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Development of thermodynamic induction up to second order gives a dynamical bifurcation for thermodynamic variables and allows for the prediction and detailed explanation of nonequilibrium phase transitions with associated spontaneous…

Statistical Mechanics · Physics 2021-10-07 S. N. Patitsas

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

Time is a parameter playing a central role in our most fundamental modeling of natural laws. Relativity theory shows that the comparison of times measured by different clocks depends on their relative motions and on the strength of the…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-11 Pierre Magain , Clémentine Hauret

We present a validation of the asdf method, an information-theoretic framework for computing thermodynamic entropy from molecular configurations. The method reformulates entropy estimation as the Shannon entropy of a residual mapping…

Statistical Mechanics · Physics 2026-04-29 Dallin Fisher , Qi-Jun Hong

Internal energy, enthalpy and entropy are the key quantities to study thermodynamic properties of the moist atmosphere, because they correspond to the First (internal energy and enthalpy) and Second (entropy) Laws of thermodynamics. The aim…

Atmospheric and Oceanic Physics · Physics 2015-10-13 Pascal Marquet , Jean-François Geleyn

We combine the two classical topological concepts, time-preserving topological factors and synchronizing time-changes of a continuous flow, and explore some of their thermodynamic consequences. Particular focus is put on equilibrium states…

Dynamical Systems · Mathematics 2025-03-25 Katrin Gelfert , Dominik Kwietniak , Yuri Lima

The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

Nonequilibrium thermodynamics of a general second-order stochastic system is investigated. We prove that at steady state, under inversion of velocities, the condition of time-reversibility over the phase space is equivalent to the…

Statistical Mechanics · Physics 2015-10-28 Hao Ge

According to thermodynamics, the inevitable increase of entropy allows the past to be distinguished from the future. From this perspective, any clock must incorporate an irreversible process that allows this flow of entropy to be tracked.…

Quantum Physics · Physics 2021-03-18 Emanuel Schwarzhans , Maximilian P. E. Lock , Paul Erker , Nicolai Friis , Marcus Huber

The Second Law of Thermodynamics asserts that the physical entropy of an adiabatic system is an increasing function in time. In this paper we will study a more stringent version of this law, according to which the entropy should not only…

Analysis of PDEs · Mathematics 2009-07-27 Michael Blaser , Tristan Riviere

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

When thermodynamics is understood as the science (or art) of constructing effective models of natural phenomena by choosing a minimal level of description capable of capturing the essential features of the physical reality of interest, the…

Statistical Mechanics · Physics 2020-03-31 Gian Paolo Beretta

The theory of small-system thermodynamics was originally developed to extend the laws of thermodynamics to length scales of nanometers. Here we review this "nanothermodynamics," and stress how it also applies to large systems that subdivide…

Statistical Mechanics · Physics 2020-07-28 Ralph V. Chamberlin , Michael R. Clark , Vladimiro Mujica , George H. Wolf

There is a relation between the irreversibility of thermodynamic processes as expressed by the breaking of time-reversal symmetry, and the entropy production in such processes. We explain on an elementary mathematical level the relations…

Statistical Mechanics · Physics 2007-05-23 C. Maes , K. Netocny

In this work, we have considered the Vaidya spacetime in null radiating fluid with perfect fluid in higher dimension and have found the solution for barotropic fluid. We have shown that the Einstein's field equations can be obtained from…

General Relativity and Quantum Cosmology · Physics 2012-10-04 Ujjal Debnath

The thermodynamic equilibrium states of a static thin ring shell in a (2+1)-dimensional flat spacetime is analyzed. Inside the ring the spacetime is flat, whereas outside it is conical flat. The first law of thermodynamics applied to the…

General Relativity and Quantum Cosmology · Physics 2015-06-17 José P. S. Lemos , Gonçalo M. Quinta

It is established that black holes have entropy and behave as thermodynamical systems. Associating entropy to gravitational fields has not remained limited to black holes, necessitating the notion of the second law of thermodynamics in…

High Energy Physics - Theory · Physics 2026-03-26 V. R. Shajiee , M. M. Sheikh-Jabbari

The main goal of this paper is to reach an explicit formulation and possible interpretation of thermodynamic length in a thermodynamic state space with two degrees of freedom. Using the energy and entropy metric in a general form, we get…

Mathematical Physics · Physics 2009-11-10 Manuel Santoro

In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…

Quantum Physics · Physics 2007-05-23 Elias P. Gyftopoulos , Gian Paolo Beretta

In a recent article we have introduced Friedmann thermodynamics, where certain geometric parameters in Friedmann models are treated like their thermodynamic counterparts (temperature, entropy, Gibbs potential etc.). This model has the…

General Relativity and Quantum Cosmology · Physics 2008-04-02 Selcuk S. Bayin