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The hydrogen dynamics on a graphene sheet is studied in the presence of carbon vacancies. We analyze the motion of atomic H by means of molecular dynamics (MD) simulations, using a tight-binding Hamiltonian fitted to density-functional…

Chemical Physics · Physics 2022-09-29 Carlos P. Herrero , Jose A. Verges , Rafael Ramirez

To clarify the yielding mechanism of small hydrocarbon molecules in chemical sputtering between hydrogen and graphene sheets, we made classical molecular dynamics simulation with modified Brenner's REBO potential which we proposed to deal…

Materials Science · Physics 2007-05-23 Hiroaki Nakamura , Atsushi Ito

Investigating atom-surface interactions is the key to an in-depth understanding of chemical processes at interfaces, which are of central importance in many fields -- from heterogeneous catalysis to corrosion. In this work, we present a…

Chemical Physics · Physics 2023-12-18 Martin Liebetrau , Yvonne Dorenkamp , Oliver Bünermann , Jörg Behler

Collisions of atoms and molecules with metal surfaces create electronic excitations in the metal, leading to nonadiabatic energy dissipation, inelastic scattering, and sticking. Mixed quantum-classical molecular dynamics simulation methods,…

New interlayer intermolecular potential model was proposed and it represented ``ABAB'' staking of graphite. Hydrogen atom sputtering on graphite surface was investigated using molecular dynamics simulation. In the initial short time period,…

Materials Science · Physics 2007-11-26 Atsushi Ito , Hiroaki Nakamura

Hydrogen adsorption by graphite is examined by classical molecular dynamics simulation using a modified Brenner REBO potential. Such interactions are typical in chemical sputtering experiments, and knowledge of the fundamental behavior of…

Soft Condensed Matter · Physics 2009-11-11 A. Ito , H. Nakamura

We present a detailed study of the nuclear quantum effects in H/D sticking to graphene, comparing classical, quantum and mixed quantum/classical simulations to results of scattering experiments. Agreement with experimentally derived…

Time-dependent density-functional theory simulations are performed to examine the effects of varying incident points and kinetic energies of hydrogen atom projectiles on a graphene-like structure. The simulations reveal that the incident…

Materials Science · Physics 2024-12-11 Samuel S. Taylor , Nicholas Skoufis , Hongbo Du , Cody Covington , Kalman Varga

The simulation of ion-atom collisions remains a formidable challenge due to the complex interplay between electronic and nuclear degrees of freedom. We present a hybrid quantum-classical computing framework for simulating time-dependent…

Quantum Physics · Physics 2026-02-03 Minchen Qiao , Yu-xi Liu

We report a new Quantum Mechanical/Molecular Dynamics (QM/MD) simulation loop to model the coupling between the electron and atom dynamics in solid/liquid interfacial systems. The method can describe simultaneously both the quantum…

Materials Science · Physics 2021-02-03 Joshua D Elliott , Alessandro Troisi , Paola Carbone

Path-integral molecular dynamics (PIMD) simulations have been carried out to study the influence of quantum dynamics of carbon atoms on the properties of a single graphene layer. Finite-temperature properties were analyzed in the range from…

Materials Science · Physics 2016-12-23 Carlos P. Herrero , Rafael Ramirez

Previous research based on electronic structure calculations and molecular dynamics (MD) simulations have demonstrated that graphdiyne (GDY) is a very suitable two-dimensional membrane for the separation of small molecules in a gas mixture…

Chemical Physics · Physics 2026-03-27 Mateo Rodríguez , José Campos-Martínez , Marta I. Hernández

Graphene outstanding properties created a huge interest in the condensed matter community and unprecedented fundings at the international scale in the hope of application developments. Recently, there have been several reports of incomplete…

Materials Science · Physics 2016-04-20 L. Delfour , A. Davydova , E. Despiau-Pujo , G. Cunge , D. B. Graves , L. Magaud

With the aim of studying nonperturbative out-of-equilibrium dynamics of high-energy particle collisions on quantum simulators, we investigate the scattering dynamics of lattice quantum electrodynamics in 1+1 dimensions. Working in the…

Atomic and molecular scattering at semiconductor interfaces plays a central role in surface chemistry and catalysis, yet predictive simulations remain challenging due to strong nonadiabatic effects causing the breakdown of the…

Materials Science · Physics 2026-01-16 Xiaohan Dan , Zhuoran Long , Tianyin Qiu , Jan Paul Menzel , Qiang Shi , Victor S. Batista

We propose a model based on density functional theory (DFT) and quantum electrodynamics (QED) to study the dynamical characteristics of graphene quantum dots (GQDs). We assume the GQD edges are saturated with hydrogen atoms, effectively…

Mesoscale and Nanoscale Physics · Physics 2026-04-09 J. Olivo , J. Blengino Albrieu , Mauro Cuevas

The powerful molecular dynamics (MD) simulation is basically based on a picture that the atoms experience classical-like trajectories under the exertion of classical force field determined by the quantum mechanically solved electronic…

Chemical Physics · Physics 2013-12-16 Wei Feng , Luting Xu , Xin-Qi Li , Weihai Fang

A first-principles coupled electron-nuclear dynamics simulation based on real-time, time-dependent density functional theory and Ehrenfest dynamics quantitatively repro-duces bimodal translational energy loss and angular distributions…

Chemical Physics · Physics 2025-12-05 Jialong Shi , Lingjun Zhu , Florian Nitz , Oliver Bünermann , Alec M. Wodtke , Hua Guo , Bin Jiang

Graphane is a quasi-two-dimensional material consisting of a single layer of fully hydrogenated graphene, with a C:H ratio of 1. We study nuclear quantum effects in the so-called chair-graphane by using path-integral molecular dynamics…

Chemical Physics · Physics 2020-08-24 Carlos P. Herrero , Rafael Ramirez

Understanding strongly correlated systems is essential for advancing quantum chemistry and materials science, yet conventional methods like Density Functional Theory (DFT) often fail to capture their complex electronic behavior. To address…

Chemical Physics · Physics 2025-09-01 Archith Rayabharam , N. R. Aluru
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