ranging from traffic control to incident analysis. However, estimating the MFD for a given network requires…

Machine Learning · Computer Science 2026-05-12 Amalie Roark , Serio Agriesti , Francisco Camara Pereira , Guido Cantelmo
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