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We review the field of exoplanetary biosignatures with a main focus upon atmospheric gas-phase species. Due to the paucity of data in Earth-like planetary atmospheres a common approach is to extrapolate knowledge from the Solar System and…
The James Webb Space Telescope (JWST) will enable the search for and characterization of terrestrial exoplanet atmospheres in the habitable zone via transmission spectroscopy. However, relatively little work has been done to use solar…
Deuterium, a heavy isotope of hydrogen, is a key tracer of the formation of the Solar System. Recent JWST observations have expanded the dataset of D/H ratios in methane on the KBOs Eris and Makemake, providing new insights into their…
The detection of strong thermochemical disequilibrium in the atmosphere of an extrasolar planet is thought to be a potential biosignature. In this article we present a new kind of false positive that can mimic a disequilibrium or any other…
Unlocking the atmospheres of sub-Neptunes is among JWST's major achievements, yet such observations demand complex analyses that strongly affect interpretations. We present an independent reanalysis of the original JWST transmission…
Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called…
The characterization of the atmospheres of habitable-zone Earth-mass exoplanets that transit across main-sequence stars, let alone the detection of bio-markers in their atmospheres, will be challenging even with future facilities. It has…
(Abridged) Super Earth exoplanets are being discovered with increasing frequency and some will be able to retain stable H2-dominated atmospheres. We study biosignature gases on exoplanets with thin H2 atmospheres and habitable surface…
The puzzling complexity of terrestrial biomolecules is driving the search for complex organic molecules in the Interstellar Medium (ISM) and serves as a motivation for many in situ studies of reservoirs of extraterrestrial organics from…
Exoplanet hunting efforts have revealed the prevalence of exotic worlds with diverse properties, including Earth-sized bodies, which has fueled our endeavor to search for life beyond the Solar System. Accumulating experiences in…
Thousands of transiting exoplanets have already been detected orbiting a wide range of host stars, including the first planets that could potentially be similar to Earth. The upcoming Extremely Large Telescopes and the James Webb Space…
Knowledge of the nucleosynthetic isotope composition of the outermost protoplanetary disk is critical to understand the formation and early dynamical evolution of the Solar System. We report the discovery of outer disk material preserved in…
Context. Several sulfur-bearing molecules are observed in the interstellar medium and in comets, in strong contrast to protoplanetary disks where only CS, H$_2$CS and SO have been detected so far. Aims. We combine observations and chemical…
O2 and O3 have been long considered the most robust individual biosignature gases in a planetary atmosphere, yet multiple mechanisms that may produce them in the absence of life have been described. However, these abiotic planetary…
Chemical disequilibrium quantified via available free energy has previously been proposed as a potential biosignature. However, exoplanet biosignature remote sensing work has not yet investigated how observational uncertainties impact the…
Some sub-Neptune planets may host habitable conditions; for example "Hycean" worlds with H2 envelopes over liquid water oceans can maintain potentially hospitable pressures and temperatures at their surface. Recent JWST observations of…
Theory and observation for the search for life on exoplanets via atmospheric "biosignature gases" is accelerating, motivated by the capabilities of the next generation of space- and ground-based telescopes. The most observationally…
Research for possible biosignature gases on habitable exoplanet atmosphere is accelerating. We add isoprene, C5H8, to the roster of biosignature gases. We found that formation of isoprene geochemical formation is highly thermodynamically…
The recent JWST detections of carbon-bearing molecules in a habitable-zone sub-Neptune have opened a new era in the study of low-mass exoplanets. The sub-Neptune regime spans a wide diversity of planetary interiors and atmospheres not…
Claims of detections of gases in exoplanet atmospheres often rely on comparisons between models including and excluding specific chemical species. However, the space of molecular combinations available for model construction is vast and…