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A wide variety of nuclear magnetic resonance experiments rely on the prediction and analysis of relaxation processes. Recently, innovative approaches have been introduced where the sample travels through a broad range of magnetic fields in…

We incorporate explicit, non-perturbative treatment of spin-orbit coupling into ab initio auxiliary-field quantum Monte Carlo (AFQMC) calculations. The approach allows a general computational framework for molecular and bulk systems in…

Strongly Correlated Electrons · Physics 2023-02-16 Brandon Eskridge , Henry Krakauer , Hao Shi , Shiwei Zhang

Vibrational properties of solids are key to determining stability, response and functionality. However, they are challenging to computationally predict at Ab-Initio accuracy, even for elemental systems. Ab-Initio methods for modeling atomic…

Materials Science · Physics 2024-06-25 Mgcini Keith Phuthi , Yang Huang , Michael Widom , Venkatasubramanian Viswanathan

First-principles atomistic simulations are essential for understanding complex material phenomena but are fundamentally limited by their computational cost. While Machine Learning Interatomic Potentials (MLIPs) have drastically improved…

Quantum spin systems with kinetic constraints have become paradigmatic for exploring collective dynamical behaviour in many-body systems. Here we discuss a facilitated spin system which is inspired by recent progress in the realization of…

Quantum Gases · Physics 2020-07-22 Paolo P. Mazza , Richard Schmidt , Igor Lesanovsky

Coupled spin-lattice dynamics (SLD) underlie a wide range of magnetic phenomena, yet a unified first-principles framework that propagates both degrees of freedom without empirical parameterization has remained elusive. We present a fully ab…

Materials Science · Physics 2026-05-05 Xianxi Zhang , Hongyu Yu , Liangliang Hong , Hongjun Xiang

The accurate computational determination of chemical, materials, biological, and atmospheric properties has critical impact on a wide range of health and environmental problems, but is deeply limited by the computational scaling of…

Chemical Physics · Physics 2021-06-09 Debadrita Saha , Srinivasan S. Iyengar , Philip Richerme , Jeremy M. Smith , Amr Sabry

Lattice spin models are useful for studying critical phenomena and allow the extraction of equilibrium and dynamical properties. Simulations of such systems are usually based on Monte Carlo (MC) techniques, and the main difficulty is often…

Computational Physics · Physics 2012-09-13 Tal Levy , Guy Cohen , Eran Rabani

Single molecular magnets (SMMs) and Metal-Organic Frameworks (MOFs) attract significant interest due to their potential in quantum information processing, scalable quantum computing, and extended lifetimes and coherence times. The limiting…

Quantum Physics · Physics 2024-07-12 Nosheen Younas , Yu Zhang , Andrei Piryatinski , Eric R Bittner

Simulations of exciton and charge hopping in amorphous organic materials involve numerous physical parameters. Each of these parameters must be computed from costly ab initio calculations before the simulation can commence, resulting in a…

Probabilistic machine learning enabled by the Bayesian formulation has recently gained significant attention in the domain of automated reasoning and decision-making. While impressive strides have been made recently to scale up the…

Emerging Technologies · Computer Science 2020-04-22 Kezhou Yang , Akul Malhotra , Sen Lu , Abhronil Sengupta

A general expression is derived for the dipolar NMR spin-lattice relaxation rate $1/T_1$ of a system exhibiting Brownian dynamics in a discrete and finite configuration space. It is shown that this approach can be particularly useful to…

Chemical Physics · Physics 2015-07-07 P. Wzietek

Accurate structural relaxation is critical for advanced materials design. Traditional approaches built on physics-derived first-principles calculations are computationally expensive, motivating the creation of machine-learning interatomic…

Simulations are vital for understanding and predicting the evolution of complex molecular systems. However, despite advances in algorithms and special purpose hardware, accessing the timescales necessary to capture the structural evolution…

Computational Physics · Physics 2021-02-18 Pantelis R. Vlachas , Julija Zavadlav , Matej Praprotnik , Petros Koumoutsakos

Spin relaxation, dephasing and diffusion are at the heart of spin-based information technology. Accurate theoretical approaches to simulate spin lifetimes ($\tau_s$), determining how fast the spin polarization and phase information will be…

Materials Science · Physics 2023-08-01 Junqing Xu , Yuan Ping

The \textit{Spirit} framework is designed for atomic scale spin simulations of magnetic systems of arbitrary geometry and magnetic structure, providing a graphical user interface with powerful visualizations and an easy to use scripting…

Electron and nuclear spins have been employed in many of the early demonstrations of quantum technology (QT). However applications in real world QT are limited by the difficulty of measuring single spins. Here we show that it is possible to…

Quantum Physics · Physics 2011-05-25 Tom Close , Femi Fadugba , Simon C. Benjamin , Joseph Fitzsimons , Brendon W. Lovett

To facilitate rational molecular and materials design, this research proposes an integrated computational framework that combines stochastic simulation, ab initio quantum chemistry, and molecular docking. The suggested workflow allows…

Materials Science · Physics 2026-01-08 Md Rakibul Karim Akanda , Michael P. Richard

Molecular spins are promising candidates for quantum information science, leveraging coherent electronic spin states for quantum sensing and computation. However, the practical application of these systems is hindered by electronic spin…

Quantum Physics · Physics 2026-03-03 Timothy J. Krogmeier , Anthony W. Schlimgen , Kade Head-Marsden

Machine learning has emerged as an invaluable tool in many research areas. In the present work, we harness this power to predict highly accurate molecular infrared spectra with unprecedented computational efficiency. To account for…

Chemical Physics · Physics 2021-03-16 Michael Gastegger , Jörg Behler , Philipp Marquetand